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An efficient method for the C-N cross-coupling of (hetero)aryl (pseudo)halides with optically pure alpha-amino acid esters em-ploying a commercially available nickel catalyst and weak inorganic base was developed. This is the first example of Ni-catalyzed N-arylation of amino acid esters without the use of electrochemistry, which was shown to effectively couple a variety of amino acid tert-butyl esters with (hetero)aryl chlorides, bromides, and tosylates in high yields and excellent enantioreten-tion. Base-mediated racemization was revealed during control experiments, but increasing the steric bulk of the amino acid ester group limited the amount of racemization of the product.
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Chrysin, a well-known naturally occurring flavonoid having several biological effects including antiproliferative activity, was coupled with different pharmacophore structures. Coupling was carried out with spacers of different lengths and types. Structures selected for hybrid formation were amines, cyclic amino acid esters, and (hetero)aromatic compounds. In addition, vindoline, which is a Vinca alkaloid containing an indole skeleton, was also used. The alkylation of amines in the presence of carbonate base resulted in an interesting carbamate side product formation beside the expected amine. We also present the detailed structure elucidation of the carbamates. The in vitro anticancer activities of the synthesized derivatives were examined against 60 human tumor cell lines in National Cancer Institute (NCI, USA).
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;33856060" target="_blank">Synthesis and In Vitro Anticancer Evaluation of Chrysin Containing Hybrids and Other Chrysin Derivatives</a></div> <div> <span class="journal-title">PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING</span>
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<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Funding Agency and Grant Number: European Union [RRF-2.3.1-21-2022-00015]
Funding text: Project no. RRF-2.3.1-21-2022-00015 has been imple-mented with the support provided by the European Union. The authors thank Aron Szigetvari and Csaba Szantay Jr. for their contribution to the NMR results.</pre>
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The possibility of functionalization of 2-(polyfluorophenyl)-4H-chromen-4-ones, with them having different numbers of fluorine atoms, with 1,2,4-triazole or imidazole under conditions of base-promoted nucleophilic aromatic substitution has been shown. A high selectivity of mono-substitution was found with the use of an azole (1.5 equiv.)/NaOBut(1.5 equiv.)/MeCN system. The structural features of fluorinated mono(azolyl)-substituted flavones in crystals were established using XRD analysis. The ability of penta- and tetrafluoroflavones to form persubstituted products with triazole under azole (6 equiv.)/NaOBut(6 equiv.)/DMF conditions was found in contrast to similar transformations with imidazole. On the basis of mono(azolyl)-containing polyfluoroflavones in reactions with triazole and pyrazole, polynuclear hybrid compounds containing various azole fragments were obtained. For poly(pyrazolyl)-substituted flavones, green emission in the solid state under UV-irradiation was found, and for some derivatives, weak fungistatic activity was found.
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Corn silk (Stigma maydis), being the styles and stigmas of maize, is a famous traditional medicine and functional tea in China. Research into the chemical composition of corn silk led to the identification of an unreported flavone (1, silkone A), accompanying with three known flavonoids (2-4). And their structures were elucidated through comprehensive spectroscopic analysis. Each obtained compound was evaluated for antioxidant capacity by DPPH, ABTS and FRAP assays. As a result, all tested compounds exhibited stronger radicals scavenging activities than Trolox in ABTS radical assay and displayed relatively weak antioxidant capacity in the other two experiments. Tyrosinase inhibitory activities of compounds 1-4 were also investigated, and compounds 3 and 4 demonstrated moderate inhibitory activities to tyrosinase with IC50 values of 0.49 and 0.21 mM, respectively, which was further investigated through molecular docking calculation. These results may contribute to the development of novel antioxidants and tyrosinase inhibitors from corn silk.
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Eucalyptus plants have attracted the attention of researchers and environmentalists worldwide because they are a rapidly growing source of wood and a source of oil used for multiple purposes. The main and the most important oil component is 1,8-cineole (eucalyptol: 60-85%). This review summarizes the literature reported to date involving the use of 1,8-cineole for the treatment of disorders. Additionally, we describe our efforts in the use of eucalyptol as a solvent for the synthesis of O,S,N-heterocycles. Solvents used in chemistry are a fundamental element of the environmental performance of processes in corporate and academic laboratories. Their influence on costs, safety and health cannot be neglected. Green solvents such as bio-based systems hold considerable additional promise to reduce the environmental impact of organic chemistry. The first section outlines the process leading to our discovery of an unprecedented solvent and its validation in the first coupling reactions. This section continues with the description of its properties and characteristics and its reuse as reported in the various studies conducted. The second section highlights the use of eucalyptol in a series of coupling reactions (i.e., Suzuki-Miyaura, Sonogashira-Hagihara, Buchwald-Hartwig, Migita-Kosugi-Stille, Hiyama and cyanation) that form O,S,N-heterocycles. We describe the optimization process applied to reach the ideal conditions. We also show that eucalyptol can be a good alternative to build heterocycles that contain oxygen, sulfur and nitrogen. These studies allowed us to demonstrate the viability and potential that bio solvents can have in synthesis laboratories.
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A simple and efficient method for the synthesis of flavones was achieved by selective sulfide LiebeskindSrogl cross-coupling reaction of 2-(methylthio)-4H-chromen-4-ones and 3-halo-2-(methylthio)-4H-chromen-4-ones with arylboronic acids. This method is the first example of employing Liebeskind-Srogl coupling for the synthesis of flavones. Various aryl groups can be directly installed to the chromone ring. The structure of all the synthesized compounds were assigned by spectroscopic analysis. (C) 2022 Elsevier Ltd. All rights reserved.
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;
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;33340239" target="_blank">Synthesis of functionalized flavones from 3-halo-2-(methylthio)-4H-chromen-4-ones</a></div> <div> <span class="journal-title">TETRAHEDRON LETTERS</span>
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Molecular Docking Studies and Application of 6-(1-Arylmethanamino)-2-Phenyl-4H-Chromen-4-Ones as Potent Antibacterial Agents
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The present article depicts the synthesis of the series of 6-(1-arylmethanamino)-2-phenyl-4H-chromen-4-ones and their antibacterial activity against the S. aureus. 6-(1-arylmethanamino)-2-phenyl-4H-chromen-4-ones (1a-1n) were obtained via reductive amination reaction of 6-aminoflavone with various commercially available aldehydes. Synthesized compounds and 6-aminoflavone (1) were assessed for their antimicrobial activities against the S. aureus. 6-aminoflavone (1) was found to have an MIC of 2 mu g/mL. The compounds with side chains 4-fluorobenzyl (1a), 4-chlorobenzyl (1b), 4-nitrobenzyl (1e), 4-methoxybenzyl (1g) and (quinolin-2-yl)methyl (1n) were found to have an MIC of 2 mu g/mL. We have demonstrated that 6-(1-arylmethanamino)-2-phenyl-4H-chromen-4-ones are easily accessible via reductive amination reaction. These compounds are found to have antibacterial effect against S. aureus.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Thorat, Nitin M. M. ✉ </span> <span class="author-type"> </span> ; <span class="author-name" > Khodade, Vinnayak S. S. </span> <span class="author-type"> </span> ; <span class="author-name" > Ingale, Ajit P. P. </span> <span class="author-type"> </span> ; <span class="author-name" > Lokwani, Deepak K. K. </span> <span class="author-type"> </span> ; <span class="author-name" > Sarkate, Aniket P. P. </span> <span class="author-type"> </span> ; <span class="author-name" > Thopate, Shankar R. R. </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;33897419" mtid="33897419" target="_blank">Molecular Docking Studies and Application of 6-(1-Arylmethanamino)-2-Phenyl-4H-Chromen-4-Ones as Potent Antibacterial Agents</a></div> <div class="pub-info"> <span class="journal-title">POLYCYCLIC AROMATIC COMPOUNDS</span> <span class="journal-volume"></span> <span class="page"> , 14 p. </span> <span class="year">(2022)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1080/10406638.2022.2150238" target="_blank" href="https://doi.org/10.1080/10406638.2022.2150238"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000896670000001" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000896670000001"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85144182683" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85144182683"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:33897419 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list">
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;
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;
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;33897419" target="_blank">Molecular Docking Studies and Application of 6-(1-Arylmethanamino)-2-Phenyl-4H-Chromen-4-Ones as Potent Antibacterial Agents</a></div> <div> <span class="journal-title">POLYCYCLIC AROMATIC COMPOUNDS</span>
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The N-arylation of chiral amino acid esters with minimal racemization is a challenging transformation because of the sensitivity of the alpha-stereocenter. A versatile synthetic method was developed to prepare N-arylated amino acid esters using cyclohexanones as aryl sources under continuous-flow conditions. The designed flow system, which consists of a coil reactor and a packed-bed reactor containing a Pd(OH)(2)/C catalyst, efficiently afforded the desired N-arylated amino acids without significant racemization, accompanied by only small amounts of easily removable co-products (i. e., H2O and alkanes). The efficiency and robustness of this method allowed for the continuous synthesis of the desired product in very high yield and enantiopurity with high space-time yield (74.1 g L-1 h(-1)) and turnover frequency (5.9 h(-1)) for at least 3 days.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Ichitsuka, Tomohiro ✉ </span> <span class="author-type"> </span> ; <span class="author-name" > Komatsuzaki, Shingo </span> <span class="author-type"> </span> ; <span class="author-name" > Masuda, Koichiro </span> <span class="author-type"> </span> ; <span class="author-name" > Koumura, Nagatoshi ✉ </span> <span class="author-type"> </span> ; <span class="author-name" > Sato, Kazuhiko </span> <span class="author-type"> </span> ; <span class="author-name" > Kobayashi, Shu ✉ </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;32442026" mtid="32442026" target="_blank">Stereoretentive N-Arylation of Amino Acid Esters with Cyclohexanones Utilizing a Continuous-Flow System</a></div> <div class="pub-info"> <span class="journal-title">CHEMISTRY-A EUROPEAN JOURNAL</span> <span class="journal-volume">27</span> : <span class="journal-issue">42</span> <span class="page"> pp. 10844-10848. , 5 p. </span> <span class="year">(2021)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1002/chem.202101439" target="_blank" href="https://doi.org/10.1002/chem.202101439"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000655517400001" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000655517400001"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85106608846" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85106608846"> Scopus </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="33909295" target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=PubMed&list_uids=33909295&dopt=Abstract"> PubMed </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:32442026 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Ichitsuka Tomohiro ✉ </span> ; 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Chiral Flavonoids as Antitumor Agents
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Flavonoids are a group of natural products with a great structural diversity, widely distributed in plant kingdom. They play an important role in plant growth, development and defense against aggressors. Flavonoids show a huge variety of biological activities such as antioxidant, anti-inflammatory, anti-mutagenic, antimicrobial and antitumor, being able to modulate a large diversity of cellular enzymatic activities. Among natural flavonoids, some classes comprise chiral molecules including flavanones, flavan-3-ols, isoflavanones, and rotenoids, which have one or more stereogenic centers. Interestingly, in some cases, individual compounds of enantiomeric pairs have shown different antitumor activity. In nature, these compounds are mainly biosynthesized as pure enantiomers. Nevertheless, they are often isolated as racemates, being necessary to carry out their chiral separation to perform enantioselectivity studies. Synthetic chiral flavonoids with promising antitumor activity have also been obtained using diverse synthetic approaches. In fact, several new chiral bioactive flavonoids have been synthesized by enantioselective synthesis. Particularly, flavopiridol was the first cyclin-dependent kinase (CDK) inhibitor which entered clinical trials. The chiral pool approaches using amino acid as chiral building blocks have also been reported to achieve small libraries of chrysin derivatives with more potent in vitro growth inhibitory effect than chrysin, reinforcing the importance of the introduction of chiral moieties to improve antitumor activity. In this work, a literature review of natural and synthetic chiral flavonoids with antitumor activity is reported for the first time.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Pinto, Claudia </span> <span class="author-type"> </span> ; <span class="author-name" > Cidade, Honorina </span> <span class="author-type"> </span> ; <span class="author-name" > Pinto, Madalena </span> <span class="author-type"> </span> ; <span class="author-name" > Tiritan, Maria Elizabeth ✉ </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;33340242" mtid="33340242" target="_blank">Chiral Flavonoids as Antitumor Agents</a></div> <div class="pub-info"> <span class="journal-title">PHARMACEUTICALS</span> <span class="journal-volume">14</span> : <span class="journal-issue">12</span> <span class="page"> Paper: 1267 , 29 p. </span> <span class="year">(2021)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.3390/ph14121267" target="_blank" href="https://doi.org/10.3390/ph14121267"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000737016400001" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000737016400001"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85121285620" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85121285620"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:33340242 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list">
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<span class="author-name" >Tiritan Maria Elizabeth ✉
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;33340242" target="_blank">Chiral Flavonoids as Antitumor Agents</a></div> <div> <span class="journal-title">PHARMACEUTICALS</span>
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Akhila, Vijayan R.
Mechanochemical Synthesis, in vitro Evaluation and Molecular Docking Studies of 4-Amino-2-arylamino-5-(benzofuran-2-oyl)thiazoles as Antidiabetic Agents
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The synthesis of 4-amino-2-arylamino-5-(benzofuran-2-oyl)thiazoles 4a-h, as example of 2,4-diaminothiazole-benzofuran hybrids and an evaluation of their antidiabetic activity, by in vitro and computational methods, are reported. The synthesis of these diaminothiazoles was achieved mechano chemically by a rapid solvent-less method. Their antidiabetic activity was assessed by alpha-glucosidase and alpha-amylase inhibition assays. The, IC50 value for alpha-glucosidase inhibition by 4-amino-5-(benzofuran-2-oyl)-2-(4-methoxyphenylamino)thiazole (4d) was found to be 20.04 mu M and the IC50 value for alpha-amylase inhibition, 195.03 mu M whereas the corresponding values for reference acarbose were 53.38 mu M and 502.03 mu M, respectively. Molecular docking studies at the active sites of alpha-glucosidase and alpha-amylase showed that among the diaminothiazoles 4a-h now studied, 4-amino-5-(benzofuran-2-oyl)-2-(4-methoxyphenylamino)thiazole (4d) has the highest D-scores of -8.63 and -8.08 for alpha-glucosidase and for alpha-amylase, with binding energies -47.76 and -19.73 kcal/mol, respectively.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Akhila, Vijayan R. </span> <span class="author-type"> </span> ; <span class="author-name" > Priya, Maheswari R. </span> <span class="author-type"> </span> ; <span class="author-name" > Sherin, Daisy R. </span> <span class="author-type"> </span> ; <span class="author-name" > Krishnapriya, Girija K. </span> <span class="author-type"> </span> ; <span class="author-name" > Keerthi, Sreerekha V. </span> <span class="author-type"> </span> ; <span class="author-name" > Manojkumar, Thanathu K. </span> <span class="author-type"> </span> ; <span class="author-name" > Rajasekharan, Kallikat N. ✉ </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;31067372" mtid="31067372" target="_blank">Mechanochemical Synthesis, in vitro Evaluation and Molecular Docking Studies of 4-Amino-2-arylamino-5-(benzofuran-2-oyl)thiazoles as Antidiabetic Agents</a></div> <div class="pub-info"> <span class="journal-title">LETTERS IN ORGANIC CHEMISTRY</span> <span class="journal-volume">16</span> : <span class="journal-issue">7</span> <span class="page"> pp. 560-568. , 9 p. </span> <span class="year">(2019)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.2174/1570178615666180815124425" target="_blank" href="https://doi.org/10.2174/1570178615666180815124425"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000469516900008" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000469516900008"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85070086138" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85070086138"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:31067372 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Akhila Vijayan R. </span> ; 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We report here the use of eucalyptol as a bio-based solvent for the Buchwald-Hartwig reaction on O,S,N-heterocycles. These heterocycles containing oxygen, sulfur and nitrogen were chosen as targets or as starting materials. Once again, eucalyptol demonstrated to be a possible sustainable alternative to common solvents.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Campos, Joana E. </span> <span class="author-type"> </span> ; <span class="author-name" > Berteina-Raboin, Sabine ✉ </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;31067370" mtid="31067370" target="_blank">Eucalyptol as a Bio-Based Solvent for Buchwald-Hartwig Reaction on O,S,N-Heterocycles</a></div> <div class="pub-info"> <span class="journal-title">CATALYSTS</span> <span class="journal-volume">9</span> : <span class="journal-issue">10</span> <span class="page"> Paper: 840 , 11 p. </span> <span class="year">(2019)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.3390/catal9100840" target="_blank" href="https://doi.org/10.3390/catal9100840"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000498266100056" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000498266100056"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85073757099" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85073757099"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:31067370 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Campos Joana E. </span> ; <span class="author-name" >Berteina-Raboin Sabine ✉ </span> </div> </div> <div class="title"><a href="/gui2/?mode=browse¶ms=publication;31067370" target="_blank">Eucalyptol as a Bio-Based Solvent for Buchwald-Hartwig Reaction on O,S,N-Heterocycles</a></div> <div> <span class="journal-title">CATALYSTS</span> <span class="journal-issn">( <a target="_blank" href="https://portal.issn.org/resource/ISSN/2073-4344">2073-4344</a>)</span>: <span class="journal-volume">9</span> <span class="journal-issue">10</span> <span class="page"> Paper 840. 11 p. </span> <span class="year">(2019)</span> </div> <div class="pub-footer"> <span class="language" xmlns="http://www.w3.org/1999/html">Nyelv: Angol | </span> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.3390/catal9100840" target="_blank" href="https://doi.org/10.3390/catal9100840"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000498266100056" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000498266100056"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85073757099" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85073757099"> Scopus </a> </span> </span> <div class="publication-citation"> <a target="_blank" href="/api/publication?cond=citations.related;eq;31067370&sort=publishedYear,desc&sort=title"> Idézett közlemények száma: 1 </a> </div> <div class="mtid"><span class="long-pub-mtid">Közlemény: 31067370</span> | <span class="status-data status-VALIDATED"> Egyeztetett </span> Idéző | <span class="type-subtype">Folyóiratcikk ( Szakcikk ) </span> | <span class="pub-category">Tudományos</span> | <span class="publication-sourceOfData">WoS-XML</span> </div> <div class="lastModified">Utolsó módosítás: 2023.08.21. 15:00 Bartus Sándor (DE/GTK admin5) </div> </div></div>
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A new nano-catalyst which contains a core of magnetic Fe3O4 nanoparticles (NPs) has been fabricated. It is covered via isonicotinic acid hydrazide and copper (Cu). In this sense, Isonicotinic acid hydrazide (INH) is applied because of its ability as a bidendental ligand and pharmaceutical activity in order to be used for the complexion and connection of Cu on Fe3O4 surface for the synthesis of Fe3O4@INH@Cu (INH= Isonicotinic acid hydrazide). In this regard, Fe3O4@INH@Cu as a heterogeneous nanocatalyst for the cross-coupling of aryl halides with potassium hydroxide (KOH) as the hydroxide source and ammonium acetate (NH4OAc), as the amine source in the presence of cesium carbonate (Cs2CO3) in polyethylene glycol (PEG-400), has been applied. The catalyst is a new magnetically recyclable catalytic system with easy preparation and purification, high activity, eco-friendly and economic advantages.
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Scattolin, Thomas
Straightforward access to N-trifluoromethyl amides, carbamates, thiocarbamates and ureas
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Amides and related carbonyl derivatives are of central importance across the physical and life sciences(1,2). As a key biological building block, the stability and conformation of amides affect the structures of peptides and proteins as well as their biological function. In addition, amide-bond formation is one of the most frequently used chemical transformations(3,4). Given their ubiquity, a technology that is capable of modifying the fundamental properties of amides without compromising on stability may have considerable potential in pharmaceutical, agrochemical and materials science. In order to influence the physical properties of organic molecules-such as solubility, lipophilicity, conformation, pK(a) and (metabolic) stability-fluorination approaches have been widely adopted(5-7). Similarly, site-specific modification with isosteres and peptidomimetics(8), or in particular by N-methylation(9), has been used to improve the stability, physical properties, bioactivities and cellular permeabilities of compounds. However, the N-trifluoromethyl carbonyl motif-which combines both N-methylation and fluorination approaches-has not yet been explored, owing to a lack of efficient methodology to synthesize it. Here we report a straightforward method to access N-trifluoromethyl analogues of amides and related carbonyl compounds. The strategy relies on the operationally simple preparation of bench-stable carbamoyl fluoride building blocks, which can be readily diversified to the corresponding N-CF3 amides, carbamates, thiocarbamates and ureas. This method tolerates rich functionality and stereochemistry, and we present numerous examples of highly functionalized compounds-including analogues of widely used drugs, antibiotics, hormones and polymer units.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Scattolin, Thomas </span> <span class="author-type"> </span> ; <span class="author-name" > Bouayad-Gervais, Samir </span> <span class="author-type"> </span> ; <span class="author-name" > Schoenebeck, Franziska ✉ </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;31067371" mtid="31067371" target="_blank">Straightforward access to N-trifluoromethyl amides, carbamates, thiocarbamates and ureas</a></div> <div class="pub-info"> <span class="journal-title">NATURE</span> <span class="journal-volume">573</span> : <span class="journal-issue">7772</span> <span class="page"> pp. 102-107. , 7 p. </span> <span class="year">(2019)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1038/s41586-019-1518-3" target="_blank" href="https://doi.org/10.1038/s41586-019-1518-3"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000483967700042" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000483967700042"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85071759027" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85071759027"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:31067371 </span> <span class="status-holder"><span class="status-data status-APPROVED"> Nyilvános </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Scattolin Thomas </span> ; <span class="author-name" >Bouayad-Gervais Samir </span> ; <span class="author-name" >Schoenebeck Franziska ✉ </span> </div> </div> <div class="title"><a href="/gui2/?mode=browse¶ms=publication;31067371" target="_blank">Straightforward access to N-trifluoromethyl amides, carbamates, thiocarbamates and ureas</a></div> <div> <span class="journal-title">NATURE</span> <span class="journal-issn">(<a target="_blank" href="https://portal.issn.org/resource/ISSN/0028-0836">0028-0836</a> <a target="_blank" href="https://portal.issn.org/resource/ISSN/1476-4687">1476-4687</a>)</span>: <span class="journal-volume">573</span> <span class="journal-issue">7772</span> <span class="page"> pp 102-107 </span> <span class="year">(2019)</span> </div> <div class="pub-footer"> <span class="language" xmlns="http://www.w3.org/1999/html">Nyelv: Angol | </span> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1038/s41586-019-1518-3" target="_blank" href="https://doi.org/10.1038/s41586-019-1518-3"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000483967700042" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000483967700042"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85071759027" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85071759027"> Scopus </a> </span> </span> <div class="publication-citation"> <a target="_blank" href="/api/publication?cond=citations.related;eq;31067371&sort=publishedYear,desc&sort=title"> Idézett közlemények száma: 1 </a> </div> <div class="mtid"><span class="long-pub-mtid">Közlemény: 31067371</span> | <span class="status-data status-APPROVED"> Nyilvános </span> Idéző | <span class="type-subtype">Folyóiratcikk ( Szakcikk ) </span> | <span class="pub-category">Tudományos</span> | <span class="publication-sourceOfData">WoS-XML</span> </div> <div class="lastModified">Utolsó módosítás: 2023.08.21. 15:04 Bartus Sándor (DE/GTK admin5) </div> </div></div>
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Transformations of 3-acyl-4H-polyfluorochromen-4-ones under the action of amino acids and biogenic amines
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For the first time 6,7,8-trifluoro- and 5,6,7,8-tetrafluorinated 3-benzoylflavones have been obtained. Their reactions with amino acids and biogenic amines were studied in comparison with polyfluorinated 3-acetyl-2-methylchromones. For chromones, reactions at the C-2 are preferred, which lead to the pyrone ring opening to form N-substituted aminoenketones. Whereas in the case of flavones the main route is the nucleophilic aromatic substitution of the fluorine atom at the C-7. Flavones and chromones react in the same way both with dopamine to give aminoenketones, and with proline to form 7-amino-substituted chromen-4-ones. All the reactions of chromen-4-ones are accompanied by deacylation, except ones of flavones with proline. Among the synthesized aminoenketones, compounds with high antimycotic and antibacterial action were found.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Shcherbakov, Konstantin V. ✉ </span> <span class="author-type"> </span> ; <span class="author-name" > Artemyeva, Mariya A. </span> <span class="author-type"> </span> ; <span class="author-name" > Burgart, Yanina V. </span> <span class="author-type"> </span> ; <span class="author-name" > Evstigneeva, Natalya P. </span> <span class="author-type"> </span> ; <span class="author-name" > Gerasimova, Natalya A. </span> <span class="author-type"> </span> ; <span class="author-name" > Zilberberg, Natalia V. </span> <span class="author-type"> </span> ; <span class="author-name" > Kungurov, Nicolai V. </span> <span class="author-type"> </span> ; <span class="author-name" > Saloutin, Victor I. </span> <span class="author-type"> </span> ; <span class="author-name" > Chupakhin, Oleg N. </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;31067369" mtid="31067369" target="_blank">Transformations of 3-acyl-4H-polyfluorochromen-4-ones under the action of amino acids and biogenic amines</a></div> <div class="pub-info"> <span class="journal-title">JOURNAL OF FLUORINE CHEMISTRY</span> <span class="journal-volume">226</span> <span class="page"> Paper: UNSP 109354 , 13 p. </span> <span class="year">(2019)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1016/j.jfluchem.2019.109354" target="_blank" href="https://doi.org/10.1016/j.jfluchem.2019.109354"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000497250900009" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000497250900009"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85070288939" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85070288939"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:31067369 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Shcherbakov Konstantin V. ✉ </span> ; 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Synthesis of Flavone Derivatives through Versatile Palladium-Catalyzed Cross-Coupling Reactions of Tosyloxy- and Mesyloxyflavones
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Tosyloxy- and mesyloxyflavones derived from abundant and biologically important hydroxyflavones were used to synthesize a series of functionalized flavones through versatile palladium-catalyzed cross-coupling reactions. A Pd(OAc) (2) /2-[2-(dicyclohexylphosphino)phenyl]-1-methyl-1 H -indole system effectively catalyzed the reactions of a broad range of tosyloxy- and mesyloxyflavones as electrophilic coupling partners with various nucleophiles to give the corresponding products in good to excellent yields. Catalyst loadings of as little as 0.1 mol% Pd were successfully used. Importantly, we demonstrated that this protocol provided a significantly improved efficiency in the synthesis of a potential chromen-4-one-based analogue of a potent inhibitor of DNA-dependent protein kinase.
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<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Cited By :42
Export Date: 6 November 2019
CODEN: JORCA
Correspondence Address: Heravi, M.M.; Department of Chemistry, Department of Chemistry, Alzahra University, Vanak, Iran; email: mmh1331@yahoo.com</pre>
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Funding Agency and Grant Number: Alexander von Humboldt FoundationAlexander von Humboldt Foundation; Science and Educational Research Board (SERB) [EMR/2016/005439]; Council for Scientific and Industrial Research (CSIR)Council of Scientific & Industrial Research (CSIR) - India [02(0298)/17/EMR-II]
Funding text: A.R.K. acknowledges the Alexander von Humboldt Foundation for an equipment grant. A.R.K. also thanks the Science and Educational Research Board (SERB) for a research grant (EMR/2016/005439) and the Council for Scientific and Industrial Research (CSIR) through the EMR scheme (02(0298)/17/EMR-II), as well as research fellowships for Y.G.S. and A.V.A.G.
Department of Chemistry, Institute of Chemical Technology, Nathalal Parekh Road, Mumbai, Matunga 400019, India
Department of Chemistry, Indian Institute of Technology, Bombay, Main Gate Road, Mumbai, Powai 400076, India
Cited By :3
Export Date: 24 May 2021
CODEN: CAAJB
Correspondence Address: Gharpure, S.J.; Department of Chemistry, Main Gate Road, India; email: sjgharpure@chem.iitb.ac.in
Funding details: EMR/ 2016/005439
Funding details: Alexander von Humboldt-Stiftung
Funding details: Department of Science and Technology, Ministry of Science and Technology, India, DST
Funding details: Bangladesh Council of Scientific and Industrial Research, BCSIR, 02(0298)/17/EMR-II
Funding text 1: A.R.K. acknowledges the Alexander von Humboldt Foundation for an equipment grant. A.R.K. also thanks the Science and Educational Research Board (SERB) for a research grant (EMR/ 2016/005439) and the Council for Scientific and Industrial Research (CSIR) through the EMR scheme (02(0298)/17/EMR-II), as well as research fellowships for Y.G.S. and A.V.A.G.
Funding text 2: versity of Mumbai (M.Sc. 2002) and the Uni- versity of York (M.Sc. 2005; Prof. Ian J. S. Fair- lamb). He completed his Ph.D. in 2008 under the supervision of Prof. Fairlamb at the Uni- versity of York, U.K., before undertaking post- doctoral work in the research group of Prof. Lutz Ackermann at the Georg-August Univer- sität Gçttingen as an Alexander von Hum- boldt Fellow. After returning to India in 2010, he was successful in securing the prestigious DST Fast Track fellowship and the DST Inspire faculty award. He is currently an UGC-FRP As- sistant Professor at the Institute of Chemical Technology, Mumbai. The central theme of his research is the application of palladium catalysis for the sustainable synthesis of important heterocyclic molecules, including pharmaceutical drugs, as well as the modification of several bioactive molecules.
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Homogeneous catalysis plays an important and ubiquitous role in the synthesis of simple and complex molecules, including drug compounds, natural products, and agrochemicals. In recent years, the wide-reaching importance of homogeneous catalysis has made it an indispensable tool for the modification of biomolecules, such as carbohydrates (sugars), amino acids, peptides, nucleosides, nucleotides, and steroids. Such a synthetic strategy offers several advantages, which have led to the development of new molecules of biological relevance at a rapid rate relative to the number of available synthetic methods. Given the powerful nature of homogeneous catalysis in effecting these synthetic transformations, this Focus Review has been compiled to highlight these important developments.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Shelke, Yogesh G. </span> <span class="author-type"> </span> ; <span class="author-name" > Yashmeen, Afsana </span> <span class="author-type"> </span> ; <span class="author-name" > Gholap, Aniket V. A. </span> <span class="author-type"> </span> ; <span class="author-name" > Gharpure, Santosh J. </span> <span class="author-type"> </span> ; <span class="author-name" > Kapdi, Anant R. </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;30391897" mtid="30391897" target="_blank">Homogeneous Catalysis: A Powerful Technology for the Modification of Important Biomolecules</a></div> <div class="pub-info"> <span class="journal-title">CHEMISTRY-AN ASIAN JOURNAL</span> <span class="journal-volume">13</span> : <span class="journal-issue">20</span> <span class="page"> pp. 2991-3013. , 23 p. </span> <span class="year">(2018)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1002/asia.201801020" target="_blank" href="https://doi.org/10.1002/asia.201801020"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000447638400003" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000447638400003"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85052839703" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85052839703"> Scopus </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="30063286" target="_blank" href="http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=PubMed&list_uids=30063286&dopt=Abstract"> PubMed </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:30391897 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Összefoglaló cikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list">
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<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Funding Agency and Grant Number: Alexander von Humboldt FoundationAlexander von Humboldt Foundation; Science and Educational Research Board (SERB) [EMR/2016/005439]; Council for Scientific and Industrial Research (CSIR)Council of Scientific & Industrial Research (CSIR) - India [02(0298)/17/EMR-II]
Funding text: A.R.K. acknowledges the Alexander von Humboldt Foundation for an equipme...</pre>
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" mtid="10045482"> <a href="/gui2/?type=authors&mode=browse&sel=10045482" target="_blank">Sipos, Zoltán</a> </span> <span class="author-type"> </span> ; <span class="author-name" mtid="10012084"> <a href="/gui2/?type=authors&mode=browse&sel=10012084" target="_blank">Kónya, Krisztina ✉</a> </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;30322288" mtid="30322288" target="_blank">Synthesis of 1,3-Azol-2-yl O-Heterocycles by Microwave-Irradiation-Assisted Direct C–H Functionalization</a></div> <div class="pub-info"> <span class="journal-title">SYNLETT</span> <span class="journal-volume">29</span> : <span class="journal-issue">18</span> <span class="page"> pp. 2412-2416. , 5 p. </span> <span class="year">(2018)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1055/s-0037-1611012" target="_blank" href="https://doi.org/10.1055/s-0037-1611012"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000448831400013" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000448831400013"> WoS </a> </span> <span class="id identifier oa_CLOSED" title=" Zárt "> <a style="color:blue" title="259327" target="_blank" href="http://hdl.handle.net/2437/259327"> DEA </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85056503125" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85056503125"> Scopus </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611012" target="_blank" href="http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611012"> Egyéb URL </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:30322288 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core">Forrás Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> <div class="publication-citation" style="margin-left: 0.5cm;"> <span title="Nyilvános idézőközlemények összesen, említések nélkül" class="citingPub-count">Nyilvános idéző összesen: 2</span> | Független: 2 | Függő: 0 | Nem jelölt: 0 | WoS jelölt: 2 | Scopus jelölt: 2 | WoS/Scopus jelölt: 2 | DOI jelölt: 2 </div> </div> </div> </div><div class="JournalArticle Publication long-list">
<div class="authors">
<img title="Forrásközlemény" style="float: left" src="/frontend/resources/grid/publication-core-icon.png">
<img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png">
<div class="autype autype0"> <span class="author-name" mtid="10045482"><a
href="/gui2/?type=authors&mode=browse&sel=10045482" target="_blank">Sipos Zoltán
(<span class="authorship-author-name">Sipos Zoltán</span>
<span class="authorAux-mtmt"> Szerves kémia</span>)
</a>
</span>
<span class="author-affil"><span title="Debreceni Egyetem">DE</span>/<span title="Természettudományi és Technológiai Kar">TTK</span>/<span title="Kémiai Intézet">KemI</span>/Szerves Kémiai Tanszék</span>
;
<span class="author-name" mtid="10012084"><a
href="/gui2/?type=authors&mode=browse&sel=10012084" target="_blank">Kónya Krisztina ✉
(<span class="authorship-author-name">Kónya Krisztina</span>
<span class="authorAux-mtmt"> Szerves kémia</span>)
</a>
</span>
<span class="author-affil"><span title="Debreceni Egyetem">DE</span>/<span title="Természettudományi és Technológiai Kar">TTK</span>/<span title="Kémiai Intézet">KemI</span>/Szerves Kémiai Tanszék</span>
</div>
</div>
<div class="title"><a href="/gui2/?mode=browse¶ms=publication;30322288" target="_blank">Synthesis of 1,3-Azol-2-yl O-Heterocycles by Microwave-Irradiation-Assisted Direct C–H Functionalization</a></div> <div> <span class="journal-title">SYNLETT</span>
<span class="journal-issn">(<a target="_blank" href="https://portal.issn.org/resource/ISSN/0936-5214">0936-5214</a> <a target="_blank" href="https://portal.issn.org/resource/ISSN/1437-2096">1437-2096</a>)</span>:
<span class="journal-volume">29</span> <span class="journal-issue">18</span>
<span class="page">
pp 2412-2416
</span> <span class="year">(2018)</span>
</div>
<div class="pub-footer">
<span class="language" xmlns="http://www.w3.org/1999/html">Nyelv:
Angol
| </span>
<span class="identifiers">
<span class="id identifier oa_none" title="none">
<a style="color:blue" title="10.1055/s-0037-1611012" target="_blank" href="https://doi.org/10.1055/s-0037-1611012">
DOI
</a>
</span>
<span class="id identifier oa_none" title="none">
<a style="color:blue" title="000448831400013" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000448831400013">
WoS
</a>
</span>
<span class="id identifier oa_CLOSED" title=" Zárt
">
<a style="color:blue" title="259327" target="_blank" href="http://hdl.handle.net/2437/259327">
DEA
</a>
</span>
<span class="id identifier oa_none" title="none">
<a style="color:blue" title="85056503125" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85056503125">
Scopus
</a>
</span>
<span class="id identifier oa_none" title="none">
<a style="color:black" title="http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611012" target="_blank" href="http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611012">
Egyéb URL
</a>
</span>
</span>
<div class="publication-citation" style="margin-left: 0.5cm;">
<span title="Nyilvános idézőközlemények összesen, említések nélkül" class="citingPub-count">Nyilvános idéző összesen: 2</span>
| Független: 2
| Függő: 0
| Nem jelölt: 0
| WoS jelölt: 2
| Scopus jelölt: 2
| WoS/Scopus jelölt: 2
| DOI jelölt: 2
</div>
<div class="publication-citation">
<a target="_blank" href="/api/publication?cond=citations.related;eq;30322288&sort=publishedYear,desc&sort=title">
Idézett közlemények száma: 5
</a>
</div>
<div class="mtid"><span class="long-pub-mtid">Közlemény: 30322288</span>
| <span class="status-data status-VALIDATED"> Egyeztetett
</span>
Forrás Idéző
| <span class="type-subtype">Folyóiratcikk
( Szakcikk
)
</span>
| <span class="pub-category">Tudományos</span>
| <span class="publication-sourceOfData">kézi felvitel</span>
</div>
<div class="funder"> Kémia az életminőség javításáért: stratégiai K+F műhely a Debreceni Egyetemen(GINOP-2.3.2-15-2016-00008) </div>
<div class="lastModified">Utolsó módosítás: 2023.09.19. 19:57 MTMT API (MTMT API user, admin)
</div>
<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Funding Agency and Grant Number: EUEuropean Union (EU); European Development Fund [GINOP-2.3.2-15-2016-00008]
Funding text: This research was financially supported by the EU and co-financed by the European Development Fund under the project GINOP-2.3.2-15-2016-00008.</pre>
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