@book{MTMT:32233757, title = {Interfacial Chemistry of Rocks and Soils. 2nd edition}, url = {https://m2.mtmt.hu/api/publication/32233757}, isbn = {9781003020080}, author = {M. Nagy, Noémi and Kónya, József}, doi = {10.1201/9781003020080}, publisher = {CRC Press - Taylor and Francis Group}, unique-id = {32233757}, year = {2022} } @article{MTMT:32318481, title = {A study of catalyst particles encapsulated inside multiwalled carbon nanotubes on zeolite and montmorillonite}, url = {https://m2.mtmt.hu/api/publication/32318481}, author = {Kadlecikova, Magdalena and Breza, Juraj and Dekan, Julius and Jesenak, Karol and Vanco, Lubomir and Bediova, Katarina}, doi = {10.1016/j.mee.2021.111556}, journal-iso = {MICROELECTRON ENG}, journal = {MICROELECTRONIC ENGINEERING}, volume = {242-243}, unique-id = {32318481}, issn = {0167-9317}, abstract = {Synthesis of carbon nanotubes on zeolite and montmorillonite is presented. Prior to synthesis, minerals were enriched by particles of iron. Synthesis of carbon nanotubes was performed by hot filament chemical vapour deposition using methane as a source of carbon. A high density of carbon nanotubes was observed in the whole volume of zeolite and montmorillonite. Iron containing particles catalysing the formation and growth of carbon nanotubes were visualized at the ends of nanotubes by field-emission scanning electron microscopy in a combined mode of secondary and backscattered electrons. 57Fe Mo center dot ssbauer spectroscopy was employed to find the oxidation state of iron in Fe-montmorillonite before the synthesis of nanotubes and in the structures of nanocomposites after the synthesis. The metallic particles in the structures of nanocomposites at the ends of carbon nanotubes are characterized by Mo center dot ssbauer spectroscopy mainly as ferromagnetic cementite (Fe3C).}, keywords = {CARBON NANOTUBES; zeolite; Montmorillonite Mossbauer spectroscopy}, year = {2021}, eissn = {1873-5568}, orcid-numbers = {Vanco, Lubomir/0000-0003-2268-0425} } @article{MTMT:31745456, title = {Use of silver-bentonite in sorption of chloride and iodide ions}, url = {https://m2.mtmt.hu/api/publication/31745456}, author = {Buzetzky, Dóra and M. Nagy, Noémi and Kónya, József}, doi = {10.1007/s10967-020-07457-2}, journal-iso = {J RADIOANAL NUCL CHEM}, journal = {JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY}, volume = {326}, unique-id = {31745456}, issn = {0236-5731}, abstract = {Ag-bentonite was prepared by ion exchange process to sorb iodide and chloride ions in batch experiments. The modified bentonite was examined with XRF and XRD. 75% of the cation exchange capacity was exchanged by silver ions. It was found that the sorption of chloride ions is an exothermic precipitation process because the solubility decreases with increasing temperature. In the case of iodide sorption, the dissolution of AgI was observed under high concentration of non-radioactive iodide ions, which is well known in analytical chemistry. The phenomenon occurs not only in the bulk aqueous phase but also in the interlayer space of montmorillonite.}, keywords = {Modified bentonite; sorption experiments; Nuclear waste; Nuclear waste; Halogenide ion; Ag -bentonite}, year = {2020}, eissn = {1588-2780}, pages = {1795-1804}, orcid-numbers = {Buzetzky, Dóra/0000-0002-9157-3810} } @inbook{MTMT:31953948, title = {Photo-Fenton Treatment of a Pharmaceutical Industrial Effluent Under Safe pH Conditions}, url = {https://m2.mtmt.hu/api/publication/31953948}, author = {Natividad, Reyna and Mendoza, Arisbeth and Brewer, Sharon E. and Martínez-Vargas, Sandra Luz and Pérez-Mazariego, J. L. and Novoa, Karen Adriana and Gómez-Oliván, Leobardo Manuel and Romero, Rubi}, booktitle = {Non-Steroidal Anti-Inflammatory Drugs in Water}, doi = {10.1007/698_2020_551}, unique-id = {31953948}, year = {2020}, pages = {241-259} } @article{MTMT:30487663, title = {Application of Modified Bentonites for Arsenite (III) Removal from Drinking Water}, url = {https://m2.mtmt.hu/api/publication/30487663}, author = {Buzetzky, Dóra and Tóth, Csilla Noémi and M. Nagy, Noémi and Kónya, József}, doi = {10.3311/PPch.12197}, journal-iso = {PERIOD POLYTECH CHEM ENG}, journal = {PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING}, volume = {63}, unique-id = {30487663}, issn = {0324-5853}, abstract = {Four modified bentonites (La(III), Y(III), Fe(III)) were prepared by ion exchange process to remove arsenite (III) ions from water. The modified bentonites were examined with X-ray fluorescence spectroscopy (XRF) and X-ray diffraction (XRD). The rare earth (REE) and Fe(III) ion content in bentonite was higher than the CEC values obtained by ammonium acetate method related to trivalent ions (2.7 x 10(-4) mol g(-1)). The kinetics, equilibrium time, sorption isotherms and desorption experiments were examined. Lanthanum, yttrium and cerium bentonite can bind similar amount of arsenite(III) ions. Iron-bentonite cannot bind significant amounts of arsenite ions. The active sites and the solubilities of the sorption complex were determined. Arsenite (III) ions sorb in the interlayer space as REEAsO3. The solubility of the arsenite complex was two orders of magnitude smaller than that of the phosphate complex. After desorption the eluted amount of arsenite (III) was 55% related to the sorbed amount of arsenite. The d(001) basal spacing of modified bentonites and that of after sorption and desorption was measured. After the sorption of arsenite ion on lanthanum bentonite, the d(001) basal spacing of montmorillonite was decreased and after desorption an increase in d(001) basal spacing was observed again. Modified bentonites can be used for removing arsenic ions from water.}, keywords = {GROUNDWATER; rare earth; Modified bentonite; arsenite (III); sorption experiments}, year = {2019}, eissn = {1587-3765}, pages = {113-121}, orcid-numbers = {Buzetzky, Dóra/0000-0002-9157-3810} } @article{MTMT:30809316, title = {Structural curiosities of lanthanide (Ln)-modified bentonites analyzed by radioanalytical methods}, url = {https://m2.mtmt.hu/api/publication/30809316}, author = {Kovács, Eszter Mária and Kónya, József and M. Nagy, Noémi}, doi = {10.1007/s10967-019-06765-6}, journal-iso = {J RADIOANAL NUCL CHEM}, journal = {JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY}, volume = {322}, unique-id = {30809316}, issn = {0236-5731}, year = {2019}, eissn = {1588-2780}, pages = {1747-1754}, orcid-numbers = {Kovács, Eszter Mária/0000-0002-3117-2521} } @article{MTMT:30782621, title = {Fe microenvironments in heat treated rare-earth exchanged montmorillonites}, url = {https://m2.mtmt.hu/api/publication/30782621}, author = {Kuzmann, Ernő and Kovács, Eszter Mária and Homonnay, Zoltán and Csákvári, Szabolcs and Klencsár, Zoltán and Kónya, Péter and M. Nagy, Noémi and Kónya, József}, doi = {10.1007/s10751-019-1622-7}, journal-iso = {HYPERFINE INTERACT}, journal = {HYPERFINE INTERACTIONS}, volume = {240}, unique-id = {30782621}, issn = {0304-3843}, abstract = {The rare-earth bentonites were prepared from Ca-bentonite by suspending Ca-bentonite in rare-earth (Ce, La, Y) perchlorate solution. 57Fe Mössbauer spectra of rare earth montmorillonites before heat treatments showed a doublet envelop at room temperature, reflecting dominantly Fe3+ assigned to (cis) octahedral site in the montmorillonite. At the same time, the 80 K spectra of these rare-earth exchanged montmorillonites revealed an additional magnetically split component, too, associated with iron atoms intercalated in the interlayer space. In the case of heat treated samples (250 °C, 360 °C and 500 °C for 4 h), a new doublet component associated with Fe3+ at trans octahedral site, appeared in both the 295 K and 80 K Mössbauer spectra. Powder X-ray diffractometry (XRD) measurements of the heat treated rare earth montmorillonites revealed that a gradual mineral phase transformation of montmorillonite to muscovite occurred upon the applied heat treatments, being consistent with the completing electron magnetic resonance (EMR) and Mössbauer spectroscopy (MS) results.}, year = {2019}, eissn = {1572-9540}, orcid-numbers = {Kuzmann, Ernő/0000-0002-0183-6649; Kovács, Eszter Mária/0000-0002-3117-2521; Homonnay, Zoltán/0000-0001-5299-5394; Klencsár, Zoltán/0000-0003-0175-7024} } @article{MTMT:3208230, title = {Use of La-, Ce-, Y-, Fe- bentonites for Removing Phosphate Ions from Aqueous Media}, url = {https://m2.mtmt.hu/api/publication/3208230}, author = {Buzetzky, Dóra and M. Nagy, Noémi and Kónya, József}, doi = {10.3311/PPch.9871}, journal-iso = {PERIOD POLYTECH CHEM ENG}, journal = {PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING}, volume = {61}, unique-id = {3208230}, issn = {0324-5853}, abstract = {Clays play an important role in the environment. By removing cations and anions either through ion exchange, adsorption and precipitation, or all these combined, they can act as nat - ural decontaminating agents of numerous pollutants. In this study, four modified bentonites (La-, Ce-, Y-, Fe-bentonite) were prepared and characterized, and their phosphate sorption capabilities were measured in batch experiments. Equilibrium times were also examined. The activation energy of the sorp - tion process was calculated. The La- , Ce- and Y-bentonite can bind similar amount of phosphate ions, while iron-bentonite can bind only half of it compared to La-, Ce- and Y-bentonite.}, year = {2017}, eissn = {1587-3765}, pages = {27-32}, orcid-numbers = {Buzetzky, Dóra/0000-0002-9157-3810} } @article{MTMT:3208553, title = {Preparation and structure's analyses of lanthanide (Ln) -exchanged bentonites}, url = {https://m2.mtmt.hu/api/publication/3208553}, author = {Kovács, Eszter Mária and Baradács, Eszter and Kónya, Péter and Kovács-Pálffy, P and Harangi, Sándor and Kuzmann, Ernő and Kónya, József and M. Nagy, Noémi}, doi = {10.1016/j.colsurfa.2017.02.085}, journal-iso = {COLLOID SURFACE A}, journal = {COLLOIDS AND SURFACES A : PHYSICOCHEMICAL AND ENGINEERING ASPECTS}, volume = {522}, unique-id = {3208553}, issn = {0927-7757}, abstract = {The interaction between Lanthanides (Ln)- ions and Ca-bentonite and the structural changes accompanying were studied. Ln-exchanged bentonites were prepared from Ca-bentonite (Istenmezeje, Hungary) by ion exchange in three consecutive washings with lanthanide solutions. Scanning Eletronmicroscopy Energy Dispersive X-ray spectroscopy (SEM-EDX) studies showed even distribution of Lns and other components of bentonite. The natural bentonite and the lanthnide exchanged bentonites were characterized by X-ray diffraction (XRD), which revealed the same mineral composition, and the increase of the basal spacing of montmorillonite from 1.465 (Ca2+) to 1.577 nm (REE3+). The d001 basal spacing of lanthanide montmorillonite increases as the ion radius of the lanthanide cation increases. The Fe3+, and Lns3+ amount on the bentonite were determined by X-ray-fluorescence spectrometry (XRF) elemental analysis. The amount of exchanged Lns were determined by washing the Ln-bentonite with 1 M ammonium-acetate, and measuring the amount of Ln released, using inductively coupled plasma optical emission spectrometry (ICP-OES). In most Ln-bentonites, the quantity of the exchanged Ln ions was about 80–90% of the cation exchange capacity (CEC) of the bentonite. In case of some lanthanides bentonite (La3+, Ce3+, and Gd3+), however, the sorbed quantity of lanthanum ions was higher than the cation exchange capacity. In case of lanthanum-bentonite, the lanthanide quantity is as high as 136% of CEC. Moreover, the iron(III) content of lanthanum bentonite is less than that of the original Ca-bentonite. Mössbauer spectra of the La-, Ce-, and Gd-exchanged samples at 78 K revealed an unexpected magnetically split component that was absent from the Ca-bentonite. This component may belong to interlayer Fe. This iron can be released from the octahedral positions crystal lattice. © 2017 Elsevier B.V.}, keywords = {WATER; X-ray diffraction; scanning electron microscopy; MONTMORILLONITE; TURKEY; CENTRAL ANATOLIA; CLAY-MINERALS; kaolinite; sorption; Earth; GENESIS; Inductively coupled plasma optical emission spectrometry; X-ray-fluorescence spectrometry; Complexometric titration; Ln-bentonites}, year = {2017}, eissn = {1873-4359}, pages = {287-294}, orcid-numbers = {Kovács, Eszter Mária/0000-0002-3117-2521; Kuzmann, Ernő/0000-0002-0183-6649} } @article{MTMT:3225767, title = {Ioncsere-folyamatok az agyagásványok "nanolaboratóriumában"}, url = {https://m2.mtmt.hu/api/publication/3225767}, author = {M. Nagy, Noémi}, doi = {10.24100/MKF.2017.01.25}, journal-iso = {MAGY KÉM FOLY KÉM KÖZL}, journal = {MAGYAR KÉMIAI FOLYÓIRAT - KÉMIAI KÖZLEMÉNYEK (1997-)}, volume = {123}, unique-id = {3225767}, issn = {1418-9933}, year = {2017}, eissn = {1418-8600}, pages = {25-31} } @article{MTMT:3097530, title = {Mössbauer study of pH dependence of iron-intercalation in montmorillonite}, url = {https://m2.mtmt.hu/api/publication/3097530}, author = {Kuzmann, Ernő and Garg, VK and Singh, H and de Oliveira, AC and Pati, SS and Homonnay, Zoltán and Rudolf, M and Molnár, ÁM and Kovács, Eszter Mária and Baranyai, Edina and Kubuki, S and M. Nagy, Noémi and Kónya, József}, doi = {10.1007/s10751-016-1314-5}, journal-iso = {HYPERFINE INTERACT}, journal = {HYPERFINE INTERACTIONS}, volume = {237}, unique-id = {3097530}, issn = {0304-3843}, abstract = {57Fe Mössbauer spectroscopy and XRD have successfully been applied to show the incorporation of Fe ion into the interlayer space of montmorillonite via treatment with FeCl 3 in acetone. The 78K 57Fe Mössbauer spectra of montmorillonite samples reflected magnetically split spectrum part indicating the intercalation of iron into the interlayer of montmorillonite via the treatment with FeCl 3+acetone and washed with water until the initial pH=2.3 increased to pH=4.14. It was found that the occurrence of intercalated iron in the form of oxide-oxihydroxide in montmorillonite increases with the pH. Intercalation was confirmed by the gradual increase in the basal spacing d001 with pH. © 2016, Springer International Publishing Switzerland.}, keywords = {pH dependence; Ca-montmorillonite; 57Fe Mössbauer spectroscopy; Interlayer Fe}, year = {2016}, eissn = {1572-9540}, orcid-numbers = {Kuzmann, Ernő/0000-0002-0183-6649; Homonnay, Zoltán/0000-0001-5299-5394; Kovács, Eszter Mária/0000-0002-3117-2521} }