@article{MTMT:34540946, title = {Solvent-targeted recovery of all major materials in beverage carton packaging waste}, url = {https://m2.mtmt.hu/api/publication/34540946}, author = {Wong, P.K. and Lui, Y.W. and Tao, Q. and Lui, M.Y.}, doi = {10.1016/j.resconrec.2023.107367}, journal-iso = {RESOUR CONSERV RECY}, journal = {RESOURCES CONSERVATION AND RECYCLING}, volume = {202}, unique-id = {34540946}, issn = {0921-3449}, year = {2024}, eissn = {1879-0658} } @article{MTMT:33868682, title = {Some Insights into the Use of Heterogeneous Copper Catalysts in the Hydroprocessing of Levulinic Acid}, url = {https://m2.mtmt.hu/api/publication/33868682}, author = {Cavuoto, Denise and Ardemani, Leandro and Ravasio, Nicoletta and Zaccheria, Federica and Scotti, Nicola}, doi = {10.3390/catal13040697}, journal-iso = {CATALYSTS}, journal = {CATALYSTS}, volume = {13}, unique-id = {33868682}, abstract = {Levulinic acid and its esters are close to being extensively produced through consolidated industrial processes, thus playing a central role in biobased industries producing commodities within the principles of the circular economy. One of the main pathways of levulinic acid and ester valorization is their transformation with hydrogen to obtain ?-valerolactone, valeric esters, 1,4-pentanediol and 2-methyl tetrahydrofuran. These reactions are catalyzed by noble and non-noble metal-based heterogeneous catalysts. The use of an abundant and non-toxic element, such as copper, is advantageous with respect to expensive or harmful metals, such as Rh, Ru, Pt or Ni. In this critical review, we wish to give a deeper insight into research advancements in the last ten years regarding the processing of levulinic acid and its esters with hydrogen using heterogeneous copper catalysts.}, keywords = {levulinic acid; 1,4-PENTANEDIOL; 2-methyl tetrahydrofuran; ?-valerolactone; heterogeneous copper catalysts; valeric esters}, year = {2023}, eissn = {2073-4344} } @article{MTMT:34202740, title = {Valorization of the Exoskeletons of Crustaceans in Seafood Wastes to Chemicals in Renewable Solvents: A Catalytic and Mechanistic Study}, url = {https://m2.mtmt.hu/api/publication/34202740}, author = {Horváth, István Tamás and Wong, Claire Yuet Yan and Choi, Alex Wing-Tat and Mika, László Tamás and Lui, Matthew Y.}, doi = {10.1021/acssuschemeng.3c04066}, journal-iso = {ACS SUSTAIN CHEM ENG}, journal = {ACS SUSTAINABLE CHEMISTRY & ENGINEERING}, volume = {11}, unique-id = {34202740}, issn = {2168-0485}, year = {2023}, eissn = {2168-0485}, pages = {15350-15363}, orcid-numbers = {Horváth, István Tamás/0000-0002-6324-186X; Lui, Matthew Y./0000-0003-2201-3956} } @article{MTMT:34540917, title = {Intensifying levulinic acid hydrogenation using mechanochemically prepared copper on manganese oxide catalysts}, url = {https://m2.mtmt.hu/api/publication/34540917}, author = {Mazumdar, Nayan Jyoti and Kumar, Praveen and Arredondo-Arechavala, Miryam and Artioli, Nancy and Manyar, Haresh}, doi = {10.1016/j.cej.2023.147479}, journal-iso = {CHEM ENG J}, journal = {CHEMICAL ENGINEERING JOURNAL}, volume = {478}, unique-id = {34540917}, issn = {1385-8947}, year = {2023}, eissn = {1873-3212}, orcid-numbers = {Mazumdar, Nayan Jyoti/0000-0003-0158-8400; Artioli, Nancy/0000-0002-3747-474X; Manyar, Haresh/0000-0002-7990-4410} } @article{MTMT:33789300, title = {Thermal hazard evaluation for γ-valerolactone production by using formic acid as hydrogen donor}, url = {https://m2.mtmt.hu/api/publication/33789300}, author = {Pan, Y. and Ren, C. and Wang, G. and Wang, Y. and Zhang, X. and Jiang, J. and Shu, C.-M.}, doi = {10.1016/j.jlp.2022.104951}, journal-iso = {J LOSS PREVENT PROC}, journal = {JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES}, volume = {81}, unique-id = {33789300}, issn = {0950-4230}, year = {2023}, eissn = {1873-3352} } @article{MTMT:33899032, title = {Thermal Stability for the Continuous Production of gamma-Valerolactone from the Hydrogenation of N-Butyl Levulinate in a CSTR}, url = {https://m2.mtmt.hu/api/publication/33899032}, author = {Salcedo, Wenel Naudy Vasquez and Renou, Bruno and Leveneur, Sebastien}, doi = {10.3390/pr11010237}, journal-iso = {PROCESSES}, journal = {PROCESSES}, volume = {11}, unique-id = {33899032}, issn = {2227-9717}, abstract = {gamma-valerolactone can be a game-changer in the chemical industry because it could substitute fossil feedstocks in different fields. Its production is from the hydrogenation of levulinic acid or alkyl levulinates and can present some risk of thermal runaway. To the best of our knowledge, no studies evaluate the thermal stability of this production in a continuous reactor. We simulated the thermal behavior of the hydrogenation of butyl levulinate over Ru/C in a continuous stirred-tank reactor and performed a sensitivity analysis. The kinetic and thermodynamic constants from Wang et al.'s articles were used. We found that the risk of thermal stability is low for this chemical system.}, keywords = {simulation; HYDROGENATION; thermal stability; GVL}, year = {2023}, eissn = {2227-9717} } @article{MTMT:33811528, title = {Novel Eco-friendly, One-Pot Method for the Synthesis of Kynurenic Acid Ethyl Esters}, url = {https://m2.mtmt.hu/api/publication/33811528}, author = {Simon, Péter and Lőrinczi, Bálint and Hetényi, Anasztázia and Szatmári, István}, doi = {10.1021/acsomega.3c01170}, journal-iso = {ACS OMEGA}, journal = {ACS OMEGA}, volume = {8}, unique-id = {33811528}, issn = {2470-1343}, year = {2023}, eissn = {2470-1343}, pages = {17966-17975}, orcid-numbers = {Lőrinczi, Bálint/0000-0001-7773-0034; Hetényi, Anasztázia/0000-0001-8080-6992; Szatmári, István/0000-0002-8571-5229} } @article{MTMT:32706976, title = {Liquid–Liquid Equilibria of Ternary Mixtures Containing n -Tetradecane + γ-Valerolactone + Aldehyde [Butanal or Pentanal or ( E )-2-Undecenal] at 298.15 K}, url = {https://m2.mtmt.hu/api/publication/32706976}, author = {Dantas, Carlos E. S. and Ceriani, Roberta}, doi = {10.1021/acs.jced.1c00688}, journal-iso = {J CHEM ENG DATA}, journal = {JOURNAL OF CHEMICAL AND ENGINEERING DATA}, volume = {67}, unique-id = {32706976}, issn = {0021-9568}, year = {2022}, eissn = {1520-5134}, pages = {393-403}, orcid-numbers = {Dantas, Carlos E. S./0000-0003-4384-8098; Ceriani, Roberta/0000-0001-8490-4960} } @article{MTMT:33789304, title = {Chemical transformations of 5-hydroxymethylfurfural into highly added value products: present and future}, url = {https://m2.mtmt.hu/api/publication/33789304}, author = {Jiang, Z. and Zeng, Y. and Hu, D. and Guo, R. and Yan, K. and Luque, R.}, doi = {10.1039/d2gc03444a}, journal-iso = {GREEN CHEM}, journal = {GREEN CHEMISTRY}, volume = {25}, unique-id = {33789304}, issn = {1463-9262}, year = {2022}, eissn = {1463-9270}, pages = {871-892} } @article{MTMT:32974079, title = {Probing the mechanism of the conversion of methyl levulinate into gamma-valerolactone catalyzed by Al(OiPr)(3) in an alcohol solvent: a DFT study}, url = {https://m2.mtmt.hu/api/publication/32974079}, author = {Ju, Zhaoyang and Feng, Shaokeng and Ren, Lanhui and Lei, Tingyu and Cheng, Haixiang and Yu, Mengting and Ge, Chengsheng}, doi = {10.1039/d1ra08429a}, journal-iso = {RSC ADV}, journal = {RSC ADVANCES}, volume = {12}, unique-id = {32974079}, issn = {2046-2069}, abstract = {Biomass-derived gamma-valerolactone (GVL) is a versatile chemical that can be used in various fields. As an efficient, cheap, and sustainable catalyst, Al(OiPr)(3) has been successfully used in the conversion of methyl levulinate (ML) to GVL in the solvent isopropanol (IPA). However, the molecular mechanism of this conversion catalyzed by Al(OiPr)(3) remains ambiguous. To investigate the mechanism of the conversion of ML to GVL catalyzed by Al(OiPr)(3), the reaction pathways, including the transesterification, Meerwein-Ponndorf-Verley (MPV) hydrogenation, and ring-closure steps, were probed using density functional theory (DFT) calculations at the M062X-D3/def2-TZVP level. Among the elementary steps, it is found that ring-closure is the rate-determining step and that Al3+ can coordinate with the oxygen of 2-hydroxy-isopropyl levulinate (2HIPL) to catalyze the last ring-closure step. A four-centered transition state can be formed, and Al(OiPr)(3) shows a strong catalytic effect in the two steps of the ester exchange reaction. The center of Al(OiPr)(3) mainly coordinates with the carbonyl oxygen atom of the ester to catalyze the reaction. The present study provides some help in understanding the conversion mechanism of ML to GVL and designing more effective catalysts for use in biomass conversion chemistry.}, year = {2022}, eissn = {2046-2069}, pages = {2788-2797} } @article{MTMT:32777729, title = {Understanding the Interactions between Triolein and Cosolvent Binary Mixtures Using Molecular Dynamics Simulations}, url = {https://m2.mtmt.hu/api/publication/32777729}, author = {Nyepetsi, Maipelo and Mbaiwa, Foster and Oyetunji, Olayinka A. and de Leeuw, Nora H.}, doi = {10.1021/acsomega.1c06762}, journal-iso = {ACS OMEGA}, journal = {ACS OMEGA}, volume = {7}, unique-id = {32777729}, issn = {2470-1343}, year = {2022}, eissn = {2470-1343}, pages = {10212-10224}, orcid-numbers = {Nyepetsi, Maipelo/0000-0001-5537-5916; Mbaiwa, Foster/0000-0001-6727-4733; Oyetunji, Olayinka A./0000-0001-8670-1104; de Leeuw, Nora H./0000-0002-8271-0545} } @article{MTMT:32687787, title = {Cationic Ru complexes anchored on POM via non-covalent interaction towards efficient transfer hydrogenation catalysis}, url = {https://m2.mtmt.hu/api/publication/32687787}, author = {Peng, Q. and Zhao, X. and Chen, M. and Wang, J. and Cui, K. and Wei, X. and Hou, Z.}, doi = {10.1016/j.mcat.2021.112049}, journal-iso = {MOL CATAL}, journal = {MOLECULAR CATALYSIS}, volume = {517}, unique-id = {32687787}, issn = {2468-8231}, abstract = {The ionic materials consisting of cationic Ru complexes and Wells-Dawson polyoxometalate anion (POM, K6P2W18O62) have been constructed via a non-covalent interaction. The as-synthesized catalysts have been characterized thoroughly by NMR, XRD, FESEM, and FT-IR, etc. The characterization suggested that a hydrogen bond interaction occurred between the proton of the amine ligand in the cationic Ru complexes and the oxygen atom of the POM anion. The hydrogen bond played an important role in enhancing catalytic activity for the transfer hydrogenation of methyl levulinate (ML) to γ-valerolactone (GVL) under very mild conditions. Especially, the transfer hydrogenation reaction proceeded via a heterogeneous catalysis approach and the heterogenized catalysts even afforded much better catalytic performance than homogeneous analogs. Notably, the catalysts can be recycled without an obvious loss of activity, and further extended to highly selective transfer hydrogenation of α,β-unsaturated ketones and aldehydes, etc. into the corresponding α,β-unsaturated alcohols without any base external additives. The high catalytic performance of these anchored catalysts was highly related to the hydrogen bond interaction and the basicity of the polyanion. The obtained knowledge from this work could lead us to a new catalysis concept of tethering active homogeneous complexes for constructing highly active anchored Ru complex catalysts for hydrogenation reaction. © 2021 Elsevier B.V.}, keywords = {COMPLEXATION; CATALYSIS; ALCOHOLS; HYDROGENATION; Oxides; ADDITIVES; KETONES; transfer hydrogenation; Synthesis (chemical); Catalyst activity; Hydrogen bonds; Ruthenium compounds; Hydrogenation reactions; Non-covalent interaction; Ru complex; polyoxometalates; hydrogenation catalysis; Polyoxometalate; Hydrogen bond interaction; Hydrogen bond interaction; Transfer hydrogenations; ]+ catalyst; Cationics; Ru complexes; Anchored catalysts; Anchored catalyst}, year = {2022}, eissn = {2468-8274} } @article{MTMT:33237728, title = {Lattice Expansion and Electronic Reconfiguration of MnCu Oxide Catalysts for Enhanced Transfer Hydrogenation of Levulinate}, url = {https://m2.mtmt.hu/api/publication/33237728}, author = {Yu, Xiao and Liu, Jiefeng and Ru, Changlong and Cai, Shiyu and Wang, Jinyao and Liu, Mengyuan and Zhang, Dongpei and Shen, Jian and Jin, Xin and Yang, Chaohe}, doi = {10.1021/acssuschemeng.2c03644}, journal-iso = {ACS SUSTAIN CHEM ENG}, journal = {ACS SUSTAINABLE CHEMISTRY & ENGINEERING}, volume = {10}, unique-id = {33237728}, issn = {2168-0485}, abstract = {Lattice-strained metal oxides often display enhanced catalytic activity and selectivity on activation of C-H, C=C, C=O, and O-H bonds in bio-oxygenates. However, limited experimental studies have been conducted on the structure sensitivity for tandem reactions, particularly on complicated surface redox chemical chain reactions over strained oxide materials. In this work, we employed transfer hydrogenation of levulinate as a representative example to illustrate how lattice strain affects tandem oxidation (dehydrogen-ation, C-H/O-H bond cleavage) and reduction (hydrogenation, C=O bond saturation) reactions. The key finding is that lattice strain at MnOx-CuOx boundaries within bimetallic MnCu oxides leads to a highly unsymmetrical strain across the interface and lattice distortion. Such unique behaviors further induce the Jahn-Teller effect for electronic reconfiguration and field split for Mn 3d orbitals. Thus, tandem H2 generation and hydrogenation of levulinate to valerolactone can occur much more efficiently with a fivefold enhancement over monometallic oxide catalysts. Detailed characterization of fresh and sintered catalyst samples further demonstrated the critical role of expansion of the Mn-O facet and phase segregation in facilitated chemical chain reactions. The design principles discussed in this work could be potentially applied for other non-noble oxide catalysts in energy and environmental fields.}, keywords = {transfer hydrogenation; Lattice strain; metal oxide; Ethyl levulinate}, year = {2022}, eissn = {2168-0485}, pages = {13402-13414} } @article{MTMT:32304401, title = {Bimetallic Ni-Co/gamma-Al2O3 catalyst for vapour phase production of gamma-valerolactone: Deactivation studies and feedstock selection}, url = {https://m2.mtmt.hu/api/publication/32304401}, author = {Kondeboina, Murali and Enumula, Siva Sankar and Reddy, K. Saidulu and Challa, Prathap and Burri, David Raju and Kamaraju, Seetha Rama Rao}, doi = {10.1016/j.fuel.2020.119094}, journal-iso = {FUEL}, journal = {FUEL}, volume = {285}, unique-id = {32304401}, issn = {0016-2361}, abstract = {With an aim to establish supported non-noble Co metal catalysts for production of a promising fuel and fuel additive gamma-valerolactone (GVL) at ambient pressure in continuous mode, Co/gamma-Al2O3 and bimetallic Ni-Co/gamma-Al2O3 catalysts were prepared and their catalytic activities vs. catalytic features were correlated. Ni-Co/gamma-Al2O3 catalyst exhibited GVL productivity of 1.125 kg(GVL).kg(catalyst)(-1)h(-1) which is relatively higher than Co/gamma-Al2O3 catalyst. Ni-Co/gamma-Al2O3 catalyst is stable during 12 h time-on-stream studies while Co/gamma-Al2O3 catalyst suffers from deactivation. The addition of Ni to Co/gamma-Al2O3 augments the resultant bimetallic catalyst activity and coke resistance capacity. As evidenced from XRD, H-2-TPR, XPS analyses the addition of Ni to Co/gamma-Al2O3 results in formation of Ni-Co alloy in the bimetallic catalysts. H(2)pulse chemisorption studies and TEM analyses illustrate formation of smaller particles in bimetallic Ni-Co/gamma-Al2O3 catalyst which in turn influenced the rate of formation of GVL. From TGA of spent catalysts, the carbon deposition rate is found to be decreased in the case of Ni-Co/gamma-Al2O3 catalyst (0.43 mmol.g(cat)(-1).h(-1)) than Co/gamma-Al2O3 catalyst (1.014 mmol.(-1)(gcat).h(-1)). Among the feedstocks of GVL i.e. levulinic acid, methyl levulinate, ethyl levulinate, ethyl levulinate is found to be prominent in constantly yielding GVL during 24 h study over bimetallic Ni-Co/gamma-Al2O3 catalyst.}, keywords = {HYDROGENATION; GAMMA-VALEROLACTONE; levulinic acid; GAMMA-AL2O3; Ni-Co}, year = {2021}, eissn = {1873-7153} } @article{MTMT:32304080, title = {Transformation of bio-derived levulinic acid to gamma-valerolactone by cyclopentadienone ruthenium(0) catalyst precursors bearing simple supporting ligands}, url = {https://m2.mtmt.hu/api/publication/32304080}, author = {Ngumbu, Denis M. and Kapfunde, Tsitsi A. and Oklu, Novisi K. and Makhubela, Banothile C. E.}, doi = {10.1002/aoc.6243}, journal-iso = {APPL ORGANOMET CHEM}, journal = {APPLIED ORGANOMETALLIC CHEMISTRY}, volume = {35}, unique-id = {32304080}, issn = {0268-2605}, abstract = {Hydrogenation of bio-based levulinic acid (LA) to gamma-valerolactone (GVL) was carried out using new cyclopentadienone ruthenium(0) complexes as catalyst precursors. These new complexes were obtained by reaction of cyclopentadione ruthenium(0) with widely available amino, pyridyl and phosphino ligands (L1-L6) using bridging N-N, P-N, or monodentate P or N donor frameworks. The hydrogenation reactions proceeded efficiently using formic acid as a hydrogen source and a low catalyst loading (0.2 mol%) in a benign solvent. At 120 degrees C, up to 1,882 TON and >99% LA conversions and selectivities to GVL were seen, and the catalysts could be recycled up to four times with consistent activity and selectivity. In situ NMR studies show that hydrogen gas was generated from formic acid decomposition with simultaneous release of carbon dioxide. Ru-hydride species have been detected, by H-1 NMR spectroscopy, and the structure of the active catalyst is proposed along with a plausible reaction pathway.}, keywords = {HYDROGENATION; levulinic acid; formic acid; valerolactone; gamma‐; ruthenium(0) catalyst precursors}, year = {2021}, eissn = {1099-0739} } @article{MTMT:32304381, title = {Influence of metal oxide and heteropoly tungstate location in mesoporous silica towards catalytic transfer hydrogenation of furfural to gamma-valerolactone}, url = {https://m2.mtmt.hu/api/publication/32304381}, author = {Srinivasa Rao, B. and Yogita and Dhana Lakshmi, D. and Kumari, P. Krishna and Lingaiah, N.}, doi = {10.1039/d1se00340b}, journal-iso = {SUSTAIN ENERG FUELS}, journal = {SUSTAINABLE ENERGY & FUELS}, volume = {5}, unique-id = {32304381}, issn = {2398-4902}, abstract = {One pot conversion of furfural to gamma-valerolactone by transfer hydrogenation has been achieved over bifunctional mesoporous silica catalysts containing Zr and tungstophosphoric acid (TPA). Different catalysts with TPA and ZrO2 located inside and outside of SBA-15 pores were prepared and their activity was evaluated for transfer hydrogenation of furfural. Different characterization techniques such as N-2-sorption, FT-IR, pyridine/2-propanol adsorbed FT-IR, X-ray diffraction, temperature programmed desorption of NH3/CO2, electron spectroscopy for chemical analysis and TEM were used to evaluate the structural and surface aspects of the catalysts. The presence of ZrO2 inside and outside the pore channels of SBA-15 was identified by XPS analysis as a higher binding energy value was observed for Zr 3d(5/2) of the catalyst with ZrO2 present inside the pores of SBA-15 due to the formation of Si-O-Zr bonds. The catalyst with ZrO2 present inside the SBA-15 pores and TPA dispersed on the support showed the highest activity with complete conversion of furfural and a GVL yield of 81%. The transfer hydrogenation activity depends on the interaction of the hydrogenating alcohol and the acid-base properties of the catalyst which are directed by the location of ZrO2 or TPA in the support. All the reaction parameters were studied and the optimum conditions were established. The catalyst exhibited good recyclability without any variation in activity.}, year = {2021}, eissn = {2398-4902}, pages = {3719-3728} } @article{MTMT:31340125, title = {Isobaric Vapor–Liquid Equilibria for Binary Mixtures of Biomass-Derived γ-Valerolactone + Tetrahydrofuran and 2-Methyltetrahydrofuran}, url = {https://m2.mtmt.hu/api/publication/31340125}, author = {AL-LAMI, MUNAF ADNAN IDAN and Havasi, Dávid and Batha, Bálint and Pusztai, Éva and Mika, László Tamás}, doi = {10.1021/acs.jced.0c00084}, journal-iso = {J CHEM ENG DATA}, journal = {JOURNAL OF CHEMICAL AND ENGINEERING DATA}, volume = {65}, unique-id = {31340125}, issn = {0021-9568}, year = {2020}, eissn = {1520-5134}, pages = {3063-3071}, orcid-numbers = {Havasi, Dávid/0000-0003-3366-4009} } @article{MTMT:31423101, title = {Ni Supported on Natural Clays as a Catalyst for the Transformation of Levulinic Acid into gamma-Valerolactone without the Addition of Molecular Hydrogen}, url = {https://m2.mtmt.hu/api/publication/31423101}, author = {Garcia, Adrian and Sanchis, Rut and Llopis, Francisco J. and Vazquez, Isabel and Pico, Maria Pilar and Lopez, Maria Luisa and alvarez-Serrano, Inmaculada and Solsona, Benjamin}, doi = {10.3390/en13133448}, journal-iso = {ENERGIES}, journal = {ENERGIES}, volume = {13}, unique-id = {31423101}, issn = {1996-1073}, abstract = {gamma-Valerolactone (GVL) is a valuable chemical that can be used as a clean additive for automotive fuels. This compound can be produced from biomass-derived compounds. Levulinic acid (LA) is a compound that can be obtained easily from biomass and it can be transformed into GVL by dehydration and hydrogenation using metallic catalysts. In this work, catalysts of Ni (a non-noble metal) supported on a series of natural and low-cost clay-materials have been tested in the transformation of LA into GVL. Catalysts were prepared by a modified wet impregnation method using oxalic acid trying to facilitate a suitable metal dispersion. The supports employed are attapulgite and two sepiolites with different surface areas. Reaction tests have been undertaken using an aqueous medium at moderate reaction temperatures of 120 and 180 degrees C. Three types of experiments were undertaken: (i) without H(2)source, (ii) using formic acid (FA) as hydrogen source and (iii) using Zn in order to transform water in hydrogen through the reaction Zn + H2O -> ZnO + H-2. The best results have been obtained combining Zn (which plays a double role as a reactant for hydrogen formation and as a catalyst) and Ni/attapulgite. Yields to GVL higher than 98% have been obtained at 180 degrees C in the best cases. The best catalytic performance has been related to the presence of tiny Ni particles as nickel crystallites larger than 4 nm were not present in the most efficient catalysts.}, keywords = {GAMMA-VALEROLACTONE; levulinic acid; Sepiolite; Attapulgite; hydrogen from water; Zn: Ni}, year = {2020}, eissn = {1996-1073} } @article{MTMT:31485910, title = {Dual acidic mesoporous KIT silicates enable one-pot production of gamma-valerolactone from biomass derivatives via cascade reactions}, url = {https://m2.mtmt.hu/api/publication/31485910}, author = {He, Jian and Li, Hu and Xu, Yufei and Yang, Song}, doi = {10.1016/j.renene.2019.06.105}, journal-iso = {RENEW ENERGY}, journal = {RENEWABLE ENERGY}, volume = {146}, unique-id = {31485910}, issn = {0960-1481}, abstract = {gamma-Valerolactone (GVL) is an interesting bio-based platform molecule that is utilized as green solvent and a versatile building block for the synthesis of bio-fuels and chemicals. Herein, an investigation on the efficient production of GVL from biomass-based carbonyl compounds such as furfural, levulinic acid, and its esters using 2-propanol as H-donor and solvent over stable Zr-incorporated mesoporous silica (KIT-5) catalysts was presented. Both Lewis and Bronsted acid sites were generated by the introduction of Zr into KIT-5, and the acid density of the resulting Zr-KIT-5(Si/Zr) could be controlled by simply adjusting Si/Zr molar ratio. Among these bifunctional catalysts, Zr-KIT-5(10) showed superior catalytic performance in the production of GVL (>91% selectivity) from biomass-derived carboxides (ca. 94% conversion), which was demonstrated to positively correlate with its large amount of acidic sites and facile access of active sites to interconnected pores. Moreover, the spent catalyst held about 90% of its original activity in the sixth run. Due to the presence of Bronsted and Lewis dual acidic sites in Zr-KIT-5, the direct conversion of furfural to GVL was also permitted in a single pot via tandem reactions involving hydrogenation, ring-opening, secondary hydrogenation, and subsequent cyclization. (C) 2019 Elsevier Ltd. All rights reserved.}, keywords = {GAMMA-VALEROLACTONE; transfer hydrogenation; BIOMASS CONVERSION; Furfural; Mesoporous silicate}, year = {2020}, eissn = {1879-0682}, pages = {359-370}, orcid-numbers = {Yang, Song/0000-0003-1301-3030} } @article{MTMT:33544340, title = {Molecular dynamics and density functional theory studies of gamma-butyrolactone (GBL) plus ethanol and gamma-valerolactone (GVL) plus ethanol liquid mixtures}, url = {https://m2.mtmt.hu/api/publication/33544340}, author = {Mbaiwa, F and Nyepetsi, M}, doi = {10.1016/j.molliq.2020.114128}, journal-iso = {J MOL LIQ}, journal = {JOURNAL OF MOLECULAR LIQUIDS}, volume = {319}, unique-id = {33544340}, issn = {0167-7322}, abstract = {gamma-Butyrolactone (GBL) and gamma-valerolactone (GVL) are two of the lactones with wide application in industry. The interactions of these two lactones with alcohols have been a subject of experimental research. This article reports the theoretical investigation of GBLiethanol and GVL/ethanol mixtures throughout the entire composition range using molecular dynamics and ab initio calculations. Molecular dynamics simulation using the optimized potentials for liquid simulations force field reproduces the experimental thermodynamics results quite wellinvestigation of the liquid structure show that ethanol interacts with GBL and GVL molecules at specific sites, namely, almost collinearly with the lactone C=O bond, below and above the lactone ring plane, and between the C-C ring bonds of the lactone. While ab initio calculations largely support the interaction of ethanol with the lactones via O-H-O hydrogen bonds, hydrogen boding via lactone C-H and ethanol O dearly have a significant role as well. The O-H-O interactions are dominated by the carbonyl oxygen. Dispersion interactions seem to play a more important role in stabilizing those interactions in which the hydrogen bonding is via the lactone ring oxygen. Generally, the two lactones behave very similarly in both liquid and gas phase studies, with minor differences attributed to more steric hindrance due the methyl group in gamma-valerolactone. (C) 2020 Elsevier B.V. All rights reserved.}, year = {2020}, eissn = {1873-3166} } @article{MTMT:31293862, title = {Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment}, url = {https://m2.mtmt.hu/api/publication/31293862}, author = {van Slagmaat, Christian A. M. R. and Delgove, Marie A. F. and Stouten, Jules and Morick, Lukas and van der Meer, Yvonne and Bernaerts, Katrien V. and De Wildeman, Stefaan M. A.}, doi = {10.1039/C9GC02088H}, journal-iso = {GREEN CHEM}, journal = {GREEN CHEMISTRY}, volume = {22}, unique-id = {31293862}, issn = {1463-9262}, year = {2020}, eissn = {1463-9270}, pages = {2443-2458} } @article{MTMT:34780281, title = {Non-noble metal catalysts for transfer hydrogenation of levulinic acid: The role of surface morphology and acid-base pairs}, url = {https://m2.mtmt.hu/api/publication/34780281}, author = {Wang, J. and Liu, J. and Yu, X. and Zhang, W. and Zhang, G. and Liu, M. and Shen, J. and Yang, C. and Jin, X.}, doi = {10.1016/j.mtener.2020.100501}, journal-iso = {MATER TODAY ENERG}, journal = {MATERIALS TODAY ENERGY}, volume = {18}, unique-id = {34780281}, issn = {2468-6069}, year = {2020}, eissn = {2468-6069} } @article{MTMT:31485912, title = {Lattice distorted MnCo oxide materials as efficient catalysts for transfer hydrogenation of levulinic acid using formic acid as H -donor}, url = {https://m2.mtmt.hu/api/publication/31485912}, author = {Wang, Jinyao and Zhang, Guangyu and Liu, Mengyuan and Xia, Qi and Yu, Xiao and Zhang, Wenxiang and Shen, Jian and Yang, Chaohe and Jin, Xin}, doi = {10.1016/j.ces.2020.115721}, journal-iso = {CHEM ENG SCI}, journal = {CHEMICAL ENGINEERING SCIENCE}, volume = {222}, unique-id = {31485912}, issn = {0009-2509}, year = {2020}, eissn = {1873-4405}, orcid-numbers = {Wang, Jinyao/0000-0002-0508-275X} } @article{MTMT:31799865, title = {Catalytic Transfer Hydrogenation of Biomass-derived Levulinates to γ- valerolactone Using Alcohols as H-donors}, url = {https://m2.mtmt.hu/api/publication/31799865}, author = {Xu, Yufei and Zhang, Heng and Li, Hu and Yang, Song}, doi = {10.2174/2213346107666200129104358}, journal-iso = {CURR GREEN CHEM}, journal = {CURRENT GREEN CHEMISTRY}, volume = {7}, unique-id = {31799865}, issn = {2213-3461}, year = {2020}, eissn = {2213-347X}, pages = {304-313}, orcid-numbers = {Xu, Yufei/0000-0002-3973-1527; Zhang, Heng/0000-0001-8436-5549; Li, Hu/0000-0003-3604-9271; Yang, Song/0000-0003-1301-3030} } @article{MTMT:31062457, title = {Multidentate Pyridyl-Aminophosphinite and Pyridyl-Phosphoramidite Ruthenium(II) Complexes: Synthesis, Structure and Application as Levulinic Acid Hydrogenation Pre-Catalysts}, url = {https://m2.mtmt.hu/api/publication/31062457}, author = {Amenuvor, Gershon and Rono, Charles K. and Darkwa, James and Makhubela, Banothile C. E.}, doi = {10.1002/ejic.201900640}, journal-iso = {EUR J INORG CHEM}, journal = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY}, unique-id = {31062457}, issn = {1434-1948}, abstract = {Invited for the cover of this issue is Banothile Makhubela from the University of Johannesburg, South Africa. The cover image shows a picturesque African sunrise signifying a new dawn with the opportunity to develop a sustainable future.}, keywords = {HYDROGENATION; structure elucidation; RUTHENIUM; phosphoramidite; Aminophosphinite}, year = {2019}, eissn = {1099-0682}, pages = {3942-3953} } @article{MTMT:30709565, title = {Green synthesis of gamma-valerolactone (GVL) through hydrogenation of biomass-derived levulinic acid using non-noble metal catalysts: A critical review}, url = {https://m2.mtmt.hu/api/publication/30709565}, author = {Dutta, S. and Yu, I.K.M. and Tsang, D.C.W. and Ng, Y.H. and Ok, Y.S. and Sherwood, J. and Clark, J.H.}, doi = {10.1016/j.cej.2019.04.199}, journal-iso = {CHEM ENG J}, journal = {CHEMICAL ENGINEERING JOURNAL}, volume = {372}, unique-id = {30709565}, issn = {1385-8947}, year = {2019}, eissn = {1873-3212}, pages = {992-1006} } @article{MTMT:30683065, title = {Regioselective Hydrogenation of Itaconic Acid to gamma-Isovalerolactone by Transition-Metal Nanoparticle Catalysts}, url = {https://m2.mtmt.hu/api/publication/30683065}, author = {Gowda, Ravikumar R. and Chen, Eugene Y-X}, doi = {10.1002/cssc.201802878}, journal-iso = {CHEMSUSCHEM}, journal = {CHEMSUSCHEM}, volume = {12}, unique-id = {30683065}, issn = {1864-5631}, abstract = {Current methods for hydrogenation of bio-derived itaconic acid (IA) lead to a mixture of isomeric lactone products. Transition-metal nanoparticles (TM-NPs), in situ-generated through thermolysis of TM(0) (Ru, Fe, W, Cr) carbonyls, in particular Ru-NPs, were found to catalyze regioselective hydrogenation of IA by syngas (2 H-2/CO) into gamma-isovalerolactone (GiVL) in approximately 70 % isolated yield. Key sustainability features of this new route include: a one-pot direct transformation of bio-renewable IA into value-added GiVL selectively, use of inexpensive and renewable syngas in aqueous solution, and development of a supported recyclable NP catalyst system, Al2O3-Ru-NPs.}, keywords = {HYDROGENATION; Itaconic acid; Syngas; nanoparticle catalyst; gamma-isovalerolactone}, year = {2019}, eissn = {1864-564X}, pages = {973-977} } @article{MTMT:30935862, title = {Valorization of Carbohydrates of Agricultural Residues and Food Wastes: A Key Strategy for Carbon Conservation}, url = {https://m2.mtmt.hu/api/publication/30935862}, author = {Lui, M.Y. and Wong, C.Y.Y. and Choi, A.W.-T. and Mui, Y.F. and Qi, L. and Horváth, István Tamás}, doi = {10.1021/acssuschemeng.9b04242}, journal-iso = {ACS SUSTAIN CHEM ENG}, journal = {ACS SUSTAINABLE CHEMISTRY & ENGINEERING}, volume = {7}, unique-id = {30935862}, issn = {2168-0485}, year = {2019}, eissn = {2168-0485}, pages = {17799-17807}, orcid-numbers = {Horváth, István Tamás/0000-0002-6324-186X} } @{MTMT:34780282, title = {Other drop-in liquid biofuels}, url = {https://m2.mtmt.hu/api/publication/34780282}, author = {No, S.-Y.}, booktitle = {Green Energy and Technology}, doi = {10.1007/978-981-13-6737-3_10}, unique-id = {34780282}, year = {2019}, pages = {405-450} } @article{MTMT:30531922, title = {One pot selective conversion of furfural to gamma-valerolactone over zirconia containing heteropoly tungstate supported on beta-zeolite catalyst}, url = {https://m2.mtmt.hu/api/publication/30531922}, author = {Rao, B. Srinivasa and Kumari, P. Krishna and Koley, Paramita and Tardio, J. and Lingaiah, N.}, doi = {10.1016/j.mcat.2018.12.024}, journal-iso = {MOL CATAL}, journal = {MOLECULAR CATALYSIS}, volume = {466}, unique-id = {30531922}, issn = {2468-8231}, abstract = {A series of metal oxide and tungstophosphoric acid (TPA) supported on beta-zeolite catalysts were prepared and evaluated for the one pot selective conversion of furfural (FA) to gamma-valerolactone (GVL) using transfer hydrogenation approach. The characterizations of the catalysts were derived from N-2 -adsorption, FT-IR, XRD, XPS and temperature programmed desorption (TPD) techniques. The acid and base sites in the catalysts were estimated by NH3 and CO2-TPD and FT-IR spectroscopy with pyridine and 2-propanol adsorption. Among the catalysts 20%ZrO2 with 5%TPA on beta-zeolite showed high activity with 85% GVL yield. The high Lewis acidic density along with basic sites are responsible for the outstanding catalytic activity of the catalyst. Based on product distribution and catalyst characteristics, a plausible mechanism was proposed. Different reaction parameters were also studied and optimum conditions were established. The catalyst was easily recovered and reused with consistent activity.}, keywords = {GAMMA-VALEROLACTONE; transfer hydrogenation; beta-zeolite; Furfural; Tungstophosphoric acid}, year = {2019}, eissn = {2468-8274}, pages = {52-59} } @article{MTMT:3387697, title = {Evaluation of Biobased Lighter Fluids}, url = {https://m2.mtmt.hu/api/publication/3387697}, author = {Cséfalvay, Edit}, doi = {10.1021/acssuschemeng.8b00546}, journal-iso = {ACS SUSTAIN CHEM ENG}, journal = {ACS SUSTAINABLE CHEMISTRY & ENGINEERING}, volume = {6}, unique-id = {3387697}, issn = {2168-0485}, year = {2018}, eissn = {2168-0485}, pages = {8417-8426} } @article{MTMT:3363077, title = {Conservative Evolution and Industrial Metabolism in Green Chemistry}, url = {https://m2.mtmt.hu/api/publication/3363077}, author = {Náray-Szabó, Gábor and Mika, László Tamás}, doi = {10.1039/c8gc00514a}, journal-iso = {GREEN CHEM}, journal = {GREEN CHEMISTRY}, volume = {20}, unique-id = {3363077}, issn = {1463-9262}, year = {2018}, eissn = {1463-9270}, pages = {2171-2191} } @article{MTMT:27338161, title = {Ru/ZrO2 Catalysts for Transfer Hydrogenation of Levulinic Acid with Formic Acid/Formate Mixtures: Importance of Support Stability}, url = {https://m2.mtmt.hu/api/publication/27338161}, author = {Gao, Yanxiu and Zhang, Hongwei and Han, Aijuan and Wang, Jie and Tan, Hui-Ru and Tok, Eng-Soon and Jaenicke, Stephan and Chuah, Gaik-Khuan}, doi = {10.1002/slct.201702152}, journal-iso = {CHEMISTRYSELECT}, journal = {CHEMISTRYSELECT}, volume = {3}, unique-id = {27338161}, issn = {2365-6549}, year = {2018}, eissn = {2365-6549}, pages = {1343-1351} } @article{MTMT:30377118, title = {Festschrift in Honor of István T. Horváth}, url = {https://m2.mtmt.hu/api/publication/30377118}, author = {Gladysz, John A.}, doi = {10.1021/acssuschemeng.8b03138}, journal-iso = {ACS SUSTAIN CHEM ENG}, journal = {ACS SUSTAINABLE CHEMISTRY & ENGINEERING}, volume = {6}, unique-id = {30377118}, issn = {2168-0485}, year = {2018}, eissn = {2168-0485}, pages = {9523-9529} } @article{MTMT:27218043, title = {Determination of γ-valerolactone content in its synthesis and biorefinery processes by headspace analysis technique}, url = {https://m2.mtmt.hu/api/publication/27218043}, author = {Hui-Chao, Hu and Shaokai, Zhang and Tong, Zeng and Yiying, Lin and Liulian, Huang and Lihui, Chen and Yonghao, Ni}, doi = {10.1016/j.fuel.2018.03.056}, journal-iso = {FUEL}, journal = {FUEL}, volume = {224}, unique-id = {27218043}, issn = {0016-2361}, year = {2018}, eissn = {1873-7153}, pages = {17-22} } @article{MTMT:27611074, title = {Synthesis of gamma-Valerolactone from Levulinic Acid and Formic Acid over Mg-Al Hydrotalcite Like Compound}, url = {https://m2.mtmt.hu/api/publication/27611074}, author = {Hussain, S K and Velisoju, Vijay Kumar and Rajan, N Pethan and Kumar, Balla Putra and Chary, Komandur V R}, doi = {10.1002/slct.201800536}, journal-iso = {CHEMISTRYSELECT}, journal = {CHEMISTRYSELECT}, volume = {3}, unique-id = {27611074}, issn = {2365-6549}, year = {2018}, eissn = {2365-6549}, pages = {6186-6194} } @{MTMT:3319729, title = {Conversion of carbohydrates to chemicals}, url = {https://m2.mtmt.hu/api/publication/3319729}, author = {Mika, László Tamás and Cséfalvay, Edit}, booktitle = {Advanced Green Chemistry Part 1: Greener Organic Reactions and Processes}, doi = {10.1142/9789813228115_0002}, unique-id = {3319729}, year = {2018}, pages = {19-76} } @article{MTMT:30529544, title = {Facile conversion of levulinic acid to gamma-valerolactone using a high surface area magnetically separable Ni/NiO catalyst}, url = {https://m2.mtmt.hu/api/publication/30529544}, author = {Singh, Hari and Iyengar, Nishant and Yadav, Rajkumar and Rai, Aditya and Sinha, Anil K.}, doi = {10.1039/c8se00274f}, journal-iso = {SUSTAIN ENERG FUELS}, journal = {SUSTAINABLE ENERGY & FUELS}, volume = {2}, unique-id = {30529544}, issn = {2398-4902}, abstract = {A study on the conversion of levulinic acid (LA) to gamma-valerolactone (GVL) and methyl levulinate (ML) has been done using a high surface area Ni/NiO catalyst. The hydrogenation of levulinic acid over the Ni/NiO catalyst showed high mass activity for gamma-valerolactone formation (16 mmol g(cat)(-1) h(-1)) at 110 degrees C at 40 bar pressure. The presence of acidity effects the conversion of LA to GVL and ML. First-principles DFT calculations were used to calculate the adsorption energy and transition state for the reaction. The Ni/NiO catalyst showed 99% LA conversion and 94% GVL selectivity at 110 degrees C in methanol, which is higher than the reported activity of Ni-based catalysts (RANEY (R) Ni and Ni/Al2O3).}, year = {2018}, eissn = {2398-4902}, pages = {1699-1706} } @article{MTMT:27353865, title = {A Comparative Study of Structurally Related Homogeneous Ruthenium and Iron Catalysts for the Hydrogenation of Levulinic Acid to -Valerolactone}, url = {https://m2.mtmt.hu/api/publication/27353865}, author = {van Slagmaat, Christian A M R and De Wildeman, Stefaan M A}, doi = {10.1002/ejic.201700938}, journal-iso = {EUR J INORG CHEM}, journal = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY}, unique-id = {27353865}, issn = {1434-1948}, year = {2018}, eissn = {1099-0682}, pages = {694-702} } @article{MTMT:30543713, title = {An efficient and reusable bimetallic Ni3Fe NPs@C catalyst for selective hydrogenation of biomass-derived levulinic acid to gamma-valerolactone}, url = {https://m2.mtmt.hu/api/publication/30543713}, author = {Wang, Haojie and Chen, Chun and Zhang, Haimin and Wang, Guozhong and Zhao, Huijun}, doi = {10.1016/S1872-2067(18)63105-5}, journal-iso = {CHINESE J CATAL}, journal = {CHINESE JOURNAL OF CATALYSIS}, volume = {39}, unique-id = {30543713}, issn = {0253-9837}, abstract = {Bimetallic nanostructures have attracted great interest as efficient catalyst to enhance activity, selectivity and stability in catalytical conversion. Herein, we report a facile one-pot carbothermal route to in-situ controllable synthesize heterogeneous bimetallic Ni3Fe NPs@C nanocatalyst. The X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and N-2 adsorption-description results reveal that the Ni3Fe alloy nanoparticles are evenly embedded in carbon matrix. The as-prepared Ni3Fe NPs@C catalyst shows excellent selective hydrogenation catalytic performance toward the conversion of levulinic acid (LA) to gamma-valerolactone (GVL) via both direct hydrogenation (DH) and transfer hydrogenation (TH). In DH of LA, the bimetallic catalyst achieved a 93.8% LA conversion efficiency with a 95.5% GVL selectivity and 38.2 mmol g(-1) h(-1) GVL productivity (under 130 degrees C, 2MPa H-2 within 2 h), which are 6 and 40 times in comparison with monometallic Ni NPs@C and Fe NPs@C catalysts, respectively. In addition, the identical catalyst displayed a full conversion of LA with almost 100% GVL selectivity and 167.1 mmol g(-1) h(-1) GVL productivity at 180 degrees C within 0.5 h in TH of LA. Under optimal reaction conditions, the DH and TH catalytic performance of 500-Ni3Fe NPs@C(3:1) catalyst for converting LA to GVL is comparable to the state-of-the-art noble-based catalysts. The demonstrated capability of bimetallic catalyst design approach to introduce dual-catalytic functionality for DH and TH reactions could be adoptable for other catalysis processes. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.}, keywords = {HYDROGENATION; GAMMA-VALEROLACTONE; levulinic acid; Bimetallic catalyst; Dual-catalytic functionality}, year = {2018}, eissn = {1872-2067}, pages = {1599-1607}, orcid-numbers = {Zhao, Huijun/0000-0002-3028-0459} } @{MTMT:3210862, title = {Asymmetric Reduction Of Ketones To Chiral Platform Molecules}, url = {https://m2.mtmt.hu/api/publication/3210862}, author = {Bálint, Fridrich and Tukacs, József Márk and Mika, László Tamás}, booktitle = {Advances in Asymmetric Autocatalysis and Related Topics}, doi = {10.1016/B978-0-12-812824-4.00012-5}, unique-id = {3210862}, year = {2017}, pages = {223-240} } @article{MTMT:3174348, title = {Vapor–Liquid Equilibrium of γ-Valerolactone and Formic Acid at p = 51 kPa}, url = {https://m2.mtmt.hu/api/publication/3174348}, author = {Havasi, Dávid and Ádám, Hajnal and Pátzay, György and Mika, László Tamás}, doi = {10.1021/acs.jced.6b00867}, journal-iso = {J CHEM ENG DATA}, journal = {JOURNAL OF CHEMICAL AND ENGINEERING DATA}, volume = {62}, unique-id = {3174348}, issn = {0021-9568}, year = {2017}, eissn = {1520-5134}, pages = {1058-1062}, orcid-numbers = {Havasi, Dávid/0000-0003-3366-4009; Pátzay, György/0000-0002-9736-178X} } @article{MTMT:27100719, title = {When 2nd generation biofuel meets water - The water solubility and phase stability issue}, url = {https://m2.mtmt.hu/api/publication/27100719}, author = {Dechambre, Dominique and Thien, Julia and Bardow, Andre}, doi = {10.1016/j.fuel.2017.07.110}, journal-iso = {FUEL}, journal = {FUEL}, volume = {209}, unique-id = {27100719}, issn = {0016-2361}, year = {2017}, eissn = {1873-7153}, pages = {615-623} } @article{MTMT:3167465, title = {Ruthenium-catalyzed solvent-free conversion of furfural to furfuryl alcohol}, url = {https://m2.mtmt.hu/api/publication/3167465}, author = {Tukacs, József Márk and Márton, Bohus and Gábor, Dibó and Mika, László Tamás}, doi = {10.1039/c6ra24723g}, journal-iso = {RSC ADV}, journal = {RSC ADVANCES}, volume = {7}, unique-id = {3167465}, issn = {2046-2069}, year = {2017}, eissn = {2046-2069}, pages = {3331-3335} } @article{MTMT:26768620, title = {Advanced Biofuels and Beyond: Chemistry Solutions for Propulsion and Production}, url = {https://m2.mtmt.hu/api/publication/26768620}, author = {Leitner, Walter and Klankermayer, Juergen and Pischinger, Stefan and Pitsch, Heinz and Kohse-Hoeinghaus, Katharina}, doi = {10.1002/anie.201607257}, journal-iso = {ANGEW CHEM INT EDIT}, journal = {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION}, volume = {56}, unique-id = {26768620}, issn = {1433-7851}, year = {2017}, eissn = {1521-3773}, pages = {5412-5452}, orcid-numbers = {Leitner, Walter/0000-0001-6100-9656} } @article{MTMT:3150789, title = {Compatibility Study of Viton, NBR 70 and EPDM O-rings with Selected Solvents}, url = {https://m2.mtmt.hu/api/publication/3150789}, author = {Lukács, Lilla and Cséfalvay, Edit}, doi = {10.3311/PPch.9606}, journal-iso = {PERIOD POLYTECH CHEM ENG}, journal = {PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING}, volume = {61}, unique-id = {3150789}, issn = {0324-5853}, year = {2017}, eissn = {1587-3765}, pages = {67-72} } @article{MTMT:3214867, title = {Rhodium-catalyzed hydroformylation in γ-valerolactone as a biomass-derived solvent}, url = {https://m2.mtmt.hu/api/publication/3214867}, author = {Pongrácz, Péter and Bartal, B and Kollár, László and Mika, László Tamás}, doi = {10.1016/j.jorganchem.2017.04.029}, journal-iso = {J ORGANOMET CHEM}, journal = {JOURNAL OF ORGANOMETALLIC CHEMISTRY}, volume = {847}, unique-id = {3214867}, issn = {0022-328X}, year = {2017}, eissn = {1872-8561}, pages = {140-145}, orcid-numbers = {Pongrácz, Péter/0009-0006-5782-2883} } @article{MTMT:3174184, title = {Microwave-Assisted Valorization of Biowastes to Levulinic Acid}, url = {https://m2.mtmt.hu/api/publication/3174184}, author = {Tukacs, József Márk and Holló, Ambrus T and Rétfalvi, Nóra and Cséfalvay, Edit and Dibó, Gábor and Havasi, Dávid and Mika, László Tamás}, doi = {10.1002/slct.201700037}, journal-iso = {CHEMISTRYSELECT}, journal = {CHEMISTRYSELECT}, volume = {2}, unique-id = {3174184}, issn = {2365-6549}, year = {2017}, eissn = {2365-6549}, pages = {1375-1380}, orcid-numbers = {Havasi, Dávid/0000-0003-3366-4009} } @article{MTMT:26768622, title = {The emerging use of square-valerolactone as a green solvent}, url = {https://m2.mtmt.hu/api/publication/26768622}, author = {Vaccaro, Luigi and Santoro, Stefano and Curini, Massimo and Lanari, Daniela}, journal-iso = {CHIM OGGI}, journal = {CHIMICA OGGI-CHEMISTRY TODAY}, volume = {35}, unique-id = {26768622}, issn = {0392-839X}, year = {2017}, eissn = {1973-8250}, pages = {46-48}, orcid-numbers = {Vaccaro, Luigi/0000-0003-4168-2303; Santoro, Stefano/0000-0003-0223-1489} } @article{MTMT:26935676, title = {Reactions of lactones with tropospheric oxidants: A kinetics and products study}, url = {https://m2.mtmt.hu/api/publication/26935676}, author = {Walavalkar, M P and Sharma, A and Dhanya, S and Naik, P D}, doi = {10.1016/j.atmosenv.2017.04.028}, journal-iso = {ATMOS ENVIRON}, journal = {ATMOSPHERIC ENVIRONMENT}, volume = {161}, unique-id = {26935676}, issn = {1352-2310}, year = {2017}, eissn = {1873-2844}, pages = {18-26} } @article{MTMT:26935683, title = {Efficient Iridium Catalysts for Base-Free Hydrogenation of Levulinic Acid}, url = {https://m2.mtmt.hu/api/publication/26935683}, author = {Wang, S and Huang, H and Dorcet, V and Roisnel, T and Bruneau, C and Fischmeister, C}, doi = {10.1021/acs.organomet.7b00503}, journal-iso = {ORGANOMETALLICS}, journal = {ORGANOMETALLICS}, volume = {36}, unique-id = {26935683}, issn = {0276-7333}, year = {2017}, eissn = {1520-6041}, pages = {3152-3162} } @article{MTMT:3155187, title = {Stability of Gamma-valerolactone under Neutral, Acidic, and Basic Conditions}, url = {https://m2.mtmt.hu/api/publication/3155187}, author = {Wong, C Y Y and Choi, A W-T and Lui, M and Fridrich, B and Horváth, Attila and Mika, László Tamás and Horváth, István Tamás}, doi = {10.1007/s11224-016-0887-6}, journal-iso = {STRUCT CHEM}, journal = {STRUCTURAL CHEMISTRY}, volume = {28}, unique-id = {3155187}, issn = {1040-0400}, year = {2017}, eissn = {1572-9001}, pages = {423-429}, orcid-numbers = {Horváth, Attila/0000-0002-1916-2451; Horváth, István Tamás/0000-0002-6324-186X} } @article{MTMT:26584181, title = {Porous Ti/Zr Microspheres for Efficient Transfer Hydrogenation of Biobased Ethyl Levulinate to gamma-Valerolactone}, url = {https://m2.mtmt.hu/api/publication/26584181}, author = {Yang, Tingting and Li, Hu and He, Jian and Liu, Yanxiu and Zhao, Wenfeng and Wang, Zhongwei and Ji, Xiaoxiao and Yang, Song}, doi = {10.1021/acsomega.6b00469}, journal-iso = {ACS OMEGA}, journal = {ACS OMEGA}, volume = {2}, unique-id = {26584181}, issn = {2470-1343}, year = {2017}, eissn = {2470-1343}, pages = {1047-1054} } @article{MTMT:3104106, title = {Application of γ-valerolactone as an alternative biomass-based medium for aminocarbonylation reactions}, url = {https://m2.mtmt.hu/api/publication/3104106}, author = {Marosvölgyi-Haskó, Diána and Blanka, Lengyel and Tukacs, József Márk and Kollár, László and Mika, László Tamás}, doi = {10.1002/cplu.201600389}, journal-iso = {CHEMPLUSCHEM}, journal = {CHEMPLUSCHEM}, volume = {81}, unique-id = {3104106}, issn = {2192-6506}, year = {2016}, eissn = {2192-6506}, pages = {1224-1229} } @article{MTMT:25790678, title = {ZrO2/SBA-15 as an efficient catalyst for the production of gamma-valerolactone from biomass-derived levulinic acid in the vapour phase at atmospheric pressure}, url = {https://m2.mtmt.hu/api/publication/25790678}, author = {Enumula, Siva Sankar and Gurram, Venkata Ramesh Babu and Kondeboina, Murali and Burri, David Raju and Kamaraju, Seetha Rama Rao}, doi = {10.1039/c5ra27513j}, journal-iso = {RSC ADV}, journal = {RSC ADVANCES}, volume = {6}, unique-id = {25790678}, issn = {2046-2069}, year = {2016}, eissn = {2046-2069}, pages = {20230-20239} } @article{MTMT:26353327, title = {Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce -Valerolactone}, url = {https://m2.mtmt.hu/api/publication/26353327}, author = {Gowda, Ravikumar R and Chen, Eugene Y -X}, doi = {10.1002/cssc.201501402}, journal-iso = {CHEMSUSCHEM}, journal = {CHEMSUSCHEM}, volume = {9}, unique-id = {26353327}, issn = {1864-5631}, year = {2016}, eissn = {1864-564X}, pages = {181-185} } @article{MTMT:26353335, title = {Direct Catalytic Transformation of Biomass Derivatives into Biofuel Component gamma-Valerolactone with Magnetic Nickel-Zirconium Nanoparticles}, url = {https://m2.mtmt.hu/api/publication/26353335}, author = {Li, Hu and Fang, Zhen and Yang, Song}, doi = {10.1002/cplu.201500492}, journal-iso = {CHEMPLUSCHEM}, journal = {CHEMPLUSCHEM}, volume = {81}, unique-id = {26353335}, issn = {2192-6506}, year = {2016}, eissn = {2192-6506}, pages = {135-142}, orcid-numbers = {Li, Hu/0000-0003-3604-9271; Fang, Zhen/0000-0002-7391-372X; Yang, Song/0000-0003-1301-3030} } @article{MTMT:26218297, title = {Homogeneous Catalyzed Reactions of Levulinic Acid: To -Valerolactone and Beyond}, url = {https://m2.mtmt.hu/api/publication/26218297}, author = {Omoruyi, Uwaila and Page, Samuel and Hallett, Jason and Miller, Philip W}, doi = {10.1002/cssc.201600517}, journal-iso = {CHEMSUSCHEM}, journal = {CHEMSUSCHEM}, volume = {9}, unique-id = {26218297}, issn = {1864-5631}, abstract = {Platform chemicals derived from lignocellulosic plant biomass are viewed as a sustainable replacement for crude oil-based feedstocks. Levulinic acid (LA) is one such biomass-derived chemical that has been widely studied for further catalytic transformation to γ-valerolactone (GVL), an important ‘green’ fuel additive, solvent, and fine chemical intermediate. Although the transformation of LA to GVL can be achieved using heterogeneous catalysis, homogeneous catalytic systems that operate under milder reactions, give higher selectivities and can be recycled continuously are attracting considerable attention. A range of new homogeneous catalysts have now been dem-onstrated to efficiently convert LA to GVL and to transform LA directly to other value-added chemicals such as 1,4-pentane-diol (1,4-PDO) and 2-methyltetrahydrofuran (2-MTHF). This Minireview covers recent advances in the area of homogeneous catalysis for the conversion of levulinic acid and levulinic ester derivatives to GVL and chemicals beyond GVL. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.}, year = {2016}, eissn = {1864-564X}, pages = {2037-2047} } @article{MTMT:2950280, title = {A step towards hydroformylation under sustainable conditions: platinum-catalysed enantioselective hydroformylation of styrene in gamma-valerolactone}, url = {https://m2.mtmt.hu/api/publication/2950280}, author = {Pongrácz, Péter and Kollár, László and Mika, László Tamás}, doi = {10.1039/C5GC01778E}, journal-iso = {GREEN CHEM}, journal = {GREEN CHEMISTRY}, volume = {18}, unique-id = {2950280}, issn = {1463-9262}, year = {2016}, eissn = {1463-9270}, pages = {842-847} } @article{MTMT:26353047, title = {Catalytic dehydrogenation of 1,2-and 1,3-diols}, url = {https://m2.mtmt.hu/api/publication/26353047}, author = {Weber, Madeline A and Ford, Peter C}, doi = {10.1016/j.molcata.2016.02.018}, journal-iso = {J MOL CATAL A-CHEM}, journal = {JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL}, volume = {416}, unique-id = {26353047}, issn = {1381-1169}, year = {2016}, eissn = {1873-314X}, pages = {81-87} } @article{MTMT:34377635, title = {pH-Regulated Aqueous Catalytic Hydrogenation of Biomass Carbohydrate Derivatives by Using Semisandwich Iridium Complexes}, url = {https://m2.mtmt.hu/api/publication/34377635}, author = {Wu, W.-P. and Xu, Y.-J. and Chang, S.-W. and Deng, J. and Fu, Y.}, doi = {10.1002/cctc.201601009}, journal-iso = {CHEMCATCHEM}, journal = {CHEMCATCHEM}, volume = {8}, unique-id = {34377635}, issn = {1867-3880}, year = {2016}, eissn = {1867-3899}, pages = {3375-3380} }