@article{MTMT:34659670, title = {Subaqueous carbonate speleothems as paleotemperature archives – clumped isotope thermometry and stable isotope compositions of inclusion-hosted wate}, url = {https://m2.mtmt.hu/api/publication/34659670}, author = {Demény, Attila and Berentés, A and Rinyu, László and Kovács, Ivett and Surányi, Gergely and Virág, Magdolna}, doi = {10.5038/1827-806X.53.1.2480}, journal-iso = {INT J SPELEOL}, journal = {INTERNATIONAL JOURNAL OF SPELEOLOGY}, volume = {53}, unique-id = {34659670}, issn = {0392-6672}, year = {2024}, eissn = {1827-806X}, pages = {25-37}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018; Kovács, Ivett/0000-0001-7015-7909; Virág, Magdolna/0000-0001-6104-1963} } @article{MTMT:33527205, title = {Tracing the Source of Hydrothermal Fluid in Ophiolite-Related Volcanogenic Massive Sulfide Deposits: A Case Study from the Italian Northern Apennines}, url = {https://m2.mtmt.hu/api/publication/33527205}, author = {Baloghné Kiss, Gabriella and Molnár, Kata and Benkó, Zsolt and Skoda, P and Kapui, Zsuzsanna and Garuti, G and Zaccarini, F and Palcsu, László and Czuppon, György}, doi = {10.3390/min13010008}, journal-iso = {MINERALS-BASEL}, journal = {MINERALS}, volume = {13}, unique-id = {33527205}, abstract = {The Italian Northern Apennines contain several Fe-Cu-Zn-bearing, Cyprus-type volcanogenic massive sulfide (VMS) deposits, which significantly contribute to the Cu resources of Italy. The massive sulfide lenses and related stockwork mineralizations are hosted by several levels (from basalt to serpentinite) of the unmetamorphosed ophiolitic series; therefore, this region offers perfect locations to study the ore-forming hydrothermal system in detail. A combination of fluid inclusion microthermometry, Raman spectroscopy, electron probe analyses (chlorite thermometry) and stable and noble gas isotope geochemistry was used to determine the fluid source of the VMS system at Bargone, Boccassuolo, Campegli, Casali–Monte Loreto, Corchia, Reppia and Vigonzano. This question of the fluid source is the focus of modern VMS research worldwide, as it has a direct influence on the metal content of the deposit. The obtained temperature and compositional data are both in the typical range of VMS systems and basically suggest evolved seawater origin for the mineralizing fluid. Modification of seawater was most commonly due to fluid–rock interaction processes, which happened during long-lasting circulation in the crust. The role of a small amount of magmatic fluid input was traced only at the lower block of Boccassuolo, which may be responsible for its higher ore grade. This fluid origin model is evidenced by O, H and C stable isotopic as well as He, Ne and Ar noble gas isotopic values.}, year = {2023}, eissn = {2075-163X}, orcid-numbers = {Baloghné Kiss, Gabriella/0000-0002-7162-2961; Molnár, Kata/0000-0001-6993-5806; Czuppon, György/0000-0002-7231-6042} } @article{MTMT:33334510, title = {Constraints for precise and accurate fluid inclusion stable isotope analysis using water-vapour saturated CRDS techniques}, url = {https://m2.mtmt.hu/api/publication/33334510}, author = {Weissbach, T and Kluge, T and Affolter, S and Leuenberger, MC. and Vonhof, H and Riechelmann, DFC. and Fohlmeister, J and Juhl, MC and Hemmer, B and Wu, Y and Warken, SF. and Schmidt, M and Frank, N and Aeschbach, W}, doi = {10.1016/j.chemgeo.2022.121268}, journal-iso = {CHEM GEOL}, journal = {CHEMICAL GEOLOGY}, volume = {617}, unique-id = {33334510}, issn = {0009-2541}, year = {2023}, eissn = {1872-6836} } @article{MTMT:34065811, title = {Mineral Crushing Methods for Noble Gas Analyses of Fluid Inclusions}, url = {https://m2.mtmt.hu/api/publication/34065811}, author = {Wilske, C. and Suckow, A. and Gerber, C. and Deslandes, A. and Crane, P. and Mallants, D.}, doi = {10.1155/2023/8040253}, journal-iso = {GEOFLUIDS}, journal = {GEOFLUIDS}, volume = {2023}, unique-id = {34065811}, issn = {1468-8115}, abstract = {Noble gases are frequently probed for investigating fluid inclusions in minerals to unravel rock-forming processes through time. Over the last decades, heating and crushing have been the two main methods applied for noble gas extraction from fluid inclusions in ultrahigh vacuum (about 10-9 mBar). The heating of minerals or pieces of bulk rock causes the release of noble gases from both fluid inclusions and the mineral or rock matrix, the latter due to temperature-dependent mineral dehydration. Crushing of minerals only affects fluid inclusions and allows a release of noble gases at room temperature with minor contributions from the mineral matrix. This review describes different ultravacuum crushing techniques for noble gas analysis from fluid inclusions. It examines the technical details and operational conditions of each crushing system as well as methods to prepare samples prior to crushing. Crushing systems were found to have unique designs across the different laboratories reviewed; they include single or multiple sample loadings and manual, magnetic, or hydraulic operation of the crushing pistons. Due to the small amounts of noble gases released, the technology requires several mg to a few grams of rock material to achieve a measurement of all stable noble gas isotopes in a single fluid inclusion. While theoretically all stable noble gas isotopes are of interest, the elements and isotopes reported in different studies vary widely and reference materials as well as laboratory intercomparisons are lacking. The review includes applications on the origins of magmatic rocks and geochemical processes in the Earth’s mantle, the origin and chemical composition of deep crustal fluids and how these contribute to the formation of minerals of economic interest, and paleoclimate studies based on speleothems.}, year = {2023}, eissn = {1468-8123}, orcid-numbers = {Wilske, C./0000-0002-2821-4583; Suckow, A./0000-0002-6237-2198; Gerber, C./0000-0003-4339-5746; Mallants, D./0000-0001-7282-1981} } @article{MTMT:32089112, title = {U-pb dating and geochemical constraints to early cretaceous hydrothermal dolomitization in the provenÇal domain (Maritime alps, nw italy-se france)}, url = {https://m2.mtmt.hu/api/publication/32089112}, author = {Barale, L. and Bertok, C. and D’atri, A. and Piana, F. and Bernasconi, S.M. and Czuppon, György and Palcsu, László and Gerdes, A. and Birgel, D. and Martire, L.}, doi = {10.4454/ofioliti.v46i2.543}, journal-iso = {OFIOLITI}, journal = {OFIOLITI}, volume = {46}, unique-id = {32089112}, issn = {0391-2612}, year = {2021}, pages = {131-149}, orcid-numbers = {Czuppon, György/0000-0002-7231-6042} } @article{MTMT:32240638, title = {Origin of dawsonite-forming fluids in the Mihályi-Répcelak field (Pannonian Basin) using stable H, C and O isotope compositions: Implication for mineral storage of carbon-dioxide}, url = {https://m2.mtmt.hu/api/publication/32240638}, author = {Cseresznyés, Dóra and Czuppon, György and Király, Csilla and Demény, Attila and Györe, D and Forray, V and Kovács, Ivett and Szabó, Csaba and Falus, György}, doi = {10.1016/j.chemgeo.2021.120536}, journal-iso = {CHEM GEOL}, journal = {CHEMICAL GEOLOGY}, volume = {584}, unique-id = {32240638}, issn = {0009-2541}, abstract = {Natural CO2 reservoirs provide an opportunity to study long-term fluid-rock interactions, which are essential to reassure the safety of mineral storage of carbon-dioxide. The Mihályi-Répcelak field (Pannonian Basin, Central Europe) is one of the largest natural CO2-bearing reservoirs in Europe (25 Mt). The CO2 was trapped in Neogene sandstones, which contain various carbonate minerals (dolomite, ankerite, siderite, dawsonite). To reveal the origin of the parent fluid, from which these minerals precipitated, dawsonite and siderite were separated by a new physical method to minimise the uncertainties in the analysis of their stable isotope composition. The δ13CDaw values range from +1.3 to +1.6‰ and the calculated δ13CCO2 values in equilibrium with dawsonite (−4.8‰ - –2.0‰) overlap with the carbon isotope compositions of the local CO2 and the European Subcontinental Lithospheric Mantle (−3.9‰ - –2.1‰). This indicates that the dawsonite-forming CO2 had a magmatic origin. The siderite data indicates that some formed from the magmatic CO2, possibly simultaneously with dawsonite (−6.0‰ - –3.9‰), whereas the rest (−8.4 - –6.1‰) formed either from a fractionated CO2 with magmatic origin or before the CO2 invasion. The hydrogen isotope composition of structural OH− of dawsonite (−57‰ to −74‰) was determined and was used to estimate the origin of the interacting porewater. The calculated porewater data (δD: −69‰ - –103‰ and δ18O: −1.4‰ - +4.7‰) indicate that the parent fluid was meteoric water modified by water-rock interaction. Our data allows estimation of the total amount of CO2 stored in the dawsonite-bearing sandstone reservoir to be 25 kg/m3, well in line with previous modelling works, which gives a total of 2.01 × 106 t of CO2, higher than previous estimates. We suggest that individual mineral analysis complemented by hydrogen isotope analysis is to be employed to effectively trace in-reservoir fluid-rock interactions in CO2 reservoirs and provide valuable input data for geochemical modelling for better predicting conditions for mineral storage of CO2.}, keywords = {Natural CO; Dawsonite; Hydrogen, carbon, oxygen stable isotopes; Mineral storage of CO, CCS}, year = {2021}, eissn = {1872-6836}, orcid-numbers = {Cseresznyés, Dóra/0000-0001-6676-7122; Czuppon, György/0000-0002-7231-6042; Demény, Attila/0000-0003-0522-9018; Kovács, Ivett/0000-0001-7015-7909; Szabó, Csaba/0000-0002-1580-6344} } @article{MTMT:31813634, title = {Paleotemperature reconstructions using speleothem fluid inclusion analyses from Hungary}, url = {https://m2.mtmt.hu/api/publication/31813634}, author = {Demény, Attila and Rinyu, László and Kern, Zoltán and Hatvani, István Gábor and Czuppon, György and Surányi, Gergely and Leél-Őssy, Szabolcs and Shen, CC and Koltai, Gabriella}, doi = {10.1016/j.chemgeo.2020.120051}, journal-iso = {CHEM GEOL}, journal = {CHEMICAL GEOLOGY}, volume = {563}, unique-id = {31813634}, issn = {0009-2541}, year = {2021}, eissn = {1872-6836}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018; Kern, Zoltán/0000-0003-4900-2587; Hatvani, István Gábor/0000-0002-9262-7315; Czuppon, György/0000-0002-7231-6042} } @article{MTMT:31329820, title = {A comparison of isotope ratio mass spectrometry and cavity ring-down spectroscopy techniques for isotope analysis of fluid inclusion water}, url = {https://m2.mtmt.hu/api/publication/31329820}, author = {de Graaf, S and Vonhof, HB. and Weissbach, T and Wassenburg, JA. and Levy, EJ. and Kluge, T and Haug, GH.}, doi = {10.1002/rcm.8837}, journal-iso = {RAPID COMMUN MASS SPECTR}, journal = {RAPID COMMUNICATIONS IN MASS SPECTROMETRY}, volume = {34}, unique-id = {31329820}, issn = {0951-4198}, year = {2020}, eissn = {1097-0231}, orcid-numbers = {de Graaf, S/0000-0003-1054-1049; Vonhof, HB./0000-0002-0897-8244} } @article{MTMT:30882547, title = {Geology and geochronology of the Paleoproterozoic Hart Dolerite, Western Australia}, url = {https://m2.mtmt.hu/api/publication/30882547}, author = {Ramsay, R.R. and Eves, A.E. and Denyszyn, S.W. and Wingate, M.T.D. and Fiorentini, M. and Gwalani, L.G. and Rogers, K.A.}, doi = {10.1016/j.precamres.2019.105482}, journal-iso = {PRECAMBRIAN RES}, journal = {PRECAMBRIAN RESEARCH}, volume = {335}, unique-id = {30882547}, issn = {0301-9268}, year = {2019}, eissn = {1872-7433} } @article{MTMT:3399845, title = {Pervasive early diagenetic dolomitization, subsequent hydrothermal alteration, and late stage hydrocarbon accumulation in a Middle Triassic carbonate sequence (Szeged Basin, SE Hungary)}, url = {https://m2.mtmt.hu/api/publication/3399845}, author = {Garaguly, István and Raucsikné Varga, Andrea Beáta and Raucsik, Béla and Schubert, Félix and Czuppon, György and Frei, R}, doi = {10.1016/j.marpetgeo.2018.07.024}, journal-iso = {MAR PETROL GEOL}, journal = {MARINE AND PETROLEUM GEOLOGY}, volume = {98}, unique-id = {3399845}, issn = {0264-8172}, year = {2018}, eissn = {1873-4073}, pages = {270-290}, orcid-numbers = {Garaguly, István/0000-0002-2802-0738; Raucsikné Varga, Andrea Beáta/0000-0002-8673-1482; Raucsik, Béla/0000-0002-1951-5974; Schubert, Félix/0000-0001-8647-5354; Czuppon, György/0000-0002-7231-6042} } @article{MTMT:3262057, title = {Stable Isotope Compositions of Different Mineral Phases Found in a Natural CO2-reservoir (NW-Hungary): Implication for their Origin}, url = {https://m2.mtmt.hu/api/publication/3262057}, author = {Cseresznyés, Dóra and Czuppon, György and Szabó-Krausz, Zsuzsanna and Király, Csilla and Szabó, Csaba and Falus, György}, doi = {10.1016/j.egypro.2017.03.1399}, journal-iso = {ENERGY PROCEDIA}, journal = {ENERGY PROCEDIA}, volume = {114}, unique-id = {3262057}, abstract = {Stable isotope systems provide exceptional insight into fluid-solid interactions occurring in the sub-surface. We provide detailed insight into the stable isotope distribution of carbonate minerals in a natural CO2 reservoir system from Mihályi-Répcelak area, NW-Hungary. Several types of measurements and calculations have been applied for the estimation of CO2 and H2O isotopic composition in equilibrium with dawsonite. The estimated G13C of CO2 exhibit values around -4.5 to -2.6 ‰ overlapping with assumed magmatic values and the presently measured gas data confirming magmatic origin, whereas we may assume that the water present during carbonate formation likely had meteoric origin. © 2017 The Authors. Published by Elsevier Ltd. Peer-review under responsibility of the organizing committee of GHGT-13. Keywords: stable isotopes; natural CO2 reservoir; carbonate minerals}, keywords = {Stable Isotope; natural CO2 reservoir; NW Hungary}, year = {2017}, eissn = {1876-6102}, pages = {2812-2818}, orcid-numbers = {Cseresznyés, Dóra/0000-0001-6676-7122; Czuppon, György/0000-0002-7231-6042; Szabó-Krausz, Zsuzsanna/0000-0002-4454-8700; Szabó, Csaba/0000-0002-1580-6344} } @article{MTMT:3191622, title = {Stable isotope compositions of speleothems from the last interglacial e Spatial patterns of climate fluctuations in Europe}, url = {https://m2.mtmt.hu/api/publication/3191622}, author = {Demény, Attila and Kern, Zoltán and Czuppon, György and Németh, Alexandra and Leél-Őssy, Szabolcs and Siklósy, Z and Lin, K and Hsun-Ming, H and Shen, Ch-Ch and Vennemann, T W and Haszpra, László}, doi = {10.1016/j.quascirev.2017.02.012}, journal-iso = {QUATERN SCI REV}, journal = {QUATERNARY SCIENCE REVIEWS}, volume = {161}, unique-id = {3191622}, issn = {0277-3791}, year = {2017}, eissn = {1873-457X}, pages = {68-80}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018; Kern, Zoltán/0000-0003-4900-2587; Czuppon, György/0000-0002-7231-6042; Haszpra, László/0000-0002-7747-6475} } @article{MTMT:3042991, title = {Recrystallization-induced oxygen isotope changes in inclusion-hosted water of speleothems - Paleoclimatological implications}, url = {https://m2.mtmt.hu/api/publication/3042991}, author = {Demény, Attila and Czuppon, György and Kern, Zoltán and Leél-Őssy, Szabolcs and Németh, Alexandra and Szabó, Máté Zoltán and Tóth, Mária and Wu, C-C and Shen, C-C and Molnár, Mihály and Németh, Tibor and Németh, Péter and Óvári, Mihály}, doi = {10.1016/j.quaint.2015.11.137}, journal-iso = {QUATERN INT}, journal = {QUATERNARY INTERNATIONAL}, volume = {415}, unique-id = {3042991}, issn = {1040-6182}, abstract = {The issue of diagenetic alteration of carbonate deposits in caves (speleothems) has gained increasing importance in recent years, as this process has serious consequences for speleothem-based paleoclimate studies. In this study stable hydrogen and oxygen isotope data of water trapped in fluid inclusions were collected for recently forming stalagmites and flowstones in order to determine how dripwater compositions are reflected and preserved in the inclusion water compositions. Hydrogen isotope compositions were found to reflect dripwater values, whereas the oxygen isotope data were increasingly shifted from the local dripwater compositions with the time elapsed after deposition. The δ18O data are correlated with X-Ray diffraction full width at half maximum values (related to crystal domain size and lattice strain), suggesting that the oxygen isotope shift is related to recrystallization of calcite. Transmission electron microscope analyses detected the presence of nanocrystalline (<50 nm) calcite, whose crystallization to coarser-grained calcite crystals (>200 nm) may have induced re-equilibration between the carbonate and the trapped inclusion water. The Ostwald ripening process provides an explanation for unexpectedly low oxygen isotope compositions in the inclusion water. The detected diagenetic alteration and its isotopic effects should be taken into consideration during sampling strategies and data evaluation as speleothems containing nanocrystalline calcite during their deposition are prone to late-stage oxygen isotope water-carbonate re-equilibration, which may shift the oxygen isotope composition of the inclusion water to more depleted values while the hydrogen isotope composition remains intact. © 2016.}, keywords = {fluid inclusion; speleothem; diagenesis; Ostwald ripening; Hydrogen and oxygen isotope compositions}, year = {2016}, eissn = {1873-4553}, pages = {25-32}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018; Czuppon, György/0000-0002-7231-6042; Kern, Zoltán/0000-0003-4900-2587; Németh, Tibor/0000-0002-1836-6006; Németh, Péter/0000-0001-5592-5877} } @article{MTMT:25772139, title = {Zirconolite, zircon and monazite-(Ce) U-Th-Pb age constraints on the emplacement, deformation and alteration history of the Cummins Range Carbonatite Complex, Halls Creek Orogen, Kimberley region, Western Australia}, url = {https://m2.mtmt.hu/api/publication/25772139}, author = {Downes, PJ and Dunkley, DJ and Fletcher, IR and McNaughton, NJ and Rasmussen, B and Jaques, AL and Verrall, M and Sweetapple, MT}, doi = {10.1007/s00710-015-0418-y}, journal-iso = {MINER PETROL}, journal = {MINERALOGY AND PETROLOGY}, volume = {110}, unique-id = {25772139}, issn = {0930-0708}, year = {2016}, eissn = {1438-1168}, pages = {199-222} } @article{MTMT:25368451, title = {Precise oxygen and hydrogen isotope determination in nanoliter quantities of speleothem inclusion water by cavity ring-down spectroscopic techniques}, url = {https://m2.mtmt.hu/api/publication/25368451}, author = {Uemura, R and Nakamoto, M and Asami, R and Mishima, S and Gibo, M and Masaka, K and Jin-Ping, C and Wu, CC and Chang, YW and Shen, CC}, doi = {10.1016/j.gca.2015.09.017}, journal-iso = {GEOCHIM COSMOCHIM AC}, journal = {GEOCHIMICA ET COSMOCHIMICA ACTA}, volume = {172}, unique-id = {25368451}, issn = {0016-7037}, year = {2016}, eissn = {1872-9533}, pages = {159-176} } @article{MTMT:2876571, title = {Lézerspektroszkópia: új technika a hidrológiai és paleoklíma-kutatás területén}, url = {https://m2.mtmt.hu/api/publication/2876571}, author = {Demény, Attila}, journal-iso = {MAGYAR TUDOMÁNY}, journal = {MAGYAR TUDOMÁNY}, volume = {176}, unique-id = {2876571}, issn = {0025-0325}, year = {2015}, eissn = {1588-1245}, pages = {462-469}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018} } @{MTMT:2956911, title = {Temperature and humidity changes at the beginning of the last interglacial reflected by combined H and O isotope compositions of inclusion-hosted water}, url = {https://m2.mtmt.hu/api/publication/2956911}, author = {Demény, Attila and Czuppon, György and Siklósy, Zoltán and Leel-Ossy, S and Lin, K and Shen, CC and Vennemann, TW}, booktitle = {ESIR Isotope Workshop XIII}, unique-id = {2956911}, year = {2015}, pages = {33-34}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018; Czuppon, György/0000-0002-7231-6042} } @article{MTMT:2920469, title = {Hungarian National Report on IAVCEI (2011-2014)}, url = {https://m2.mtmt.hu/api/publication/2920469}, author = {Dobosi, Gábor and Harangi, Szabolcs}, journal-iso = {GEOMAT KÖZL}, journal = {GEOMATIKAI KÖZLEMÉNYEK / PUBLICATIONS IN GEOMATICS}, volume = {18}, unique-id = {2920469}, issn = {1419-6492}, year = {2015}, pages = {137-145}, orcid-numbers = {Harangi, Szabolcs/0000-0003-2372-4581} } @article{MTMT:2780250, title = {Stable H–C–O isotope and trace element geochemistry of the Cummins Range Carbonatite Complex, Kimberley region, Western Australia: implications for hydrothermal REE mineralization, carbonatite evolution and mantle source regions}, url = {https://m2.mtmt.hu/api/publication/2780250}, author = {Downes, PJ and Demény, Attila and Czuppon, György and Lynton, Jaques A and Verrall, M and Sweetapple, M and Adams, D and McNaughton, NJ and Gwalani, LG and Griffin, BJ}, doi = {10.1007/s00126-014-0552-1}, journal-iso = {MINER DEPOSITA}, journal = {MINERALIUM DEPOSITA}, volume = {49}, unique-id = {2780250}, issn = {0026-4598}, year = {2014}, eissn = {1432-1866}, pages = {905-932}, orcid-numbers = {Demény, Attila/0000-0003-0522-9018; Czuppon, György/0000-0002-7231-6042} }