TY - JOUR AU - Kónya, Krisztina AU - Pajtás, Dávid AU - Kiss, Attila AU - Patonay, Tamás TI - Buchwald–Hartwig Reactions of Monohaloflavones JF - EUROPEAN JOURNAL OF ORGANIC CHEMISTRY J2 - EUR J ORG CHEM VL - 2015 PY - 2015 IS - 4 SP - 828 EP - 839 PG - 12 SN - 1434-193X DO - 10.1002/ejoc.201403108 UR - https://m2.mtmt.hu/api/publication/2873077 ID - 2873077 AB - The article describes the amination of different monobromoor monochloroflavones with primary and secondary alkylamines and aniline derivatives by Buchwald–Hartwig reaction. The influence of the phosphine ligands used is described. The use of amino acid derivatives as a nitrogen source is also demonstrated. This latter reaction allows the synthesis of unique flavone–amino-acid conjugates. LA - English DB - MTMT ER - TY - JOUR AU - Fekete, S AU - Patonay, Tamás AU - Silva, AMS AU - Cavaleiro, JAS TI - A new synthesis of novel alkenylated flavones by palladium-catalyzed cross-coupling reactions JF - ARKIVOC J2 - ARKIVOC VL - 2012 PY - 2012 IS - 5 SP - 210 EP - 225 PG - 16 SN - 1551-7012 DO - 10.3998/ark.5550190.0013.519 UR - https://m2.mtmt.hu/api/publication/2211109 ID - 2211109 AB - Bromoflavones were treated with various terminal alkynes in palladium-catalyzed cross-coupling reactions under phosphine-free condions to give the expected alkenylated flavones in moderate to good yields. The presence of two different beta hydrogens in the terminal alkene led to the formation of both alkenylated and alkylated products. LA - English DB - MTMT ER -