TY - JOUR AU - Keresztesi, Ágnes AU - Ion-Andrei, Nita AU - Marius-Victor, Birsan AU - Bodor, Zsolt AU - Pernyeszi, Tímea Judit AU - Miruna, Mihaela Micheu AU - Szép, Róbert TI - Assessing the variations in the chemical composition of rainwater and air masses using the zonal and meridional index JF - ATMOSPHERIC RESEARCH J2 - ATMOS RES VL - 237 PY - 2020 PG - 16 SN - 0169-8095 DO - 10.1016/j.atmosres.2020.104846 UR - https://m2.mtmt.hu/api/publication/31156817 ID - 31156817 LA - English DB - MTMT ER - TY - JOUR AU - Szép, Róbert AU - Bodor, Zsolt AU - Miklóssy, Ildikó AU - Niță, I-A AU - Oprea, OA AU - Keresztesi, Ágnes TI - Influence of peat fires on the rainwater chemistry in intra-mountain basins with specific atmospheric circulations (Eastern Carpathians, Romania) JF - SCIENCE OF THE TOTAL ENVIRONMENT J2 - SCI TOTAL ENVIRON VL - 647 PY - 2019 SP - 275 EP - 289 PG - 15 SN - 0048-9697 DO - 10.1016/j.scitotenv.2018.07.462 UR - https://m2.mtmt.hu/api/publication/3403706 ID - 3403706 AB - A comprehensive study on the chemical composition of precipitation, the influence of peat fires and their relations with atmospheric circulation was conducted in the year of 2012, in two intra-mountain basins, the Ciuc basin (CB) and the Giurgeu basin (GB), Eastern Carpathians, Romania. Atmospheric circulation types showed the presence of a westerly anticyclonic circulation, characterized by a strong development of the Azores High to the northern Atlantic, contributing to the appearance of peat-fires. Using ROCADA daily gridded climatic datasets, the maximum and minimum daily temperatures were extracted, showing deviation from 2 degrees C to 6 degrees C in the studied year against the multiannual mean for the 1981-2016 period. Rainwater samples were analyzed for pH, major anions and cations; HCO3- concentrations were calculated based on the empirical relationship between pH and HCO3-. The results showed that 45.16% and 54.55% of precipitation had pH > 7.0 at CB and GB, respectively. NH3, NH4+ and Ca2+ are the main neutralizing agents. The significant correlation between SO42- and NH4+ (r = 0.711 - CB; r = 0.736 - GB) indicated neutralization by NH3 in the forms of (NH4)(2)SO4 and NH4HSO4. Positive regression coefficient between the sum of (H+ + [NH4+] + [Ca2+]) and the sum of ([nss - SO42-] + [NO3-]) (r = 0.855 CB; r = 0.796 - GB), showed that acid neutralization was primarily brought by NH4+ and/or CaCO3. Using Na as an indicator of marine origin, the proportions of sea salt and non-sea-salt were estimated fromelemental ratios. According to correlation analysis and PCA, main acidic ions (SO42- and NO3-) and NH4+ were mainly derived from anthropogenic activities (biomass burning, peat fires, fertilization), while Ca2+ and Mg2+ originated from terrestrial sources. The behavior of gaseous pollutants and smoke distribution resulted from peat fires were deciphered using the HYSPLIT model in a case study. (c) 2018 Elsevier B.V. All rights reserved. LA - English DB - MTMT ER - TY - JOUR AU - Szép, Róbert AU - Elena, Mateescu AU - Aurelia, Cristina Nechifor AU - Keresztesi, Ágnes TI - Chemical characteristics and source analysis on ionic composition of rainwater collected in the Carpathians "Cold Pole", Ciuc basin, Eastern Carpathians, Romania JF - ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH J2 - ENVIRON SCI POLLUT R VL - 24 PY - 2017 IS - 35 SP - 27288 EP - 27302 PG - 15 SN - 0944-1344 DO - 10.1007/s11356-017-0318-2 UR - https://m2.mtmt.hu/api/publication/3282406 ID - 3282406 LA - English DB - MTMT ER -