TY  - JOUR
AU  - Szatmári, István
AU  - Hetényi, Anasztázia
AU  - Lázár, László
AU  - Fülöp, Ferenc
TI  - Transformation reactions of the Betti base analog aminonaphthols
JF  - JOURNAL OF HETEROCYCLIC CHEMISTRY
J2  - J HETEROCYCLIC CHEM
VL  - 41
PY  - 2004
IS  - 3
SP  - 367
EP  - 373
PG  - 7
SN  - 0022-152X
DO  - 10.1002/jhet.5570410310
UR  - https://m2.mtmt.hu/api/publication/1013250
ID  - 1013250
AB  - By means of simple or domino ring-closure reactions of 1-(alpha-aminobenzyl)-2-naphthol (Betti base: 1), 1-aminomethyl-2-naplithol (2) and 2-(alpha-aminobenzyl)-1-naphthol (reverse Berri base: 3) with phosgene, ethyl benzimidate, 2-carboxybenzaldehyde, levulinic acid, salicylaldehyde/formalin or salicylaldehyde/acetaldehyde, naphth[1,2-e][1,3]oxazine and naphth[2,1-e][1,3]oxazine derivatives were prepared. All of the nitrogen-bridged polycyclic derivatives of 1 and 3 containing a number of centers of asymmetry were formed with nearly complete diastereoselectivity. Considerable differences were observed in the ring-closing abilities of the unsubstituted and phenyl-substituted aminonaphthols 1 and 2 and of the regioisomeric compounds 1 and 3.
LA  - English
DB  - MTMT
ER  -