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The role of the active oxide, its contribution to\nthe perimeter along the gold nanoparticles has been interpreted. The\noxide may invoke electronic interaction and simultaneously the defect\nstructure of oxides likely has a key issue in the formation and\nstabilization of very small Au particles. The activity of the Au/oxide\nperimeter depends not only on the size of the Au particles, but also on\nthe size and morphology of the oxide component (likely amorphous\nstructure) regardless of whether it is supporting Au nanoparticles or\ndecorating them. The activity in CO oxidation over Au catalysts is\nstrongly affected by the length of the Au/\"active\" oxide perimeter\nwhich is regarded as the \"active interface\". 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