TY - JOUR AU - Kéki, Sándor AU - Magyar, I AU - Beck, Mihály AU - Gáspár, Vilmos TI - Modeling the oscillatory bromate oxidation of ferroin in open systems JF - JOURNAL OF PHYSICAL CHEMISTRY US J2 - J PHYS CHEM US VL - 96 PY - 1992 SP - 1725 EP - 1729 PG - 5 SN - 0022-3654 DO - 10.1021/j100183a042 UR - https://m2.mtmt.hu/api/publication/1002156 ID - 1002156 AB - A model for the ferroin-bromate-bromide-sulfuric acid system in a continuously stirred (flow-through) tank reactor has been constructed by extending the Noyes-Field-Thompson mechanism with the following composite processes: (a) ferroin-bromate, (b) ferroin-bromous acid, (c) ferroin-hypobromous acid, (d) ferroin-bromine, (e) feriin-bromide, and (f) ferriin-bromine. The calculated high amplitude oscillations and kinetic phase diagram are in good accordance with the experiments reported earlier. By completing the scheme with a reaction step accounting for the precipitation and dissolution of a ferroin-tribromide salt, the batch oscillations found at high concentrations of reactants can also be simulated. LA - English DB - MTMT ER - TY - JOUR AU - Gyorgyi, L AU - Turányi, Tamás AU - Field, R J TI - Mechanistic details of the oscillatory Belousov-Zhabotinskii reaction JF - JOURNAL OF PHYSICAL CHEMISTRY US J2 - J PHYS CHEM US VL - 94 PY - 1990 IS - 18 SP - 7162 EP - 7170 PG - 9 SN - 0022-3654 DO - 10.1021/j100381a039 UR - https://m2.mtmt.hu/api/publication/1064315 ID - 1064315 LA - English DB - MTMT ER - TY - JOUR AU - GYORGYI, L AU - Oltiné Varga, Margit AU - KOROS, E AU - FIELD, RJ AU - RUOFF, P TI - SIMULATIONS OF THE IODIDE-ION PERTURBED UNCATALYZED BELOUSOV-ZHABOTINSKII OSCILLATOR WITH 1-HYDROXY-4-(2-(METHYLAMINO)PROPYL)BENZENE JF - JOURNAL OF PHYSICAL CHEMISTRY US J2 - J PHYS CHEM US VL - 93 PY - 1989 IS - 7 SP - 2836 EP - 2842 PG - 7 SN - 0022-3654 DO - 10.1021/j100344a027 UR - https://m2.mtmt.hu/api/publication/1485705 ID - 1485705 N1 - Admin megjegyzés-24644578 #JournalID1# Name: JOURNAL OF PHYSICAL CHEMISTRY ISSN: 0022-3654 #JournalID2# LA - English DB - MTMT ER - TY - JOUR AU - Ruoff, Péter AU - Oltiné Varga, Margit AU - Kőrös, Endre TI - HOW BROMATE OSCILLATORS ARE CONTROLLED JF - ACCOUNTS OF CHEMICAL RESEARCH J2 - ACCOUNTS CHEM RES VL - 21 PY - 1988 IS - 9 SP - 326 EP - 332 PG - 7 SN - 0001-4842 DO - 10.1021/ar00153a002 UR - https://m2.mtmt.hu/api/publication/1767487 ID - 1767487 N1 - Department of Chemistry, Rogaland University Center, Ullandhaug N-4004 Stavanger, Norway Institute of Inorganic and Analytical Chemistry, L. Eötvös University, H-1443 Budapest, Hungary Cited By :33 Export Date: 16 September 2019 Correspondence Address: Ruoff, P.; Department of Biological Sciences, Michigan Technological University, Houghton, MI 49931, United States LA - English DB - MTMT ER -