TY  - CHAP
AU  - Gáspár, Vilmos
AU  - Kéki, Sándor
AU  - Beck, Mihály
ED  - KLTE, (rend. közread.)
TI  - Role of one- and two electron steps in the mechanism of ferroin-bromate reaction
T2  - International Conference on Dynamics of Exotic Phenomena in Chemistry
PB  - Kossuth Lajos Tudományegyetem (KLTE)
CY  - Debrecen
SN  - 9634716229
PY  - 1989
SP  - 251
UR  - https://m2.mtmt.hu/api/publication/1002100
ID  - 1002100
LA  - English
DB  - MTMT
ER  - 

TY  - JOUR
AU  - Gáspár, Vilmos
AU  - Bazsa, György
AU  - Beck, Mihály
TI  - Bistability and bromide-controlled oscillation during bromate oxidation of ferroin in a continuous flow stirred tank reactor.
JF  - JOURNAL OF PHYSICAL CHEMISTRY US
J2  - J PHYS CHEM US
VL  - 89
PY  - 1985
IS  - 25
SP  - 5495
EP  - 5499
PG  - 5
SN  - 0022-3654
DO  - 10.1021/j100271a036
UR  - https://m2.mtmt.hu/api/publication/1002030
ID  - 1002030
N1  - Cited By :17            
            Export Date: 5 March 2020            
            Correspondence Address: Beck, M.T.; Department of Physical Chemistry, Institute of Chemistry, Kossuth Lajos University, Pf.7., Debrecen, 4010, Hungary
AB  - Autocatalytic oxidation of Fe(phen)32+ (ferroin) by bromate has been investigated in a continuous flow stirred tank reactor (CSTR). A closed region of bistability exitst in the plot of input stream concentrations of ferroin and bromate. The bromate-ferroin-bromide systems exhibits bistability and high amplitude oscillations over a broad range of concentrations. As a first approximation a revised Oregonator type model extended by reactions of ferroin and ferriin describes the system. However, further reactions have to be taken into consideration for a quantitative description.
LA  - English
DB  - MTMT
ER  - 

TY  - JOUR
AU  - Orbán, Miklós
AU  - P, De Kepper
AU  - I R, Epstein
TI  - Systematic design of chemical oscillators. 10. The Minimal Bromate Oscillator: Bromate-Bromide-Catalyst
JF  - JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
J2  - J AM CHEM SOC
VL  - 104
PY  - 1982
IS  - 9
SP  - 2657
EP  - 2658
PG  - 2
SN  - 0002-7863
DO  - 10.1021/ja00373a063
UR  - https://m2.mtmt.hu/api/publication/1293928
ID  - 1293928
N1  - Cited By :56            
            Export Date: 18 October 2023            
            Correspondence Address: Epstein, I.R.; Department of Chemistry, , Waltham, Massachusetts 02254, United States
LA  - English
DB  - MTMT
ER  - 

TY  - JOUR
AU  - Beck, Mihály
AU  - Bazsa, György
AU  - Hauck, K
TI  - Periodic reaction between bromate and ferroin
JF  - BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS
J2  - BER BUNSEN PHYS CHEM
VL  - 84
PY  - 1980
SP  - 408
SN  - 0005-9021
DO  - 10.1002/bbpc.19800840423/abstract
UR  - https://m2.mtmt.hu/api/publication/1001987
ID  - 1001987
LA  - English
DB  - MTMT
ER  - 

TY  - JOUR
AU  - E, Kőrös
AU  - M, Burger
AU  - V, Friedrich
AU  - L, Ladányi
AU  - Ungvárainé, Nagy Zsuzsa
AU  - Orbán, Miklós
TI  - Chemistry of Belousov-Type Oscillating Reactions
JF  - FARADAY DISCUSSIONS OF THE CHEMICAL SOCIETY
J2  - FARADAY DISCUSS CHEM
VL  - 9
PY  - 1974
SP  - 28
EP  - 37
PG  - 10
SN  - 0301-7249
DO  - 10.1039/FS9740900028
UR  - https://m2.mtmt.hu/api/publication/1293900
ID  - 1293900
AB  - The heat output and the accumulation of monobromomalonic acid during chemical oscillation in the bromate, malonic acid, sulphuric acid and catalyst [Ce(III), Mn(II), Fe(phen)2+3, Ru(dipy)2+3] systems were measured and the results interpreted. The behaviour of the reacting oscillating systems depends to a certain extent on the catalyst applied. Both the rate of heat evolution and the rate of accumulation of monobromomalonic acid are periodic. The heat of the cerium-catalysed Belousov oscillating reaction is 130 ± 5 kJ mol–1 bromate.
LA  - English
DB  - MTMT
ER  -