@article{MTMT:34802495, title = {Lewis Acid-Catalyzed Tandem Reaction Strategy for the Synthesis of Dihydrophenalene-Fused Lactones}, url = {https://m2.mtmt.hu/api/publication/34802495}, author = {OuYang, Mingjing and OuYang, Jiewen and Dong, Yibin and Li, Jinwei and Yang, Wen}, doi = {10.1021/acs.joc.4c00314}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34802495}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904}, orcid-numbers = {Yang, Wen/0000-0002-3166-4171} } @article{MTMT:34794428, title = {Synthesis of 3,4,5-Trisubstituted 1,2,4-Triazoles via I2-Catalyzed Cycloaddition of Amidines with Hydrazones}, url = {https://m2.mtmt.hu/api/publication/34794428}, author = {Li, X. and Yuan, X. and Wu, Y. and Guo, H. and Liu, Q. and Huang, S.}, doi = {10.1021/acs.joc.3c02637}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34794428}, issn = {0022-3263}, abstract = {A general and practical method for the construction of various 3,4,5-trisubstituted 1,2,4-triazoles via I2-catalyzed cycloaddition of N-functionalized amidines with hydrazones is reported. This strategy features cheap and readily available catalyst and starting materials, broader substrate scope, and moderate-to-good yields. The mechanism study shows that the existence of hydrogen on the nitrogen of hydrazones is crucial for this transformation. © 2024 American Chemical Society.}, keywords = {CATALYSIS; hydrazones; Cycloadditions; Functionalized; Organic compounds; General method; Practical method; Mechanism studies; ]+ catalyst}, year = {2024}, eissn = {1520-6904} } @article{MTMT:34789389, title = {NBS-Promoted Synthesis of Thiocyanated Aminomaleimides and Site-Selective Intramolecular Cyclization Access to 1,4-Benzothiazepines via S–CN Bond Cleavage}, url = {https://m2.mtmt.hu/api/publication/34789389}, author = {Yang, Qi and Huang, Shuntao and Yin, Lu and Wang, Zhuoyu and Chen, Xuebing and Huang, Chao}, doi = {10.1021/acs.joc.3c02607}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34789389}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904}, orcid-numbers = {Chen, Xuebing/0000-0002-1936-1274; Huang, Chao/0000-0003-1214-6608} } @article{MTMT:34778896, title = {Computational Studies on the Diastereospecific Lithium Variant of Oppenauer Oxidation of a Tofisopam Intermediate}, url = {https://m2.mtmt.hu/api/publication/34778896}, author = {Ábrányi-Balogh, Péter and Molnárné Samu, Erika and Pánczél, János K. and Benkő, Zoltán and Simig, Gyula and Volk, Balázs}, doi = {10.1021/acs.joc.3c02660}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34778896}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904}, orcid-numbers = {Benkő, Zoltán/0000-0001-6647-8320; Simig, Gyula/0000-0002-2569-6476; Volk, Balázs/0000-0002-2019-1874} } @article{MTMT:34769989, title = {Regioselective Fluorohydrin Synthesis from Allylsilanes and Evidence for a Silicon–Fluorine Gauche Effect}, url = {https://m2.mtmt.hu/api/publication/34769989}, author = {Clover, Alexie W. and Jones, Adam P. and Berger, Robert F. and Kaminsky, Werner and O’Neil, Gregory. W.}, doi = {10.1021/acs.joc.3c02163}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34769989}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904}, orcid-numbers = {Berger, Robert F./0000-0002-2691-8667; Kaminsky, Werner/0000-0002-9100-4909; O’Neil, Gregory. W./0000-0002-1695-1906} } @article{MTMT:34766467, title = {Reductive Coupling of P(O)-H Compounds and Aldehydes for the General Synthesis of Phosphines and Phosphine Oxides}, url = {https://m2.mtmt.hu/api/publication/34766467}, author = {Wang, Jie and Xiao, Jing and Tang, Zi-Long and Lan, Dong-Hui and Han, Li-Biao}, doi = {10.1021/acs.joc.3c02678}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34766467}, issn = {0022-3263}, abstract = {A novel strategy for the selective construction of a C(sp(3))-P(III) or -P(V) bond from >P(O)-H compounds and aldehydes is disclosed. By using the H3PO3/I-2 system, various secondary phosphine oxides could react with both aromatic and aliphatic aldehydes to afford valuable phosphines (isolated as sulfides) and phosphine oxides in good yields. This method features a wide substrate scope and simple reaction conditions and avoids the use of toxic halides and metals.}, keywords = {BOND FORMATION; BENZYL; metal-free}, year = {2024}, eissn = {1520-6904} } @article{MTMT:34757297, title = {Visible Light-Induced 1,2-Diphenyldisulfane-Mediated Defluoroborylation of Polyfluoroarenes}, url = {https://m2.mtmt.hu/api/publication/34757297}, author = {Pan, Q.-J. and Miao, Y.-Q. and Cao, H.-J. and Liu, Z. and Chen, X.}, doi = {10.1021/acs.joc.4c00286}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34757297}, issn = {0022-3263}, abstract = {A green and practical protocol of defluoroborylation of polyfluoroarenes with stable and readily accessible NHC-borane was developed, using 1,2-diphenyldisulfane as a hydrogen atom transfer (HAT) and single electron transfer (SET) reagent precursor under visible-light irradiation, leading to the concise formation of value-added fluorinated organoboron scaffolds. Mechanism studies revealed the method underwent a boryl radical addition reaction with polyfluoroarene, followed by successive single electron transfer pathways and defluorination of the C-F bond to offer the targeted product. This unprecedented platform relies on 1,2-diphenyldisulfane and base without using expensive photocatalysts, highlighting the methodology has promising application value to prepare borylated polyfluoroarene compounds. © 2024 American Chemical Society.}, keywords = {Atoms; SCAFFOLDS; Electron transitions; Free radical reactions; Addition reactions; VISIBLE-LIGHT IRRADIATION; Hydrogen atoms; organoboron; Mechanism studies; Single electron transfer; Electron transfer pathways; Transfer electrons; ATOM-TRANSFER; Visible light induced; Radical addition reactions}, year = {2024}, eissn = {1520-6904} } @article{MTMT:34746702, title = {Synthesis of C3-Substituted N1-tert-Butyl 1,2,4-Triazinium Salts via the Liebeskind-Srogl Reaction for Fluorogenic Labeling of Live Cells}, url = {https://m2.mtmt.hu/api/publication/34746702}, author = {Šlachtová, V. and Bellová, S. and Vrabel, M.}, doi = {10.1021/acs.joc.3c02454}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34746702}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904} } @article{MTMT:34715064, title = {Palladium-Catalyzed Chemoselective Phosphorylation of Poly(pseudo)halides: A Route for Organophosphorus Synthesis}, url = {https://m2.mtmt.hu/api/publication/34715064}, author = {Chen, Zicong and Pang, Wai Hang and Yuen, On Ying and Ng, Shan Shan and So, Chau Ming}, doi = {10.1021/acs.joc.3c02345}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34715064}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904}, orcid-numbers = {So, Chau Ming/0000-0001-6268-651X} } @article{MTMT:34684536, title = {One-Pot Reaction Sequence: N -Acylation/Pictet–Spengler Reaction/Intramolecular [4 + 2] Cycloaddition/Aromatization in the Synthesis of β-Carboline Alkaloid Analogues}, url = {https://m2.mtmt.hu/api/publication/34684536}, author = {Alekseeva, Kseniya A. and Fedoseeva, Milana A. and Bakhanovich, Olga V. and Khrustalev, Victor N. and Potkin, Vladimir I. and Zhou, Hongwei and Nikitina, Eugenia V. and Zaytsev, Vladimir P. and Zubkov, Fedor I.}, doi = {10.1021/acs.joc.3c02533}, journal-iso = {J ORG CHEM}, journal = {JOURNAL OF ORGANIC CHEMISTRY}, unique-id = {34684536}, issn = {0022-3263}, year = {2024}, eissn = {1520-6904}, orcid-numbers = {Zhou, Hongwei/0000-0001-8308-960X; Zaytsev, Vladimir P./0000-0001-9175-7583; Zubkov, Fedor I./0000-0002-0289-0831} }