@article{MTMT:34774127, title = {Melt Rheological and Bead Foaming Behavior of Recycled Polyethylene Terephthalate/Polybutylene Terephthalate Blends Modified with a Joncryl Chain Extender}, url = {https://m2.mtmt.hu/api/publication/34774127}, author = {Akdevelioğlu, Yavuz and Himmelsbach, Andreas and Ruckdäschel, Holger and Nofar, Mohammadreza}, doi = {10.1021/acs.iecr.3c03371}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, volume = {#}, unique-id = {34774127}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, pages = {#}, orcid-numbers = {Ruckdäschel, Holger/0000-0001-5985-2628; Nofar, Mohammadreza/0000-0002-4364-2930} } @article{MTMT:34770013, title = {Strengthened Poly(vinylidene fluoride)/Epoxidized Natural Rubber Blend by a Reactive Compatibilizer Based on an Amino Acid-Modified Fluorocarbon Elastomer}, url = {https://m2.mtmt.hu/api/publication/34770013}, author = {Kao-ian, Puntira and Banerjee, Shib Shankar and Yudha S, Salprima and Salaeh, Subhan}, doi = {10.1021/acs.iecr.3c04672}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, volume = {Előzetes kiadás / Early view}, unique-id = {34770013}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, orcid-numbers = {Banerjee, Shib Shankar/0000-0001-6785-2150; Salaeh, Subhan/0000-0001-7743-7997} } @article{MTMT:34748300, title = {Efficient Recovery of Itaconic Acid Using Weak and Strong Anion Exchange Resins from Aqueous Solutions}, url = {https://m2.mtmt.hu/api/publication/34748300}, author = {Can, Cihat Erdem and Zeidan, Hani and Marti, Mustafa Esen}, doi = {10.1021/acs.iecr.3c04158}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, volume = {&}, unique-id = {34748300}, issn = {0888-5885}, abstract = {Itaconic acid (IA) has the potential to be one of the industry’s most remarkable raw materials, but it must be recovered with high efficiency and selectivity from complex aqueous-based production media. In this study, three types of weak basic anion exchangers (WBAEs, Amberlite IRA-67, Lewatit MP-62, and Lewatit MP-64) and a strong basic anion exchanger (SBAE, Lewatit M-500) were tested for the separation of IA from aqueous solutions. The process was considerably affected by the operating pH, and the highest efficiencies were obtained at pH 3 and 4 with the WBAEs and SBAE, respectively. Equilibration was achieved in ∼60 min, and the data fitted the pseudo-second-order kinetic model for all resins tested. Decreasing yields with an increase in temperature confirmed the exothermic nature of the process. Isotherm curves demonstrated the consistency of the equilibrium data with Type I. The capacities increased with IA concentrations and decreased with resin doses. Lewatit MP-62 achieved the highest capacity (522.7 mg of IA/g of resin), and its performance was significantly better than those previously reported in the literature. The equilibrium data were in agreement with the Langmuir isotherm model; however, the R2 values attained with the Freundlich and Temkin models were also relatively high, indicating the need for further isotherm analyses.}, year = {2024}, eissn = {1520-5045}, orcid-numbers = {Zeidan, Hani/0000-0002-5891-3887; Marti, Mustafa Esen/0000-0002-9829-0602} } @article{MTMT:34724518, title = {Mechanism and Reaction Kinetics of Formaldehyde Oxidation on TiO 2 : Amorphous Hydroxylated Outperforms Anatase}, url = {https://m2.mtmt.hu/api/publication/34724518}, author = {Sun, Zhiguang and Zhu, Xiaobing and Li, Xiao-Song and Cai, Rui and Zhu, Ai-Min}, doi = {10.1021/acs.iecr.3c04334}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, unique-id = {34724518}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, orcid-numbers = {Sun, Zhiguang/0000-0002-5098-9983; Zhu, Xiaobing/0000-0003-1789-2546; Zhu, Ai-Min/0000-0002-4527-6372} } @article{MTMT:34652743, title = {Continuous Antisolvent Crystallization of L-Histidine: Impact of Process Parameters and Kinetic Estimation}, url = {https://m2.mtmt.hu/api/publication/34652743}, author = {Liu, Peng and Yang, Li and Ma, Yixin and Zhang, Yan and Wang, Haoliang and Cheng, Jingcai and Yang, Chao}, doi = {10.1021/acs.iecr.3c03870}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, unique-id = {34652743}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045} } @article{MTMT:34619271, title = {Assessment of PET Depolymerization Processes for Circular Economy. 1. Thermodynamics, Chemistry, Purification, and Process Design}, url = {https://m2.mtmt.hu/api/publication/34619271}, author = {McNeeley, Adam and Liu, Y. A.}, doi = {10.1021/acs.iecr.3c04000}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, unique-id = {34619271}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, orcid-numbers = {Liu, Y. A./0000-0002-8050-8343} } @article{MTMT:34556441, title = {Prediction of Alkyl Carbenium Ion Concentrations and Octane Number Increase in Heptane Hydroisomerization over a Pt/WO3/ZrO2 Catalyst}, url = {https://m2.mtmt.hu/api/publication/34556441}, author = {R., Sotelo-Boyás and M.D., Smolikov and V.A., Shkurenok and A.V., Lavrenov and A., González-Garay and J.L., Rosas-Trigueros and J.F., Cázares-Marroquín}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, volume = {63}, unique-id = {34556441}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, pages = {1784-1801} } @article{MTMT:34516513, title = {Antimigration Polypropylene Antioxidants: A Review}, url = {https://m2.mtmt.hu/api/publication/34516513}, author = {Li, Zijia and Zhang, Chunting and Jiang, Yu and Bai, Yiqing and Xu, Meng and Xu, Kai and Gao, Dali and Leroux, Fabrice and Feng, Yongjun}, doi = {10.1021/acs.iecr.3c03891}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, unique-id = {34516513}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, orcid-numbers = {Feng, Yongjun/0000-0001-9254-6219} } @article{MTMT:34736671, title = {Incorporating Phenolated Lignin into Polyurethane Materials: Impact on Mechanical, Thermal, and Adhesion Performance}, url = {https://m2.mtmt.hu/api/publication/34736671}, author = {Falireas, Panagiotis G. and Gracia-Vitoria, Jaime and Hensen, Andrea and Vanbroekhoven, Karolien and Vendamme, Richard}, doi = {10.1021/acs.iecr.3c03453}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, volume = {63}, unique-id = {34736671}, issn = {0888-5885}, year = {2024}, eissn = {1520-5045}, pages = {3921-3935}, orcid-numbers = {Falireas, Panagiotis G./0000-0002-3114-9989} } @article{MTMT:34681008, title = {Dynamic Modeling and Optimal Design Space Determination of Pharmaceutical Crystallization Processes: Realizing the Synergy between Off-the-Shelf Laboratory and Industrial Scale Data}, url = {https://m2.mtmt.hu/api/publication/34681008}, author = {Orosz, Álmos and Szilágyi, Emőke and Spaits, András and Borsos, Ákos and Farkas, Ferenc and Markovits, Imre and Százdi, László and Volk, Balázs and Kátainé Fadgyas, Katalin and Szilágyi, Botond}, doi = {10.1021/acs.iecr.3c03954}, journal-iso = {IND ENG CHEM RES}, journal = {INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH}, volume = {63}, unique-id = {34681008}, issn = {0888-5885}, abstract = {Well-designed and operated pharmaceutical crystallization can enhance the key features of the active pharmaceutical ingredients, which can be taken to the next level by a model-based design. Model development not only requires computer implementation, kinetic identification, and advanced programming skills but also a suitable number of information-rich experiments. Numerous products have been crystallized for a long time, with many related laboratory-scale experiments and plant-scale manufacturing data accumulated from past developments and productions. The question arises: can these historical data be utilized to build process models, which can be used subsequently to optimize processes? We aim to demonstrate in this study that this approach can be feasible. To illustrate this, we used the data of two commercial crystallization production campaigns, totaling 16 industrial crystallizations, and six laboratory experiments, four of which were formerly performed for different purposes. Our tailored PBM involves primary and secondary nucleation, crystal growth, and dissolution and can simultaneously reproduce laboratory- and plant-scale dynamics. Despite relying on nontargeted experiments and measuring/sampling strategy, the estimated parameters were accurate, with an average deviation between the nominal values and 95% confidence interval bonds of 16.1%. The model was employed to construct an optimal design space (DS) for a temperature cycling operation involving, as a constraint, 2, 3, and 4 cycles: the goal was to define a temperature domain with minimal batch time and heating/cooling energy demand that respects the constraints on the product PSD and heating/cooling rates. The problem was solved as a constrained robust optimization, where discrete temperature stamps and corresponding time stamps were optimized. The optimal operation halved the current batch time. The optimized temperature profile was validated on a laboratory scale for two particle size specifications. More expansive DS (1 vs 0.5 h random temperature variation allowed around the nominal temperature profile) was observed to translate to longer batch times (30 vs 25 h) and deeper temperature cycles of 40 vs 20 °C, reflecting a trade-off between nominal performance and robustness. The optimal laboratory-scale operation was validated successfully by repeated experiments. © 2024 American Chemical Society.}, keywords = {Temperature control; Optimal systems; Constrained optimization; particle size; Product design; Key feature; Laboratories; Industrial scale; Crystallization process; Temperature profiles; Economic and social effects; Batch time; Pharmaceutical crystallizations; Active pharmaceuticals ingredients; Dynamics models; Modeling designs; Optimal design space}, year = {2024}, eissn = {1520-5045}, pages = {4068-4082}, orcid-numbers = {Orosz, Álmos/0000-0003-0825-3275; Volk, Balázs/0000-0002-2019-1874; Szilágyi, Botond/0000-0001-7777-9612} }