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"/api/journal/185", "label" : "AICHE JOURNAL 0001-1541 1547-5905", "pIssn" : "0001-1541", "eIssn" : "1547-5905", "reviewType" : "REVIEWED", "noIF" : false, "sciIndexed" : true, "scopusIndexed" : true, "lang" : "FOREIGN", "hungarian" : false, "published" : true, "oldId" : 185, "snippet" : true }, "volume" : "9(2)", "firstPage" : "1", "firstPageOrInternalIdForSort" : "1", "publishedYear" : 2024, "abstractText" : "The partial hydrogenation of alkynes into alkenes constitutes a pivotal chemical transformation in the synthesis of fine chemicals, pharmaceuticals, and polymers. Nevertheless, the extant industrial catalyst falls short of achieving a felicitous equilibrium between its catalytic potency and selectivity. Herein, triphenylphosphine (PPh 3 ) modified Pd/Al 2 O 3 catalysts are fabricated through a “one‐pot” process, which achieve highly selective hydrogenation of alkynes at room temperature. PPh 3 plays a dual role—as a reducing agent and a ligand. Kinetic and characterization studies reveal PPh 3 alters H 2 activation from homolytic to heterolytic cleavage, which facilitate the formation of alkene. Moreover, PPh 3 can also optimize the reaction microenvironment, achieving the reduced self‐poisoning of alkyne and promoted desorption of alkene. In the realm of alkyne hydrogenation, our philosophy encompasses a global optimization of active sites, ligand systems, and reaction microenvironmental. This method steers the course of catalyst development for other reactions beyond the field of alkyne hydrogenation.", "digital" : true, "printed" : true, "sourceYear" : 2024, "foreignEdition" : true, "foreignLanguage" : true, "fullPublication" : true, "conferencePublication" : false, "nationalOrigin" : false, "missingAuthor" : false, "oaType" : "NONE", "oaCheckDate" : "2024-03-06", "oaFree" : false, "citationCount" : 0, "citationCountUnpublished" : 0, "citationCountWoOther" : 0, "independentCitCountWoOther" : 0, "doiCitationCount" : 0, "wosCitationCount" : 0, "scopusCitationCount" : 0, "independentCitationCount" : 0, "unhandledCitationCount" : 0, "citingPubCount" : 0, "independentCitingPubCount" : 0, "unhandledCitingPubCount" : 0, "citedPubCount" : 1, "citedCount" : 1, "ratings" : [ { "otype" : "SjrRating", "mtid" : 11447427, "link" : "/api/sjrrating/11447427", "label" : "sjr:Q1 (2024) Scopus - Chemical Engineering (miscellaneous) AICHE JOURNAL 0001-1541 1547-5905", "listPos" : 66, "rankValue" : 0.24, "type" : "journal", "ratingType" : { "otype" : "RatingType", "mtid" : 10002, "link" : "/api/ratingtype/10002", "label" : "sjr", "code" : "sjr", "published" : true, "snippet" : true }, "subject" : { "otype" : "ClassificationExternal", "mtid" : 1501, "link" : "/api/classificationexternal/1501", "label" : "Scopus - Chemical Engineering (miscellaneous)", "published" : true, "oldId" : 1501, "snippet" : true }, "ranking" : "Q1", "calculation" : "FROM_PREVIOUS_TO_LAST_YEAR", "published" : true, "snippet" : true } ], "ratingsForSort" : "Q1", "hasCitationDuplums" : false, "userChangeableUntil" : "2024-06-04T10:41:51.165+0000", "directInstitutesForSort" : "", "ownerAuthorCount" : 2, "ownerInstituteCount" : 9, "directInstituteCount" : 0, "authorCount" : 11, "contributorCount" : 0, "hasQualityFactor" : true, "link" : "/api/publication/34723507", "label" : "Wang Mingxuan et al. 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