@article{MTMT:34658399, title = {Enhanced inverted singlet-triplet gaps in azaphenalenes and non-alternant hydrocarbons}, url = {https://m2.mtmt.hu/api/publication/34658399}, author = {Garner, Marc H. and Blaskovits, J. Terence and Corminboeuf, Clemence}, doi = {10.1039/d3cc05747j}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, unique-id = {34658399}, issn = {1359-7345}, year = {2024}, eissn = {1364-548X}, orcid-numbers = {Blaskovits, J. Terence/0000-0002-1452-5508} } @article{MTMT:34651210, title = {Insights into interfacial mechanisms: CsPbBr3 nanocrystals as sustainable photocatalysts for primary amine oxidation}, url = {https://m2.mtmt.hu/api/publication/34651210}, author = {Ahlawat, Monika and Rao, Vishal Govind}, doi = {10.1039/d3cc05725a}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, unique-id = {34651210}, issn = {1359-7345}, year = {2024}, eissn = {1364-548X} } @article{MTMT:34594494, title = {α-Aryl substituted GdDOTA derivatives, the perfect contrast agents for MRI?}, url = {https://m2.mtmt.hu/api/publication/34594494}, author = {Maier, Karley B. and Rust, Lauren N. and Carniato, Fabio and Botta, Mauro and Woods, Mark}, doi = {10.1039/d3cc05989h}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, unique-id = {34594494}, issn = {1359-7345}, abstract = {Enhancing the performance of Gd3+ chelates as relaxation agents for MRI has the potential to lower doses, improving safety and mitigating the environmental impact on our surface waters. More than three decades of research into manipulating the properties of Gd3+ have failed to develop a chelate that simultaneously optimizes all relevant parameters and affords maximal relaxivity. Introducing aryl substituents into the alpha-position of the pendant arms of a GdDOTA chelate affords chelates that, for the first time, simultaneously optimize all physico-chemical properties. Slowing tumbling by binding to human serum albumin affords a relaxivity of 110 +/- 5 mM-1 s-1, close to the maximum possible. As discrete chelates, these alpha-aryl substituted GdDOTA chelates exhibit relaxivities that are 2-3 times higher than those of currently used agents, even at the higher fields (1.5 & 3.0 T) used in modern clinical MRI.Introducing aryl substituents into the alpha-position of the well-known GdDOTA affords chelates that have unprecedentedly high relaxivities and robustness.}, year = {2024}, eissn = {1364-548X} } @article{MTMT:34524715, title = {The Lewis Superacidic Aluminium Cation: [(NHC)Al(C6F5)2]+}, url = {https://m2.mtmt.hu/api/publication/34524715}, author = {Ju, S. and Zhang, C. and Tang, B. and Liu, L.L. and Stephan, D.W. and Wu, Y.}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, unique-id = {34524715}, issn = {1359-7345}, year = {2024}, eissn = {1364-548X}, pages = {698-701} } @article{MTMT:34437815, title = {Organophotocatalytic α-deuteration of unprotected primary amines via H/D exchange with D2O}, url = {https://m2.mtmt.hu/api/publication/34437815}, author = {Meng, X. and Dong, Y. and Liu, Q. and Wang, W.}, doi = {10.1039/d3cc04634f}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, volume = {60}, unique-id = {34437815}, issn = {1359-7345}, abstract = {We report a straightforward H/D exchange method for the synthesis of α-deuterated primary amines from a diverse set of primary amines with high levels of deuteration and chemo- and site selectivity and preparative utility. This cost-effective strategy enables the direct conversion of primary amines to α-deuterated counterparts using D2O as the deuterium source under mild reaction conditions without requiring additional functionality manipulation and with minimal byproduct production. © 2024 The Royal Society of Chemistry.}, keywords = {AMINES; DEUTERIUM; Chemo-selectivity; Cost effectiveness; Primary amines; DIRECT CONVERSION; Mild reaction conditions; H-D exchange; Cost effective strategies; site selectivity; Exchange methods; Deuterations}, year = {2024}, eissn = {1364-548X}, pages = {296-299} } @article{MTMT:34619878, title = {Synthesis of SiN/SiS-heterocycles via the reactions of a bis-silylene with isocyanate/isothiocyanate molecules}, url = {https://m2.mtmt.hu/api/publication/34619878}, author = {Liu, Rui and Mondal, Kartik Chandra and Wang, Chenfeng and Suthar, Sonam and Fang, Zijie and Zuo, Darui and Li, Yan}, doi = {10.1039/d3cc04950g}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, volume = {60}, unique-id = {34619878}, issn = {1359-7345}, abstract = {Reactions of o-carborane-fused bis-silylene 1 with isocyanate/isothiocyanate molecules furnished a series of SiN/SiS-heterocycles, which show distinct styles of cyclization and were theoretically studied.}, year = {2024}, eissn = {1364-548X}, pages = {1148-1151}, orcid-numbers = {Mondal, Kartik Chandra/0000-0002-5830-3608} } @article{MTMT:34600625, title = {Dopamine oxidation promoted by human telomeric DNA models in the presence of a Cu(ii) terpyridine chelate}, url = {https://m2.mtmt.hu/api/publication/34600625}, author = {Bao, Yu and Zhou, Wenqin and Miao, Wenhui and Jia, Guoqing and Li, Can}, doi = {10.1039/d3cc05530b}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, volume = {60}, unique-id = {34600625}, issn = {1359-7345}, abstract = {We found that under oxidative stress conditions, the coexistence of human telomeric DNA (HT-DNA) and a copper-terpyridine metallodrug can accelerate dopamine oxidation. The unwinding of HT-DNA from a duplex to cytosine-rich (C-rich) and guanine-rich (G-rich) single strands promotes dopamine oxidation in a general order of C-rich > G-rich > duplex. Along with dopamine oxidation, HT-DNA also undergoes severe damage.}, year = {2024}, eissn = {1364-548X}, pages = {1172-1175} } @article{MTMT:34659541, title = {The chemical logic of enzymatic lignin degradation}, url = {https://m2.mtmt.hu/api/publication/34659541}, author = {Bugg, Timothy D. H.}, doi = {10.1039/d3cc05298b}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, volume = {60}, unique-id = {34659541}, issn = {1359-7345}, year = {2024}, eissn = {1364-548X}, pages = {804-814} } @article{MTMT:34648757, title = {Recent progress in iodine capture by macrocycles and cages}, url = {https://m2.mtmt.hu/api/publication/34648757}, author = {Zhou, Weinan and Lavendomme, Roy and Zhang, Dawei}, doi = {10.1039/d3cc05337g}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, volume = {60}, unique-id = {34648757}, issn = {1359-7345}, year = {2024}, eissn = {1364-548X}, pages = {779-792}, orcid-numbers = {Zhou, Weinan/0000-0002-1378-863X; Lavendomme, Roy/0000-0001-6238-8491; Zhang, Dawei/0000-0002-0898-9795} } @article{MTMT:34607292, title = {Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks}, url = {https://m2.mtmt.hu/api/publication/34607292}, author = {Eckstein, Brian J. and Martin, Hannah R. and Moghadasnia, Michael P. and Halder, Arijit and Melville, Michael J. and Buzinski, Tara N. and Balaich, Gary J. and Mcguirk, C. Michael}, doi = {10.1039/d3cc05162e}, journal-iso = {CHEM COMMUN}, journal = {CHEMICAL COMMUNICATIONS}, volume = {60}, unique-id = {34607292}, issn = {1359-7345}, abstract = {Incremental, single-atom substitutions of Se-based chalcogen bond (Ch-bond) donors with stronger donating Te centers were implemented in two new triptycene tris(1,2,5-chalcogenadiazole) tectons. The appreciably more favorable Ch-bonding ability of the Te-based donors promotes assembly of low-density networks and more stable Ch-bonded organic frameworks (ChOFs).Systematic replacement of selenium for tellurium in a chalcogen-bonding tecton results in divergent assembly behavior from competitive solvents.}, year = {2024}, eissn = {1364-548X}, pages = {758-761}, orcid-numbers = {Halder, Arijit/0000-0002-4047-2593} }