@article{MTMT:34788699, title = {Tellurium and Nano-Tellurium: Medicine or Poison?}, url = {https://m2.mtmt.hu/api/publication/34788699}, author = {Sári, Daniella and Ferroudj , Aya and Semsey, Dávid and El-Ramady, Hassan and Brevik, Eric C. and Prokisch, József}, doi = {10.3390/nano14080670}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34788699}, abstract = {Tellurium (Te) is the heaviest stable chalcogen and is a rare element in Earth’s crust (one to five ppb). It was discovered in gold ore from mines in Kleinschlatten near the present-day city of Zlatna, Romania. Industrial and other applications of Te focus on its inorganic forms. Tellurium can be toxic to animals and humans at low doses. Chronic tellurium poisoning endangers the kidney, liver, and nervous system. However, Te can be effective against bacteria and is able to destroy cancer cells. Tellurium can also be used to develop redox modulators and enzyme inhibitors. Soluble salts that contain Te had a role as therapeutic and antimicrobial agents before the advent of antibiotics. The pharmaceutical use of Te is not widespread due to the narrow margin between beneficial and toxic doses, but there are differences between the measure of toxicity based on the Te form. Nano-tellurium (Te-NPs) has several applications: it can act as an adsorptive agent to remove pollutants, and it can be used in antibacterial coating, photo-catalysis for the degradation of dyes, and conductive electronic materials. Nano-sized Te particles are the most promising and can be produced in both chemical and biological ways. Safety assessments are essential to determine the potential risks and benefits of using Te compounds in various applications. Future challenges and directions in developing nano-materials, nano-alloys, and nano-structures based on Te are still open to debate.}, keywords = {Nano-medicine; nano-toxicity; medicinal attributes}, year = {2024}, eissn = {2079-4991}, orcid-numbers = {El-Ramady, Hassan/0000-0002-1113-726X; Brevik, Eric C./0000-0002-6004-0018} } @article{MTMT:34802642, title = {Engineered and Mimicked Extracellular Nanovesicles for Therapeutic Delivery}, url = {https://m2.mtmt.hu/api/publication/34802642}, author = {Poinsot, V. and Pizzinat, N. and Ong-Meang, V.}, doi = {10.3390/nano14070639}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34802642}, year = {2024}, eissn = {2079-4991} } @article{MTMT:34801218, title = {Incidence of the Brownian Relaxation Process on the Magnetic Properties of Ferrofluids}, url = {https://m2.mtmt.hu/api/publication/34801218}, author = {Vajtai, Lili and Nemes, Norbert Marcel and Morales, Maria del Puerto and Molnár, Kolos and Pinke, Balazs Gabor and Simon, Ferenc}, doi = {10.3390/nano14070634}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34801218}, abstract = {Ferrofluids containing magnetic nanoparticles represent a special class of magnetic materials due to the added freedom of particle tumbling in the fluids. We studied this process, known as Brownian relaxation, and its effect on the magnetic properties of ferrofluids with controlled magnetite nanoparticle sizes. For small nanoparticles (below 10 nm diameter), the Neel process is expected to dominate the magnetic response, whereas for larger particles, Brownian relaxation becomes important. Temperature- and magnetic-field-dependent magnetization studies, differential scanning calorimetry, and AC susceptibility measurements were carried out for 6 and 13.5 nm diameter magnetite nanoparticles suspended in water. We identify clear fingerprints of Brownian relaxation for the sample of large-diameter nanoparticles as both magnetic and thermal hysteresis develop at the water freezing temperature, whereas the samples of small-diameter nanoparticles remain hysteresis-free down to the magnetic blocking temperature. This is supported by the temperature-dependent AC susceptibility measurements: above 273 K, the data show a low-frequency Debye peak, which is characteristic of Brownian relaxation. This peak vanishes below 273 K.}, keywords = {NANOPARTICLES; Anisotropy; HYPERTHERMIA; Ferrofluid; Materials Science, Multidisciplinary; Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; MAGNETOMETRY; dipole interactions; Néel relaxation; Néel relaxation; Brownian relaxation}, year = {2024}, eissn = {2079-4991}, orcid-numbers = {Molnár, Kolos/0000-0002-9331-4652} } @article{MTMT:34777533, title = {Molecular Dynamics Study of Nanoribbon Formation by Encapsulating Cyclic Hydrocarbon Molecules inside Single-Walled Carbon Nanotube}, url = {https://m2.mtmt.hu/api/publication/34777533}, author = {Eskandari, Somayeh and Koltai, János and László, István and Kürti, Jenő}, doi = {10.3390/nano14070627}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34777533}, abstract = {Carbon nanotubes filled with organic molecules can serve as chemical nanoreactors. Recent experimental results show that, by introducing cyclic hydrocarbon molecules inside carbon nanotubes, they can be transformed into nanoribbons or inner tubes, depending on the experimental conditions. In this paper, we present our results obtained as a continuation of our previous molecular dynamics simulation work. In our previous work, the initial geometry consisted of independent carbon atoms. Now, as an initial condition, we have placed different molecules inside a carbon nanotube (18,0): C5H5 (fragment of ferrocene), C5, C5+H2; C6H6 (benzene), C6, C6+H2; C20H12 (perylene); and C24H12 (coronene). The simulations were performed using the REBO-II potential of the LAMMPS software package, supplemented with a Lennard-Jones potential between the nanotube wall atoms and the inner atoms. The simulation proved difficult due to the slow dynamics of the H abstraction. However, with a slight modification of the parameterization, it was possible to model the formation of carbon nanoribbons inside the carbon nanotube.}, year = {2024}, eissn = {2079-4991}, orcid-numbers = {Koltai, János/0000-0003-2576-9740; Kürti, Jenő/0000-0001-9752-2769} } @article{MTMT:34761133, title = {Recent Advances of VO2 in Sensors and Actuators}, url = {https://m2.mtmt.hu/api/publication/34761133}, author = {Darwish, Mahmoud Ibrahim Azmi and Zhabura, Yana and Pohl, László}, doi = {10.3390/nano14070582}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34761133}, abstract = {Vanadium dioxide (VO2) stands out for its versatility in numerous applications, thanks to its unique reversible insulator-to-metal phase transition. This transition can be initiated by various stimuli, leading to significant alterations in the material’s characteristics, including its resistivity and optical properties. As the interest in the material is growing year by year, the purpose of this review is to explore the trends and current state of progress on some of the applications proposed for VO2 in the field of sensors and actuators using literature review methods. Some key applications identified are resistive sensors such as strain, temperature, light, gas concentration, and thermal fluid flow sensors for microfluidics and mechanical microactuators. Several critical challenges have been recognized in the field, including the expanded investigation of VO2-based applications across multiple domains, exploring various methods to enhance device performance such as modifying the phase transition temperature, advancing the fabrication techniques for VO2 structures, and developing innovative modelling approaches. Current research in the field shows a variety of different sensors, actuators, and material combinations, leading to different sensor and actuator performance input ranges and output sensitivities.}, year = {2024}, eissn = {2079-4991}, orcid-numbers = {Pohl, László/0000-0003-2390-1381} } @article{MTMT:34786553, title = {Efficient and Selective Removal of Palladium from Simulated High-Level Liquid Waste Using a Silica-Based Adsorbent NTAamide(C8)/SiO2-P}, url = {https://m2.mtmt.hu/api/publication/34786553}, author = {Shi, J. and Wang, J. and Wang, W. and Wu, X. and Wang, H. and Li, J.}, doi = {10.3390/nano14060544}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34786553}, abstract = {In order to realize the effective separation of palladium from high-level liquid waste (HLLW), a ligand-supported adsorbent (NTAamide(C8)/SiO2-P) was prepared by the impregnation method in a vacuum. The SiO2-P carrier was synthesized by in situ polymerization of divinylbenzene and styrene monomers on a macroporous silica skeleton. The NTAamide(C8)/SiO2-P adsorbent was fabricated by impregnating an NTAamide(C8) ligand into the pore of a SiO2-P carrier under a vacuum condition. The adsorption performance of NTAamide(C8)/SiO2-P in nitric acid medium has been systematically studied. In a solution of 0.2 M HNO3, the distribution coefficient of Pd on NTAamide(C8)/SiO2-P was 1848 mL/g with an adsorption percentage of 90.24%. With the concentration of nitric acid increasing, the adsorption capacity of NTAamide(C8)/SiO2-P decreases. Compared to the other 10 potential interfering ions in fission products, NTAamide(C8)/SiO2-P exhibited excellent adsorption selectivity for Pd(II). The separation factor (SFPd/other metals > 77.8) is significantly higher than that of similar materials. The interference of NaNO3 had a negligible effect on the adsorption performance of NTAamide(C8)/SiO2-P, which maintained above 90%. The adsorption kinetics of Pd(II) adsorption on NTAamide(C8)/SiO2-P fits well with the pseudo-second order model. The Sips model is more suitable than the Langmuir and Freundlich model for describing the adsorption behavior. Thermodynamic analysis showed that the adsorption of Pd(II) on NTAamide(C8)/SiO2-P was a spontaneous, endothermic, and rapid process. NTAamide(C8)/SiO2-P also demonstrated good reusability and economic feasibility. © 2024 by the authors.}, year = {2024}, eissn = {2079-4991} } @article{MTMT:34768723, title = {“Polymerization” of Bimerons in Quasi-Two-Dimensional Chiral Magnets with Easy-Plane Anisotropy}, url = {https://m2.mtmt.hu/api/publication/34768723}, author = {Mukai, N. and Leonov, A.O.}, doi = {10.3390/nano14060504}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34768723}, year = {2024}, eissn = {2079-4991} } @article{MTMT:34761436, title = {Enhanced Stability of Oral Vitamin C Delivery: A Novel Large-Scale Method for Liposomes Production and Encapsulation through Dynamic High-Pressure Microfluidization}, url = {https://m2.mtmt.hu/api/publication/34761436}, author = {Romano, Eugenia and Palladino, Roberta and Cannavale, Mariagabriella and Lamparelli, Erwin Pavel and Maglione, Barbara}, doi = {10.3390/nano14060516}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34761436}, abstract = {In recent years, nanocarriers have been widely used as an effective solution for oral administration of pharmaceuticals. However, there is still an urgent need to speed up their translation to clinical practice. Cost-effective and industrially scalable methodologies are still needed. Herein, the production of vitamin C-loaded liposomes for nutraceutical purposes has been investigated and optimized by adopting a High-Pressure Homogenizer. Initially, the impact of process parameters on particles size, distributions, and morphology was explored. The findings document that the pressure and cycle manipulation allow for control over liposome size and polydispersity, reaching a maximum encapsulation efficiency exceeding 80%. This significantly improves the storage stability of vitamin C, as demonstrated by monitoring its antioxidant activity. Furthermore, the in vitro simulation of gastrointestinal digestion shows that liposomes could protect the active substance from damage and control its release in the gastrointestinal fluid. Thus, the whole nanodelivery system can contribute to enhancing vitamin C bioavailability. In conclusion, the results indicate that this innovative approach to producing vitamin C liposomes holds promise for clinical translation and industrial scale-up. Indeed, by utilizing food-grade materials and straightforward equipment, it is possible to produce stable and functional liposomes suitable for health products.}, year = {2024}, eissn = {2079-4991}, pages = {516}, orcid-numbers = {Romano, Eugenia/0000-0002-1500-6478; Palladino, Roberta/0009-0002-7508-5152} } @article{MTMT:34737048, title = {Automated Monitoring System for Suspended Photocatalytic Batch Reactions Based on Online Circulatory Spectrophotometry}, url = {https://m2.mtmt.hu/api/publication/34737048}, author = {Lei, Da-Peng and Huang, Jian-Hua}, doi = {10.3390/nano14060508}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34737048}, abstract = {Employing an automated monitoring system (AMS) for data acquisition offers benefits, such as reducing the workload, in the kinetic study of suspended photocatalytic batch reactions. However, the current methods in this field tend to narrowly focus on the substrate and often overlook the optical characteristics of both the mixture and solid particles. To address this limitation, in this study, we propose a novel AMS based on online circulatory spectrophotometry (OCS) and incorporate debubbling, aeration, and segmented flow (DAS), named DAS-OCS-AMS. Initially, a debubbler is introduced to mitigate the issue of signal noise caused by bubbles (SNB). Subsequently, an aerated and segmented device is developed to address the issue of particle deposition on the inner wall of the pipeline (PDP) and on the windows of the flow cell (PDW). The proposed DAS-OCS-AMS is applied to monitor the kinetics of the photocatalytic degradation of Acid Orange Ⅱ by TiO2 (P25), and its results are compared with those obtained using the traditional OCS-AMS. The comparative analysis indicates that the proposed DAS-OCS-AMS effectively mitigates the influence of SNB, PDP, and PDW, yielding precise results both for the mixture and solid particles. The DAS-OCS-AMS provides a highly flexible universal framework for online circulatory automated monitoring and a robust hardware foundation for subsequent data processing research.}, year = {2024}, eissn = {2079-4991}, pages = {508}, orcid-numbers = {Lei, Da-Peng/0000-0002-6983-3217} } @article{MTMT:34815420, title = {Defects and Defect Engineering of Two-Dimensional Transition Metal Dichalcogenide (2D TMDC) Materials}, url = {https://m2.mtmt.hu/api/publication/34815420}, author = {Hossen, M.F. and Shendokar, S. and Aravamudhan, S.}, doi = {10.3390/nano14050410}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {14}, unique-id = {34815420}, year = {2024}, eissn = {2079-4991} }