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The understanding of the thermodynamic stability and speciation of metal complexes in solution requires access to their enthalpy and entropy of formation. In this work, we specifically focus our investigation on the complexation process of silver(I) ion in acetonitrile (AN) with substituted mono pyridines and cyclic monoamines. The aim of this study is to provide reliable thermodynamic data to obtain insights on metal complex formation, focusing on ligands donor properties and solvation effects. Carefully designed potentiometric and calorimetric experiments allowed to define the species present at different ligand/metal ratios and to obtain the complex formation constants and enthalpies. In general, the enthalpy terms associated with the complex formation are highly exothermic, while the entropy values are always unfavorable. The formation constants of AgL j species for the ligands investigated in AN are compared with those previously obtained in dimethyl sulfoxide (DMSO) and water. The trends in stability constants and enthalpy values are discussed in relation to the p K a data available in the different solvents. Higher p K a values correspond to greater ligand basicity and result in more stable and more enthalpy stabilized complexes.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Sanadar, Martina </span> <span class="author-type"> </span> ; <span class="author-name" > Kovačević, Anđela </span> <span class="author-type"> </span> ; <span class="author-name" > Cracchiolo, Maria </span> <span class="author-type"> </span> ; <span class="author-name" > Melchior, Andrea </span> <span class="author-type"> </span> ; <span class="author-name" > Tolazzi, Marilena </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;34753162" mtid="34753162" target="_blank">Thermodynamics of complex formation of silver(I) with substituted pyridines and cyclic amines in non-aqueous solvents</a></div> <div class="pub-info"> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-volume"></span> <span class="page"> </span> <span class="year">(2024)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:black" title="10.1007/s10973-024-12894-2" target="_blank" href="https://doi.org/10.1007/s10973-024-12894-2"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="001169823500004" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/001169823500004"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="https://link.springer.com/10.1007/s10973-024-12894-2" target="_blank" href="https://link.springer.com/10.1007/s10973-024-12894-2"> Egyéb URL </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:34753162 </span> <span class="status-holder"><span class="status-data status-APPROVED"> Nyilvános </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Sanadar Martina </span> ; <span class="author-name" >Kovačević Anđela </span> ; <span class="author-name" >Cracchiolo Maria </span> ; <span class="author-name" >Melchior Andrea </span> ; <span class="author-name" >Tolazzi Marilena </span> </div> </div> <div class="title"><a href="/gui2/?mode=browse¶ms=publication;34753162" target="_blank">Thermodynamics of complex formation of silver(I) with substituted pyridines and cyclic amines in non-aqueous solvents</a></div> <div> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-issn">(<a target="_blank" href="https://portal.issn.org/resource/ISSN/1388-6150">1388-6150</a> <a target="_blank" href="https://portal.issn.org/resource/ISSN/1572-8943">1572-8943</a>)</span>: <span class="journal-volume"></span> <span class="page"> </span> <span class="year">(2024)</span> </div> <div class="pub-footer"> <span class="language" xmlns="http://www.w3.org/1999/html">Nyelv: Angol | </span> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:black" title="10.1007/s10973-024-12894-2" target="_blank" href="https://doi.org/10.1007/s10973-024-12894-2"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="001169823500004" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/001169823500004"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="https://link.springer.com/10.1007/s10973-024-12894-2" target="_blank" href="https://link.springer.com/10.1007/s10973-024-12894-2"> Egyéb URL </a> </span> </span> <div class="publication-citation"> <a target="_blank" href="/api/publication?cond=citations.related;eq;34753162&sort=publishedYear,desc&sort=title"> Idézett közlemények száma: 1 </a> </div> <div class="mtid"><span class="long-pub-mtid">Közlemény: 34753162</span> | <span class="status-data status-APPROVED"> Nyilvános </span> Idéző | <span class="type-subtype">Folyóiratcikk ( Szakcikk ) </span> | <span class="pub-category">Tudományos</span> | <span class="publication-sourceOfData">kézi felvitel</span> </div> <div class="lastModified">Utolsó módosítás: 2024.03.23. 10:20 Csontné Kiricsi Mónika (Biokémia) </div> </div></div>
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Passive cooling techniques have gained widespread use in everyday life and various industries by utilizing sunlight reflection to cool objects without requiring additional energy input. Porous polymer materials possess the unique ability to provide both thermal insulation and solar reflection due to their inherent multiphase structure. In this study, we developed a porous polypropylene (PP) with a hierarchically structured surface layer using a simple and efficient solvent treatment method based on recrystallization. As a result, the porous structure and hierarchically structured surface significantly increase the solar reflectance from 11 to 86%. We found that by manipulating the recrystallization process and using reflective additives, solar reflectivity can be further improved. With the use of TiO2 and BaSO4 additives, a solar reflectance of 90% was achieved, while a solar reflectance of 93% was achieved with nucleating agents. In practical terms, these improvements result in significant temperature reductions in cooling performance tests compared to extruded PP sheets: 17, 19, and 22 degrees C for porous PP, porous PP/TiO2 or PP/BaSO4, and porous nucleated PP, respectively. The modification method introduced could help PP offer new possibilities for developing low-cost chemically resistant and thermally insulating layers in thermal management applications.
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" mtid="10081617"> <a href="/gui2/?type=authors&mode=browse&sel=10081617" target="_blank">Vamos, Csenge ✉</a> </span> <span class="author-type"> </span> ; <span class="author-name" mtid="10001066"> <a href="/gui2/?type=authors&mode=browse&sel=10001066" target="_blank">Barany, Tamas</a> </span> <span class="author-type"> </span> ; <span class="author-name" > Marosfoi, Botond Bela </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;34727226" mtid="34727226" target="_blank">Porous polypropylene produced by phase separation for high solar reflectivity and passive cooling</a></div> <div class="pub-info"> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-volume">Előzetes kiadás / Early view</span> <span class="page"> , 13 p. </span> <span class="year">(2024)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_GOLD" title=" Gold "> <a style="color:blue" title="10.1007/s10973-024-12891-5" target="_blank" href="https://doi.org/10.1007/s10973-024-12891-5"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="001169816400002" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/001169816400002"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85187265691" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85187265691"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:34727226 </span> <span class="status-holder"><span class="status-data status-APPROVED"> Nyilvános </span></span> <span class="pub-core">Forrás </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list">
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<span class="authorAux-mtmt"> Polimertechnika/Anyag- és gyártástudomány</span>)
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<span class="author-affil"><span title="Budapesti Műszaki és Gazdaságtudományi Egyetem">BME</span>/<span title="Gépészmérnöki Kar">GPK</span>/Polimertechnika Tanszék</span>
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<span class="authorAux-mtmt"> Polimer anyagtudomány és technológia</span>)
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;34727226" target="_blank">Porous polypropylene produced by phase separation for high solar reflectivity and passive cooling</a></div> <div> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span>
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<div class="lastModified">Utolsó módosítás: 2024.03.16. 07:28 Fülöp Tamás (BME GPK admin5)
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<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Funding Agency and Grant Number: Ministry of Culture and Innovation of Hungary
Funding text: No Statement Available</pre>
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The heat pulse (flash) experiment is a well-known, widely used method to determine thermal diffusivity. However, for heterogeneous, highly porous materials, neither the measurement nor the evaluation methodologies are straightforward. In the present paper, we focus on two open-cell carbon foam types, differing in their porosity but having the same sample size. Recent experiments showed that a non-Fourier behavior, called ’over-diffusive’ propagation, can be present for such a complex structure. The (continuum) Guyer–Krumhansl equation stands as a promising candidate to model such transient thermal behavior. In order to obtain a reliable evaluation and thus reliable thermal parameters, we utilize a novel, state-of-the-art evaluation procedure developed recently using an analytical solution of the Guyer–Krumhansl equation. Based on our observations, it turned out that the presence of high porosity alone is necessary but not satisfactory for non-Fourier behavior. Additionally, the mentioned non-Fourier effects are porosity-dependent; however, porous samples can also follow the Fourier law on a particular time scale. These data serve as a basis to properly identify the characteristic heat transfer mechanisms and their corresponding time scales, which altogether result in the present non-Fourier behavior. Based on these, we determined the validity region of Fourier’s law in respect of time scales.
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China Academy of Safety Science and Technology, Beijing, 100012, China
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Correspondence Address: Zhou, K.; Faculty of Engineering, Hubei, China; email: zhoukq@cug.edu.cn
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Wei, Qi </span> <span class="author-type"> </span> ; <span class="author-name" > Zhang, Jiale </span> <span class="author-type"> </span> ; <span class="author-name" > Cheng, Yulong </span> <span class="author-type"> </span> ; <span class="author-name" > Xie, Zhehan </span> <span class="author-type"> </span> ; <span class="author-name" > Liu, Yingting </span> <span class="author-type"> </span> ; <span class="author-name" > Zhou, Keqing </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;34686204" mtid="34686204" target="_blank">Surface modification of MXene nanosheets with P-N-containing agents for boosting flame retardancy of epoxy resin</a></div> <div class="pub-info"> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-volume"></span> <span class="page"> </span> <span class="year">(2024)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:black" title="10.1007/s10973-024-12938-7" target="_blank" href="https://doi.org/10.1007/s10973-024-12938-7"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="85185678453" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85185678453"> Scopus </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="https://link.springer.com/10.1007/s10973-024-12938-7" target="_blank" href="https://link.springer.com/10.1007/s10973-024-12938-7"> Egyéb URL </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:34686204 </span> <span class="status-holder"><span class="status-data status-APPROVED"> Nyilvános </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list">
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;34686204" target="_blank">Surface modification of MXene nanosheets with P-N-containing agents for boosting flame retardancy of epoxy resin</a></div> <div> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span>
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<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Faculty of Engineering, China University of Geosciences (Wuhan), Hubei, Wuhan, 430074, China
School of Mechanical and Automotive Engineering, South China University of Technology, Wushan Road 381, Guangzhou, 510641, China
China Academy of Safety Science and Technology, Beijing, 100012, China
Export Date: 4 March 2024 ...</pre>
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Department of Mechanical Engineering, Mechanical Engineering Faculty, Yildiz Technical University, Istanbul, Turkey
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Correspondence Address: Natarajan, M.; Department of Thermal and Energy Engineering, Tamilnadu, India; email: m.natarajan@vit.ac.in
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<pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Megjegyzés</u>: Department of Thermal and Energy Engineering, School of Mechanical Engineering, Vellore Institute of Technology, VIT, Tamilnadu, Vellore, 632014, India
Department of Mechanical Engineering, College of Engineering, King Khalid University, PO Box 394, Abha, 61421, Saudi Arabia
Energy Centre, Maulana Azad National Institute of Technology (MANIT), M.P...</pre>
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Kumar, Sushil </span> <span class="author-type"> </span> ; <span class="author-name" > Kumar, Raj ✉ </span> <span class="author-type"> </span> ; <span class="author-name" > Thakur, Robin </span> <span class="author-type"> </span> ; <span class="author-name" > Kumar, Sushil </span> <span class="author-type"> </span> ; <span class="author-name" > Lee, Daeho ✉ </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;34638584" mtid="34638584" target="_blank">Effects of climate variables and nanofluid-based cooling on the efficiency of a liquid spectrum filter-based concentrated photovoltaic thermal system</a></div> <div class="pub-info"> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-volume"></span> <span class="page"> , 19 p. </span> <span class="year">(2024)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1007/s10973-023-12836-4" target="_blank" href="https://doi.org/10.1007/s10973-023-12836-4"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="001145878900002" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/001145878900002"> WoS </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:34638584 </span> <span class="status-holder"><span class="status-data status-VALIDATED"> Egyeztetett </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list">
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<div class="title"><a href="/gui2/?mode=browse¶ms=publication;34638584" target="_blank">Effects of climate variables and nanofluid-based cooling on the efficiency of a liquid spectrum filter-based concentrated photovoltaic thermal system</a></div> <div> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span>
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<div class="JournalArticle Publication short-list"> <div class="authors"> <span class="author-name" > Zhao, Y </span> <span class="author-type"> </span> ; <span class="author-name" > Liu, XM </span> <span class="author-type"> </span> </div ><div class="title"><a href="/gui2/?mode=browse¶ms=publication;34634033" mtid="34634033" target="_blank">Entransy dissipation thermal resistance for asphalt pavement and application in optimization of cooling structure</a></div> <div class="pub-info"> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-volume"></span> <span class="page"> , 17 p. </span> <span class="year">(2024)</span> </div> <div class="pub-end"><div class="identifier-list"> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1007/s10973-023-12834-6" target="_blank" href="https://doi.org/10.1007/s10973-023-12834-6"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="001153910100001" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/001153910100001"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85183668376" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85183668376"> Scopus </a> </span> </span> </div> <div class="short-pub-prop-list"> <span class="short-pub-mtid"> Közlemény:34634033 </span> <span class="status-holder"><span class="status-data status-ADMIN_APPROVED"> Admin láttamozott </span></span> <span class="pub-core"> Idéző </span> <span class="pub-type">Folyóiratcikk (Szakcikk ) </span> <!-- && !record.category.scientific --> <span class="pub-category">Tudományos</span> </div> </div> </div><div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" >Zhao Y </span> ; <span class="author-name" >Liu XM </span> </div> </div> <div class="title"><a href="/gui2/?mode=browse¶ms=publication;34634033" target="_blank">Entransy dissipation thermal resistance for asphalt pavement and application in optimization of cooling structure</a></div> <div> <span class="journal-title">JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY</span> <span class="journal-issn">(<a target="_blank" href="https://portal.issn.org/resource/ISSN/1388-6150">1388-6150</a> <a target="_blank" href="https://portal.issn.org/resource/ISSN/1572-8943">1572-8943</a>)</span>: <span class="journal-volume"></span> <span class="page"> 17 p. </span> <span class="year">(2024)</span> </div> <div class="pub-footer"> <span class="language" xmlns="http://www.w3.org/1999/html">Nyelv: Angol | </span> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1007/s10973-023-12834-6" target="_blank" href="https://doi.org/10.1007/s10973-023-12834-6"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="001153910100001" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/001153910100001"> WoS </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85183668376" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85183668376"> Scopus </a> </span> </span> <div class="publication-citation"> <a target="_blank" href="/api/publication?cond=citations.related;eq;34634033&sort=publishedYear,desc&sort=title"> Idézett közlemények száma: 1 </a> </div> <div class="mtid"><span class="long-pub-mtid">Közlemény: 34634033</span> | <span class="status-data status-ADMIN_APPROVED"> Admin láttamozott </span> Idéző | <span class="type-subtype">Folyóiratcikk ( Szakcikk ) </span> | <span class="pub-category">Tudományos</span> | <span class="publication-sourceOfData">WOS TAGGED</span> </div> <div class="lastModified">Utolsó módosítás: 2024.03.01. 13:52 Tomcsik Adrienn (Wigner admin5) </div> </div></div>