TY - JOUR AU - Macedo, V.M. AU - Barbosa, J.C. AU - Salazar, H. AU - Fidalgo-Marijuan, A. AU - Gajjala, R.K.R. AU - Almásy, László AU - Gonçalves, B.F. AU - Petrenko, V.I. AU - Silva, M.M. AU - Gonçalves, R. AU - Costa, C.M. AU - Lanceros-Mendez, S. TI - Enhanced performance of solid polymer electrolytes combining poly(vinylidene fluoride-co-hexafluoropropylene), metal-organic framework and ionic liquid for advanced solid state lithium-ion batteries JF - JOURNAL OF ENERGY STORAGE J2 - J ENERGY STORAGE VL - 90 A PY - 2024 SN - 2352-152X DO - 10.1016/j.est.2024.111919 UR - https://m2.mtmt.hu/api/publication/34835398 ID - 34835398 AB - The search for sustainable and high-performance materials for lithium-ion batteries is leading to significant advances in solid polymer electrolyte (SPE) technology. However, the current drawbacks of this approach prove the need for further research and development in the field. Herein, novel ternary solid polymer electrolytes have been developed using varying loads of MOF-808 metal-organic framework and [BMIM][SCN] ionic liquid (IL) incorporated in a poly(vinylidene fluoride-co-hexafluoropropylene) matrix. The solid polymer electrolytes were evaluated at morphological, structural, thermal, mechanical and electrochemical levels, and their performance in cycling battery testing was assessed. The results showed a homogeneous structure throughout all the samples and a good dispersion of the distinct components. The polymer polar phase and degree of crystallinity of the samples are increased with increasing IL content, and the thermal and mechanical properties are appropriate for battery application. The ionic conductivity of the samples reaches maximum values of 4.68 × 10−5 S‧cm−1 at room temperature, lithium transference numbers up to 0.65, and high electrochemical stability, making them well-suited for battery applications. The assembled stability after 50 cycles at C/10 with a discharge capacity value of 150 mAh‧g−1 at room temperature was tested/derived. The obtained results show the potential of this system for high performance room temperature solid polymer electrolytes. LA - English DB - MTMT ER - TY - JOUR AU - Murmiliuk, Anastasiia AU - Iwase, Hiroki AU - Kang, Jia-Jhen AU - Mohanakumar, Shilpa AU - Appavou, Marie-Sousai AU - Wood, Kathleen AU - Almásy, László AU - Len, Adél AU - Schwärzer, Kuno AU - Allgaier, Jürgen AU - Dulle, Martin AU - Gensch, Thomas AU - Förster, Beate AU - Ito, Kanae AU - Nakagawa, Hiroshi AU - Wiegand, Simone AU - Förster, Stephan AU - Radulescu, Aurel TI - Polyelectrolyte-protein synergism: pH-responsive polyelectrolyte/insulin complexes as versatile carriers for targeted protein and drug delivery JF - JOURNAL OF COLLOID AND INTERFACE SCIENCE J2 - J COLLOID INTERF SCI VL - 665 PY - 2024 SP - 801 EP - 813 PG - 13 SN - 0021-9797 DO - 10.1016/j.jcis.2024.03.156 UR - https://m2.mtmt.hu/api/publication/34763681 ID - 34763681 LA - English DB - MTMT ER - TY - JOUR AU - Ecsédi, Bertold AU - Forgács, Attila AU - Balogh, Zoltán AU - Fábián, István AU - Kalmár, József TI - Hydration and wetting mechanism of borosilicate – Polyvinyl alcohol (PVA) hybrid aerogels of potential bioactivity JF - JOURNAL OF MOLECULAR LIQUIDS J2 - J MOL LIQ VL - 401 PY - 2024 PG - 8 SN - 0167-7322 DO - 10.1016/j.molliq.2024.124605 UR - https://m2.mtmt.hu/api/publication/34763386 ID - 34763386 LA - English DB - MTMT ER - TY - JOUR AU - Kouznetsova, T. AU - Ivanets, A. AU - Prozorovich, V. AU - Shornikova, P. AU - Kapysh, L. AU - Tian, Q. AU - Péter, László AU - Trif, László AU - Almásy, László TI - Design of Nickel-Containing Nanocomposites Based on Ordered Mesoporous Silica: Synthesis, Structure, and Methylene Blue Adsorption JF - GELS (BASEL) J2 - GELS-BASEL VL - 10 PY - 2024 IS - 2 PG - 15 SN - 2310-2861 DO - 10.3390/gels10020133 UR - https://m2.mtmt.hu/api/publication/34751383 ID - 34751383 N1 - Export Date: 29 April 2024 LA - English DB - MTMT ER - TY - JOUR AU - Bajnok, Katalin AU - Kovács, Zoltán AU - Nagy, Anna Andrea TI - Better late (Roman) than never! A possible amphora fragment from 6th century Balatonlelle, Western Hungary JF - ARCHEOMETRIAI MŰHELY J2 - ARCHEOMETRIAI MŰHELY VL - 21 PY - 2024 IS - 2 SP - 201 EP - 216 PG - 16 SN - 1786-271X DO - 10.55023/issn.1786-271X.2024-016 UR - https://m2.mtmt.hu/api/publication/34750995 ID - 34750995 AB - This study reports on a unique finding connected to the re-examination of the ceramic assemblage recovered from the Langobard age (6th century AD) settlement of Balatonlelle, situated in the territory of the former Roman province of Pannonia (now in western Hungary). An undecorated body sherd, not picked up by either the initial typological evaluation of the ceramics or by the preliminary petrographic analysis, was now reassessed by thin section ceramic petrography and scanning electron microscopy. The new analyses revealed that this sherd contains rock and mineral inclusions originated from ophiolites, including slightly serpentinised peridotite fragments. Such rocks do not occur on the surface in Hungary, whereas they are commonly found in the Eastern Mediterranean. The presence of ophiolites in the potsherd indicates that this vessel was produced in a distant territory. The macroscopic characteristics of the sherd combined with its petrographic fingerprint suggest that this pot might have been a transport amphora produced in the Eastern Mediterranean. Although rarely found in Pannonia in the Migration Period, several amphora types, including the most frequently found LRA 1 type, were produced in numerous production centres in the Eastern Mediterranean, in territories geologically congruous with the aplastic inclusions found in the fabric of the Balatonlelle sherd. The significance of this finding is that from Langobard age Pannonia, amphorae occur only sporadically, connected mainly to former Roman settlements. While any conclusions drawn from a single sherd must necessarily remain tentative, this sherd nonetheless provides some material evidence for the existence of some sort of contact between Balatonlelle and the Eastern Mediterranean during the 6th century, be it economic, political or cultural. This study also aims to celebrate the career of György Szakmány, who was one of the key figures to establish ceramic petrographic research and education in Hungary, and trained many generations of petrographers – including the present authors. As such, it also serves as an example how ceramic petrography can bring a new dimension of information to archaeological research. LA - English DB - MTMT ER - TY - JOUR AU - Balogh, Zoltán AU - Kalmár, József AU - Gommes, Cedric J. TI - Wetting of alginate aerogels, from mesoporous solids to hydrogels: a small-angle scattering analysis JF - JOURNAL OF APPLIED CRYSTALLOGRAPHY J2 - J APPL CRYSTALLOGR VL - 57 PY - 2024 IS - 2 SP - 369 EP - 379 PG - 11 SN - 0021-8898 DO - 10.1107/S1600576724001705 UR - https://m2.mtmt.hu/api/publication/34655160 ID - 34655160 N1 - Accepted on 20-Febr-2024. Published on-line on 21-March-2024. LA - English DB - MTMT ER - TY - JOUR AU - Kherais, Mohammad AU - Csébfalvi, Anikó Borbála AU - Len, Adél AU - Fülöp, Attila AU - Pál-Schreiner, Judit TI - The effect of moisture content on the mechanical properties of wood structure JF - POLLACK PERIODICA: AN INTERNATIONAL JOURNAL FOR ENGINEERING AND INFORMATION SCIENCES J2 - POLLACK PERIODICA VL - 19 PY - 2024 SP - 41 EP - 46 PG - 6 SN - 1788-1994 DO - 10.1556/606.2023.00917 UR - https://m2.mtmt.hu/api/publication/34569274 ID - 34569274 AB - In the last two decades, the utilization of timber in construction has gained increasing attention among researchers and sustainable building designers. Therefore, studies of climate impact on timber structures have been conducted, many of them focusing on the moisture content caused changes in timber. In the present study, four-point bending tests have been performed on three testing groups, containing 30 samples each. The first group has been tested under its natural conditions, while the second and the third groups were fully saturated with water. The third group was glazed with a protection material. The results show the changes in the modulus of elasticity and the modulus of rupture caused by the moisture content increase. In the same time the material behavior changed from brittle to semi-ductile or ductile for some samples. LA - English DB - MTMT ER - TY - JOUR AU - Li, Tao AU - Zhang, Yuhua AU - Guan, Yijia AU - He, Qilong AU - Cheng, Dongyang AU - Almásy, László AU - Lu, Dan AU - Kjelstrup-Hansen, Jakob AU - Knaapila, Matti TI - The development of poly(9,9-dioctylfluorene) from solutions to solution processed films in terms of β-conformation: Perspective of molecular weight and solvent quality JF - POLYMER J2 - POLYMER VL - 295 PY - 2024 PG - 14 SN - 0032-3861 DO - 10.1016/j.polymer.2024.126748 UR - https://m2.mtmt.hu/api/publication/34569273 ID - 34569273 AB - We report how the solution structure, β-conformation and film morphology develop in poly(9,9-dioctylfluorene) (PFO) solutions and suspensions, as well as in subsequently prepared films when the molecular weight and solvent quality are systematically varied in toluene-acetone mixtures. The polymer series with molecular weights ranging from 10 kDa to 100 kDa is prepared using the precipitation fraction. The β conformation is favored by increasing molecular weight (≥30 kDa) and decreasing solvent quality (≥45 % acetone content). The content of the β conformation in the films is significantly increased when the β conformation already exists in precursor suspensions. In contrast, when there is no β conformation in the precursor solution, no β conformation will appear in the films. The mechanisms of phenomenological transformation are discussed. This work is a step toward developing quantitative guidelines for controlling PFO solutions and their film properties. LA - English DB - MTMT ER - TY - JOUR AU - Rogozhkin, S.V. AU - Klauz, A.V. AU - Ke, Y. AU - Almásy, László AU - Nikitin, A.A. AU - Khomich, A.A. AU - Bogachev, A.A. AU - Gorshkova, Y.E. AU - Bokuchava, G.D. AU - Kopitsa, G.P. AU - Sun, L. TI - Study of Precipitates in Oxide Dispersion-Strengthened Steels by SANS, TEM, and APT JF - NANOMATERIALS J2 - NANOMATERIALS-BASEL VL - 14 PY - 2024 IS - 2 SN - 2079-4991 DO - 10.3390/nano14020194 UR - https://m2.mtmt.hu/api/publication/34555223 ID - 34555223 AB - In this work, the nanostructure of oxide dispersion-strengthened steels was studied by small-angle neutron scattering (SANS), transmission electron microscopy (TEM), and atom probe tomography (APT). The steels under study have different alloying systems differing in their contents of Cr, V, Ti, Al, and Zr. The methods of local analysis of TEM and APT revealed a significant number of nanosized oxide particles and clusters. Their sizes, number densities, and compositions were determined. A calculation of hardness from SANS data collected without an external magnetic field, or under a 1.1 T field, showed good agreement with the microhardness of the materials. The importance of taking into account two types of inclusions (oxides and clusters) and both nuclear and magnetic scattering was shown by the analysis of the scattering data. © 2024 by the authors. LA - English DB - MTMT ER - TY - JOUR AU - Balogh, Zoltán AU - Len, Adél AU - Baksa, Viktória AU - Krajnc, Andraž AU - Herman, Petra AU - Szemán-Nagy, Gábor AU - Czigány, Zsolt AU - Fábián, István AU - Kalmár, József AU - Dudás, Zoltán Imre TI - Nanoscale structural characteristics and in vitro bioactivity of borosilicate – polyvinyl alcohol (PVA) hybrid aerogels for bone regeneration JF - ACS APPLIED NANO MATERIALS J2 - ACS APPL NANO MATER VL - 7 PY - 2024 IS - 4 SP - 4092 EP - 4102 PG - 11 SN - 2574-0970 DO - 10.1021/acsanm.3c05668 UR - https://m2.mtmt.hu/api/publication/34538335 ID - 34538335 LA - English DB - MTMT ER -