@article{MTMT:34538415, title = {Hybrid Bio-Nanocomposites by Integrating Nanoscale Au in Butterfly Scales Colored by Photonic Nanoarchitectures}, url = {https://m2.mtmt.hu/api/publication/34538415}, author = {Kertész, Krisztián Imre and Piszter, Gábor and Vargáné Beck, Andrea and Horváth, Anita and Nagy, G. and Molnár, György and Radnóczi, György Zoltán and Horváth, Zsolt Endre and Illés, Levente and Biró, László Péter}, doi = {10.3390/photonics10111275}, journal-iso = {PHOTONICS-BASEL}, journal = {PHOTONICS}, volume = {10}, unique-id = {34538415}, year = {2023}, eissn = {2304-6732}, orcid-numbers = {Kertész, Krisztián Imre/0000-0001-8004-9135; Piszter, Gábor/0000-0001-7155-4025; Molnár, György/0000-0002-4792-5516; Radnóczi, György Zoltán/0000-0002-7106-6272; Horváth, Zsolt Endre/0000-0002-4632-0136; Biró, László Péter/0000-0001-7261-0420} } @article{MTMT:34524708, title = {Magas hőmérsékleteken oxidált krómbevonatos Zr burkolatminták elektronsugaras vizsgálatai}, url = {https://m2.mtmt.hu/api/publication/34524708}, author = {Pintérné Csordás, Anna and Illés, Levente and Perez-Feró, Erzsébet and Novotny, Tamás and Hózer, Zoltán and Stuckert, J and Sevecek, M}, journal-iso = {ANYAGVIZSGÁLÓK LAPJA}, journal = {ANYAGVIZSGÁLÓK LAPJA}, unique-id = {34524708}, issn = {1215-8410}, year = {2023}, eissn = {1787-5072}, pages = {11-26}, orcid-numbers = {Hózer, Zoltán/0000-0001-6518-6297} } @article{MTMT:34189377, title = {Performance of Zr-Based Metal–Organic Framework Materials as In Vitro Systems for the Oral Delivery of Captopril and Ibuprofen}, url = {https://m2.mtmt.hu/api/publication/34189377}, author = {Cretu, C. and Nicola, R. and Marinescu, S.-A. and Picioruș, E.-M. and Suba, M. and Duda-Seiman, C. and Len, Adél and Illés, Levente and Horváth, Zsolt Endre and Putz, A.-M.}, doi = {10.3390/ijms241813887}, journal-iso = {INT J MOL SCI}, journal = {INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES}, volume = {24}, unique-id = {34189377}, issn = {1661-6596}, year = {2023}, eissn = {1422-0067}, orcid-numbers = {Horváth, Zsolt Endre/0000-0002-4632-0136} } @article{MTMT:33641673, title = {Ion-induced nanopattern formation in FeRh thin films}, url = {https://m2.mtmt.hu/api/publication/33641673}, author = {Merkel, Dániel and Hegedűs, Gergő and Gracheva, Maria and Deák, András and Illés, Levente and Németh, Attila and Maccari, F. and Radulov, I. and Major, Márton and Chumakov, A. I. and Bessas, D. and Nagy, Dénes Lajos and Zolnai, Zsolt and Graning, S. and Sájerman, K. and Szilágyi, Edit and Lengyel, Attila}, journal-iso = {ESRF HIGHLIGHTS}, journal = {ESRF HIGHLIGHTS}, volume = {2022}, unique-id = {33641673}, year = {2023}, pages = {28-29}, orcid-numbers = {Gracheva, Maria/0000-0001-5245-8425; Deák, András/0000-0002-2526-1245; Major, Márton/0000-0001-6074-6144; Nagy, Dénes Lajos/0000-0002-6790-9505; Zolnai, Zsolt/0000-0003-3457-7679} } @article{MTMT:33366417, title = {Spectral Engineering of Hybrid Biotemplated Photonic/Photocatalytic Nanoarchitectures}, url = {https://m2.mtmt.hu/api/publication/33366417}, author = {Piszter, Gábor and Kertész, Krisztián Imre and Kovács, Dávid and Zámbó, Dániel and Baji, Zsófia and Illés, Levente and Nagy, Gergely and Pap, József Sándor and Bálint, Zsolt and Biró, László Péter}, doi = {10.3390/nano12244490}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {12}, unique-id = {33366417}, abstract = {Solar radiation is a cheap and abundant energy for water remediation, hydrogen generation by water splitting, and CO2 reduction. Supported photocatalysts have to be tuned to the pollutants to be eliminated. Spectral engineering may be a handy tool to increase the efficiency or the selectivity of these. Photonic nanoarchitectures of biological origin with hierarchical organization from nanometers to centimeters are candidates for such applications. We used the blue wing surface of laboratory-reared male Polyommatus icarus butterflies in combination with atomic layer deposition (ALD) of conformal ZnO coating and octahedral Cu2O nanoparticles (NP) to explore the possibilities of engineering the optical and catalytic properties of hybrid photonic nanoarchitectures. The samples were characterized by UV-Vis spectroscopy and optical and scanning electron microscopy. Their photocatalytic performance was benchmarked by comparing the initial decomposition rates of rhodamine B. Cu2O NPs alone or on the butterfly wings, covered by a 5 nm thick layer of ZnO, showed poor performance. Butterfly wings, or ZnO coated butterfly wings with 15 nm ALD layer showed a 3 to 3.5 times enhancement as compared to bare glass. The best performance of almost 4.3 times increase was obtained for the wings conformally coated with 15 nm ZnO, deposited with Cu2O NPs, followed by conformal coating with an additional 5 nm of ZnO by ALD. This enhanced efficiency is associated with slow light effects on the red edge of the reflectance maximum of the photonic nanoarchitectures and with enhanced carrier separation through the n-type ZnO and the p-type Cu2O heterojunction. Properly chosen biologic photonic nanoarchitectures in combination with carefully selected photocatalyst(s) can significantly increase the photodegradation of pollutants in water under visible light illumination.}, keywords = {ZnO; Photocatalysis; ALD; UV-Visible spectroscopy; biotemplating; p-n heterojunction; Cu2O nanoparticles; Butterfly wing; spectral engineering; hybrid photonic nanoarchitecture}, year = {2022}, eissn = {2079-4991}, orcid-numbers = {Piszter, Gábor/0000-0001-7155-4025; Kertész, Krisztián Imre/0000-0001-8004-9135; Baji, Zsófia/0000-0001-5051-3128; Biró, László Péter/0000-0001-7261-0420} } @CONFERENCE{MTMT:33296726, title = {Archaeometric investigations on Lengyel culture (Late Neolithic-Early Copper Age) polished stone tools from the iconic Lengyel site (SW Hungary) (Poster S4-P10.1515)}, url = {https://m2.mtmt.hu/api/publication/33296726}, author = {T. Biró, Katalin and Szakmány, György and Illés, Levente and Kovács, Zoltán and Harsányi, Ildikó and Szilágyi, Veronika}, booktitle = {Book of Abstracts}, unique-id = {33296726}, year = {2022}, pages = {108-108}, orcid-numbers = {T. Biró, Katalin/0009-0006-6919-3404; Szakmány, György/0000-0002-9557-2030} } @article{MTMT:33215064, title = {Supercritical carbon dioxide assisted synthesis of ultra-stable sulfur/carbon composite cathodes for Li– S batteries}, url = {https://m2.mtmt.hu/api/publication/33215064}, author = {SHIVA SHANKAR, LAKSHMI and Zalka, Dóra and Szabó, Tamás and Kózelné Székely, Edit and Kőrösi, Márton and Pászti, Zoltán and Balázsi, Katalin and Illés, Levente and Czigány, Zsolt and Kun, Róbert}, doi = {10.1016/j.mtchem.2022.101240}, journal-iso = {MATER TODAY CHEM}, journal = {MATERIALS TODAY CHEMISTRY}, volume = {26}, unique-id = {33215064}, issn = {2468-5194}, abstract = {To mitigate the shuttle effect and enhance the electrical conductivity in lithium battery cathode, the unique characteristics of supercritical CO2 solvent (SC–CO2) and the distinctive porous and layered microstructure of reduced graphene oxide (rGO) are exploited in the fabrication of a high-performance rGO/sulfur composite cathode. Exploiting SC-CO2 technology can realize highly efficient sulfur transfer and precise microstructure regulation of S/C composite cathodes for Li–S batteries. On exposure, due to the sudden pressure release process, the SC-CO2 expands the interlayers of rGO rendering plenty of storage space for small sulfur allotropes in carbon matrices which increases the active sulfur loading. Being a remarkable hydrophobic solvent, the wetting properties of SC-CO2 are excellent, ensuring sulfur dissolution and penetration deep into the voids and interlayers of rGO. This creates intimate contact of sulfur with rGO interlayers, guaranteeing precise sulfur content, uniform sulfur distribution, and strong interaction between sulfur and carbon leading to enhanced electrical conductivity and sulfur utilization efficiency. Another important feature is that the S/C composites can be prepared at room temperature, unlike other conventional techniques which require a higher temperature. Moreover, the product mixture can be separated simply by de-pressuring SC-CO2. Herein, the rGO/sulfur composite cathode prepared on a lab scale showed an initial discharge capacity of 1024 mAh/g at 0.1C rate with capacity retention of 92.2% and coulombic efficiency of 99% even after 200 charge-discharge cycles. The developed cells showed excellent performance (929 mAh/g at 1 C rate) with an ultralow decay of 0.04% per cycle even after 200 charge-discharge cycles. Through this work, we believe that the synergistic effect of SC-CO2 technology and rGO as sulfur host will open up a promising future for the synthesis of efficient S/C composite cathodes with ultra-high cycling stability.}, keywords = {REDUCED GRAPHENE OXIDE; supercritical fluid; Li-S battery; Sulfur cathode; Carbon–sulfur composite; Polysulfide confinement}, year = {2022}, eissn = {2468-5194}, orcid-numbers = {SHIVA SHANKAR, LAKSHMI/0000-0003-0832-4387; Szabó, Tamás/0000-0001-8182-640X; Kózelné Székely, Edit/0000-0002-6935-0071; Kőrösi, Márton/0000-0002-1224-4788; Balázsi, Katalin/0000-0002-8929-9672; Czigány, Zsolt/0000-0001-6410-8801} } @article{MTMT:33025102, title = {Shock-formed carbon materials with intergrown sp3- and sp2-bonded nanostructured units}, url = {https://m2.mtmt.hu/api/publication/33025102}, author = {Németh, Péter and Lancaster, HJ. and Salzmann, CG. and McColl, K and Fogarassy, Zsolt and Garvie, LAJ. and Illés, Levente and Pécz, Béla and Murri, M and Corà, F and Smith, RL. and Mezouar, M and Howard, CA. and McMillan, PF.}, doi = {10.1073/pnas.2203672119}, journal-iso = {P NATL ACAD SCI USA}, journal = {PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA}, volume = {119}, unique-id = {33025102}, issn = {0027-8424}, abstract = {Diamond is the hardest material found in nature. Its applications range from abrasives and electronics to nanomedicine and laser technology. The common form of diamond is cubic. Yet, dense carbon materials formed by shock compression have been described as hexagonal diamond or lonsdaleite. This study provides a structural understanding of lonsdaleite and demonstrates the existence of bulk materials containing extensive regions of nanostructured diamond and graphene-like intergrowths called diaphites. The structural complexities found in Canyon Diablo iron meteorite diamonds occur in a wide range of carbonaceous materials, and their identification can place constraints on the pressure?temperature conditions experienced during an impact. The predicted advanced properties of such materials highlight their potential use in future engineering applications. Studies of dense carbon materials formed by bolide impacts or produced by laboratory compression provide key information on the high-pressure behavior of carbon and for identifying and designing unique structures for technological applications. However, a major obstacle to studying and designing these materials is an incomplete understanding of their fundamental structures. Here, we report the remarkable structural diversity of cubic/hexagonally (c/h) stacked diamond and their association with diamond-graphite nanocomposites containing sp3-/sp2-bonding patterns, i.e., diaphites, from hard carbon materials formed by shock impact of graphite in the Canyon Diablo iron meteorite. We show evidence for a range of intergrowth types and nanostructures containing unusually short (0.31 nm) graphene spacings and demonstrate that previously neglected or misinterpreted Raman bands can be associated with diaphite structures. Our study provides a structural understanding of the material known as lonsdaleite, previously described as hexagonal diamond, and extends this understanding to other natural and synthetic ultrahard carbon phases. The unique three-dimensional carbon architectures encountered in shock-formed samples can place constraints on the pressure?temperature conditions experienced during an impact and provide exceptional opportunities to engineer the properties of carbon nanocomposite materials and phase assemblages.}, year = {2022}, eissn = {1091-6490}, orcid-numbers = {Németh, Péter/0000-0001-5592-5877; Fogarassy, Zsolt/0000-0003-4981-1237; Pécz, Béla/0000-0002-4651-6972} } @article{MTMT:32836598, title = {A Three-Dimensional Analysis of Magnetic Nanopattern Formation in FeRh Thin Films on MgO Substrates: Implications for Spintronic Devices}, url = {https://m2.mtmt.hu/api/publication/32836598}, author = {Merkel, Dániel and Hegedűs, Gergő and Gracheva, Maria and Deák, András and Illés, Levente and Németh, Attila and Maccari, F. and Radulov, I. and Major, Márton and Chumakov, A.I. and Bessas, D. and Nagy, Dénes Lajos and Zolnai, Zsolt and Graning, S. and Sájerman, K. and Szilágyi, Edit and Lengyel, Attila}, doi = {10.1021/acsanm.2c00511}, journal-iso = {ACS APPL NANO MATER}, journal = {ACS APPLIED NANO MATERIALS}, volume = {5}, unique-id = {32836598}, year = {2022}, eissn = {2574-0970}, pages = {5516-5526}, orcid-numbers = {Gracheva, Maria/0000-0001-5245-8425; Deák, András/0000-0002-2526-1245; Major, Márton/0000-0001-6074-6144; Nagy, Dénes Lajos/0000-0002-6790-9505; Zolnai, Zsolt/0000-0003-3457-7679} } @article{MTMT:32918042, title = {A Cserhát-Cserhátalja-Gödöllői-dombság-Mátraalja vidékéről származó csiszolt kőeszközök előzetes archeometriai vizsgálati eredményei / Preliminary archaeometrical results on some polished stone artefacts from Northern Hungary (Cserhát Mts. and foothill region, Mátra foothill region and Gödöllő hills)}, url = {https://m2.mtmt.hu/api/publication/32918042}, author = {Szilágyi, Veronika and Illés, Levente and T. Biró, Katalin and Péntek, Attila and Harsányi, Ildikó and Sági, Tamás and Kovács, Zoltán and Fehér, Kristóf and Szakmány, György}, doi = {10.55023/issn.1786-271X.2021-018}, journal-iso = {ARCHEOMETRIAI MŰHELY}, journal = {ARCHEOMETRIAI MŰHELY}, volume = {18}, unique-id = {32918042}, issn = {1786-271X}, year = {2021}, pages = {237-260}, orcid-numbers = {T. Biró, Katalin/0009-0006-6919-3404; Sági, Tamás/0000-0003-4664-5472; Szakmány, György/0000-0002-9557-2030} }