TY - JOUR AU - Carrilho, Rui M. B. AU - Calvete, Mário J. F. AU - Mikle, Gábor AU - Kollár, László AU - Pereira, Mariette M. TI - Carbon monoxide as a C1 building block in fine chemical synthesis JF - CHINESE JOURNAL OF CHEMISTRY J2 - CHINESE J CHEM VL - 42 PY - 2024 IS - 2 SP - 199 EP - 221 PG - 23 SN - 1001-604X DO - 10.1002/cjoc.202300384 UR - https://m2.mtmt.hu/api/publication/34225873 ID - 34225873 N1 - Funding Agency and Grant Number: Portuguese Agency for Scientific Research "Fundaco para a Ciencia e a Tecnologia" (FCT) [COMPETE2020-UE, UIDB/00070/ 2020, UIDP/00070/2020, UIDB/00313/2020, UIDP/00313/2020, UIDB/00285/2020]; MTA Distinguished Guest Scientist Fellowship 2023 grant; NKFIH [TKP2021-EGA-17] Funding text: The authors acknowledge Portuguese Agency for Scientific Research "Fundac & atilde;o para a Ciencia e a Tecnologia" (FCT) and COMPETE2020-UE, for funding through projects UIDB/00070/ 2020, UIDP/00070/2020, UIDB/00313/2020, UIDP/00313/2020 and UIDB/00285/2020 to Coimbra Chemistry Centre (CQC). M.M. Pereira thanks MTA Distinguished Guest Scientist Fellowship 2023 grant. L. Kollar thanks to NKFIH for funding through project TKP2021-EGA-17. AB - Carbon monoxide (CO) has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis, especially in the fine chemicals industry, due to the development of efficient and selective catalysts for its activation. In this review, we present a comprehensive critical analysis of the last 10 years literature on the use of CO as a renewable feedstock for fine chemicals production. The review is organized by type of catalytic reaction, namely alkene and alkyne carbonylation, hydroformylation, carbonylation of aryl halides, carbonylative cross‐coupling and C–H carbonylation. Notable examples of the synthesis of relevant building blocks and/or known pharmaceuticals are highlighted. Emphasis is placed on examples of utilizing CO as the C1 building block in one or more catalytic steps. The catalyst used and the reaction conditions are consistently presented throughout all of the examples. LA - English DB - MTMT ER - TY - JOUR AU - Bede, Fanni AU - Mahó, Sándor AU - Sándor, Viktor AU - Mikle, Gábor AU - Kollár, László TI - Carboxamide formation in less favoured positions: Facile synthesis of 7-carboxamidochenodeoxycholanic acid derivatives JF - TETRAHEDRON J2 - TETRAHEDRON VL - 133 PY - 2023 PG - 4 SN - 0040-4020 DO - 10.1016/j.tet.2023.133292 UR - https://m2.mtmt.hu/api/publication/33636217 ID - 33636217 N1 - Funding Agency and Grant Number: NKFIH, Hungary [TKP2021-EGA-17] Funding text: The research was funded by NKFIH, Hungary within the framework of the project TKP2021-EGA-17. LA - English DB - MTMT ER - TY - JOUR AU - Mikle, Gábor AU - Skodáné Földes, Rita AU - Kollár, László TI - Amino- and azidocarbonylation of iodoalkenes JF - TETRAHEDRON J2 - TETRAHEDRON VL - 100 PY - 2021 PG - 6 SN - 0040-4020 DO - 10.1016/j.tet.2021.132495 UR - https://m2.mtmt.hu/api/publication/32477433 ID - 32477433 N1 - Export Date: 18 November 2022 CODEN: TETRA Correspondence Address: Kollár, L.; Department of Inorganic Chemistry, P.O. Box 266, Hungary; email: kollar@gamma.ttk.pte.hu LA - English DB - MTMT ER - TY - JOUR AU - Mikle, Gábor AU - Bede, Fanni AU - Kollár, László TI - Synthesis of N-picolylcarboxamides in aminocarbonylation JF - TETRAHEDRON J2 - TETRAHEDRON VL - 88 PY - 2021 PG - 4 SN - 0040-4020 DO - 10.1016/j.tet.2021.132128 UR - https://m2.mtmt.hu/api/publication/32006368 ID - 32006368 N1 - Funding Agency and Grant Number: Hungarian Scientific Research Fund [OTKA K113177]; National Research, Development and Innovation Fund of Hungary [TKP2020IKA-08, 2020e4.1.1-TKP2020]; [GINOP-2.3.2-15-2016-00049] Funding text: The authors thank the Hungarian Scientific Research Fund (OTKA K113177) for the financial support. This work was supported by the GINOP-2.3.2-15-2016-00049 grant. Project no. TKP2020IKA-08 has been implemented with the support provided from the National Research, Development and Innovation Fund of Hungary, financed under the 2020e4.1.1-TKP2020 funding scheme. LA - English DB - MTMT ER - TY - JOUR AU - Mikle, Gábor AU - Noveczky, P. AU - Mahó, Sándor AU - Kollár, László TI - Palladium-catalysed amino-vs. Alkoxycarbonylation of iodoalkenes using bifunctional N,O-nucleophiles JF - TETRAHEDRON J2 - TETRAHEDRON VL - 85 PY - 2021 PG - 12 SN - 0040-4020 DO - 10.1016/j.tet.2021.132050 UR - https://m2.mtmt.hu/api/publication/31951951 ID - 31951951 N1 - Funding Agency and Grant Number: Hungarian Scientific Research Fund [K113177]; [GINOP-2.3.2-15-2016-00049] Funding text: The authors thank the Hungarian Scientific Research Fund (K113177) for the financial support, as well as Johnson Matthey for the generous gift of Pd(OAc)2. This work was supported by the GINOP-2.3.2-15-2016-00049 grant. LA - English DB - MTMT ER - TY - JOUR AU - Mikle, Gábor AU - Zugó, A. AU - Szatnik, E. AU - Maxim, A. AU - Mahó, Sándor AU - Kollár, László TI - Synthesis of novel pregnane-based 20-carboxamides via palladium-catalysed aminocarbonylation JF - CHEMICAL PAPERS / CHEMICKÉ ZVESTI J2 - CHEM PAP / CHEM ZVESTI VL - 75 PY - 2021 IS - 5 SP - 1861 EP - 1867 PG - 7 SN - 2585-7290 DO - 10.1007/s11696-020-01478-7 UR - https://m2.mtmt.hu/api/publication/31807039 ID - 31807039 N1 - Funding Agency and Grant Number: Hungarian Scientific Research Fund [OTKA K113177]; [GINOP-2.3.2-15-2016-00049] Funding text: This work was supported by the Hungarian Scientific Research Fund (OTKA K113177) and the GINOP-2.3.2-15-2016-00049 Grant. LA - English DB - MTMT ER - TY - JOUR AU - Pálinkás, Noémi AU - Mikle, Gábor AU - Aranyi, Anita AU - Péter, Antal AU - Kollár, László TI - Synthesis of Axially Chiral Carboxamides via Aminocarbonylation of Aryl and Vinyl Iodides with 2,2'-Diamino-1,1'-binaphthalene in the Presence of Palladium Catalysts JF - CHEMISTRYSELECT J2 - CHEMISTRYSELECT VL - 5 PY - 2020 IS - 35 SP - 11048 EP - 11051 PG - 4 SN - 2365-6549 DO - 10.1002/slct.202002093 UR - https://m2.mtmt.hu/api/publication/31625419 ID - 31625419 N1 - Funding Agency and Grant Number: Hungarian Scientific Research Fund [OTKA K113177, GINOP-2.3.2-15-2016-00049] Funding text: The authors thank the Hungarian Scientific Research Fund (OTKA K113177) for the financial support. This work was also supported by the GINOP-2.3.2-15-2016-00049 grant. AB - Palladium-catalysed aminocarbonylation of iodobenzene and 1-iodocyclohexene with both enantiomerically pure and racemic 2,2'-diamino-1,1'-binaphthalene (BINAM) asN-nucleophile was carried out. The mono- and dicarboxamide enantiomers possessing axial chirality were synthesised using (S-ax)-BINAM. In the possession of these reference compounds the partial chiral kinetic resolution of racemic BINAM was carried out using various optically active bidentate ligands such as (2S,4S)-BDPP, (2S,3S)-CHIRAPHOS and (R)-BINAP. It was revealed by chiral HPLC measurements that up to 10 % enantiomeric excess of carboxamides can be achieved in this way. Although with low enantioselection, enantioselectve aminocarbonylation was carried out for the first time. LA - English DB - MTMT ER - TY - JOUR AU - Bartal, Brigitta AU - Mikle, Gábor AU - Kollár, László AU - Pongrácz, Péter TI - Palladium catalyzed carbonylations of alkenyl halides with formic acid to get corresponding α,β-unsaturated carboxylic acids and esters JF - MOLECULAR CATALYSIS J2 - MOL CATAL VL - 467 PY - 2019 SP - 143 EP - 149 PG - 7 SN - 2468-8231 DO - 10.1016/j.mcat.2018.12.026 UR - https://m2.mtmt.hu/api/publication/30476926 ID - 30476926 LA - English DB - MTMT ER - TY - JOUR AU - Szuroczki, Péter AU - Mikle, Gábor AU - Kollár, László TI - Palladium-catalysed aminocarbonylation/cyclization of iodoalkenes toward N-propargylcarboxamides and oxazoles JF - MOLECULAR CATALYSIS J2 - MOL CATAL VL - 452 PY - 2018 SP - 68 EP - 74 PG - 7 SN - 2468-8231 DO - 10.1016/j.mcat.2018.03.015 UR - https://m2.mtmt.hu/api/publication/3400417 ID - 3400417 N1 - Funding Agency and Grant Number: Hungarian Research FundOrszagos Tudomanyos Kutatasi Alapprogramok (OTKA) [K113177]; Talentum Fund of the Gedeon Richter Chemical Works Ltd.; [GINOP-2.3.2-15-2016-00049] Funding text: The authors thank one of the reviewers for drawing the attention to the importance of the gem-dimethyl effect. The authors thank the Hungarian Research Fund (K113177) for the financial support. This work was supported by the GINOP-2.3.2-15-2016-00049 grant. P. Sz. thanks Talentum Fund of the Gedeon Richter Chemical Works Ltd. for the scholarship. The present scientific contribution is dedicated to the 650th anniversary of the foundation of the University of Pecs, Hungary. LA - English DB - MTMT ER - TY - JOUR AU - Mikle, Gábor AU - Boros, Borbála AU - Kollár, László TI - Asymmetric aminocarbonylation of iodoalkenes in the presence of alpha-phenylethylamine as an N-nucleophile JF - TETRAHEDRON-ASYMMETRY J2 - TETRAHEDRON ASYMMETR VL - 28 PY - 2017 IS - 12 SP - 1733 EP - 1738 PG - 6 SN - 0957-4166 DO - 10.1016/j.tetasy.2017.10.012 UR - https://m2.mtmt.hu/api/publication/3320441 ID - 3320441 N1 - Funding Agency and Grant Number: Hungarian Scientific Research FundOrszagos Tudomanyos Kutatasi Alapprogramok (OTKA) [K113177]; [GINOP-2.3.2-15-2016-00049] Funding text: The authors thank the Hungarian Scientific Research Fund (K113177) for the financial support and Johnson Matthey for the generous gift of palladium(II) acetate. This work was supported by the GINOP-2.3.2-15-2016-00049 grant. The present scientific contribution is dedicated to the 650th anniversary of the foundation of the University of Pecs, Hungary. LA - English DB - MTMT ER -