@article{MTMT:34225873, title = {Carbon monoxide as a C1 building block in fine chemical synthesis}, url = {https://m2.mtmt.hu/api/publication/34225873}, author = {Carrilho, Rui M. B. and Calvete, Mário J. F. and Mikle, Gábor and Kollár, László and Pereira, Mariette M.}, doi = {10.1002/cjoc.202300384}, journal-iso = {CHINESE J CHEM}, journal = {CHINESE JOURNAL OF CHEMISTRY}, volume = {42}, unique-id = {34225873}, issn = {1001-604X}, abstract = {Carbon monoxide (CO) has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis, especially in the fine chemicals industry, due to the development of efficient and selective catalysts for its activation. In this review, we present a comprehensive critical analysis of the last 10 years literature on the use of CO as a renewable feedstock for fine chemicals production. The review is organized by type of catalytic reaction, namely alkene and alkyne carbonylation, hydroformylation, carbonylation of aryl halides, carbonylative cross‐coupling and C–H carbonylation. Notable examples of the synthesis of relevant building blocks and/or known pharmaceuticals are highlighted. Emphasis is placed on examples of utilizing CO as the C1 building block in one or more catalytic steps. The catalyst used and the reaction conditions are consistently presented throughout all of the examples.}, year = {2024}, eissn = {1614-7065}, pages = {199-221}, orcid-numbers = {Carrilho, Rui M. B./0000-0001-9923-359X; Pereira, Mariette M./0000-0003-4958-7677} } @article{MTMT:33636217, title = {Carboxamide formation in less favoured positions: Facile synthesis of 7-carboxamidochenodeoxycholanic acid derivatives}, url = {https://m2.mtmt.hu/api/publication/33636217}, author = {Bede, Fanni and Mahó, Sándor and Sándor, Viktor and Mikle, Gábor and Kollár, László}, doi = {10.1016/j.tet.2023.133292}, journal-iso = {TETRAHEDRON}, journal = {TETRAHEDRON}, volume = {133}, unique-id = {33636217}, issn = {0040-4020}, year = {2023}, eissn = {1464-5416} } @article{MTMT:32477433, title = {Amino- and azidocarbonylation of iodoalkenes}, url = {https://m2.mtmt.hu/api/publication/32477433}, author = {Mikle, Gábor and Skodáné Földes, Rita and Kollár, László}, doi = {10.1016/j.tet.2021.132495}, journal-iso = {TETRAHEDRON}, journal = {TETRAHEDRON}, volume = {100}, unique-id = {32477433}, issn = {0040-4020}, year = {2021}, eissn = {1464-5416}, orcid-numbers = {Skodáné Földes, Rita/0000-0002-9810-1509} } @article{MTMT:32006368, title = {Synthesis of N-picolylcarboxamides in aminocarbonylation}, url = {https://m2.mtmt.hu/api/publication/32006368}, author = {Mikle, Gábor and Bede, Fanni and Kollár, László}, doi = {10.1016/j.tet.2021.132128}, journal-iso = {TETRAHEDRON}, journal = {TETRAHEDRON}, volume = {88}, unique-id = {32006368}, issn = {0040-4020}, year = {2021}, eissn = {1464-5416} } @article{MTMT:31951951, title = {Palladium-catalysed amino-vs. Alkoxycarbonylation of iodoalkenes using bifunctional N,O-nucleophiles}, url = {https://m2.mtmt.hu/api/publication/31951951}, author = {Mikle, Gábor and Noveczky, P. and Mahó, Sándor and Kollár, László}, doi = {10.1016/j.tet.2021.132050}, journal-iso = {TETRAHEDRON}, journal = {TETRAHEDRON}, volume = {85}, unique-id = {31951951}, issn = {0040-4020}, year = {2021}, eissn = {1464-5416} } @article{MTMT:31807039, title = {Synthesis of novel pregnane-based 20-carboxamides via palladium-catalysed aminocarbonylation}, url = {https://m2.mtmt.hu/api/publication/31807039}, author = {Mikle, Gábor and Zugó, A. and Szatnik, E. and Maxim, A. and Mahó, Sándor and Kollár, László}, doi = {10.1007/s11696-020-01478-7}, journal-iso = {CHEM PAP / CHEM ZVESTI}, journal = {CHEMICAL PAPERS / CHEMICKÉ ZVESTI}, volume = {75}, unique-id = {31807039}, issn = {2585-7290}, year = {2021}, eissn = {1336-9075}, pages = {1861-1867} } @article{MTMT:31625419, title = {Synthesis of Axially Chiral Carboxamides via Aminocarbonylation of Aryl and Vinyl Iodides with 2,2'-Diamino-1,1'-binaphthalene in the Presence of Palladium Catalysts}, url = {https://m2.mtmt.hu/api/publication/31625419}, author = {Pálinkás, Noémi and Mikle, Gábor and Aranyi, Anita and Péter, Antal and Kollár, László}, doi = {10.1002/slct.202002093}, journal-iso = {CHEMISTRYSELECT}, journal = {CHEMISTRYSELECT}, volume = {5}, unique-id = {31625419}, issn = {2365-6549}, abstract = {Palladium-catalysed aminocarbonylation of iodobenzene and 1-iodocyclohexene with both enantiomerically pure and racemic 2,2'-diamino-1,1'-binaphthalene (BINAM) asN-nucleophile was carried out. The mono- and dicarboxamide enantiomers possessing axial chirality were synthesised using (S-ax)-BINAM. In the possession of these reference compounds the partial chiral kinetic resolution of racemic BINAM was carried out using various optically active bidentate ligands such as (2S,4S)-BDPP, (2S,3S)-CHIRAPHOS and (R)-BINAP. It was revealed by chiral HPLC measurements that up to 10 % enantiomeric excess of carboxamides can be achieved in this way. Although with low enantioselection, enantioselectve aminocarbonylation was carried out for the first time.}, keywords = {COMPLEXES; carbon monoxide; FACILE SYNTHESIS; Carbonylation; Carbonylation; Carboxamide; Axial chirality}, year = {2020}, eissn = {2365-6549}, pages = {11048-11051} } @article{MTMT:30476926, title = {Palladium catalyzed carbonylations of alkenyl halides with formic acid to get corresponding α,β-unsaturated carboxylic acids and esters}, url = {https://m2.mtmt.hu/api/publication/30476926}, author = {Bartal, Brigitta and Mikle, Gábor and Kollár, László and Pongrácz, Péter}, doi = {10.1016/j.mcat.2018.12.026}, journal-iso = {MOL CATAL}, journal = {MOLECULAR CATALYSIS}, volume = {467}, unique-id = {30476926}, issn = {2468-8231}, year = {2019}, eissn = {2468-8274}, pages = {143-149}, orcid-numbers = {Pongrácz, Péter/0009-0006-5782-2883} } @article{MTMT:3400417, title = {Palladium-catalysed aminocarbonylation/cyclization of iodoalkenes toward N-propargylcarboxamides and oxazoles}, url = {https://m2.mtmt.hu/api/publication/3400417}, author = {Szuroczki, Péter and Mikle, Gábor and Kollár, László}, doi = {10.1016/j.mcat.2018.03.015}, journal-iso = {MOL CATAL}, journal = {MOLECULAR CATALYSIS}, volume = {452}, unique-id = {3400417}, issn = {2468-8231}, year = {2018}, eissn = {2468-8274}, pages = {68-74} } @article{MTMT:3320441, title = {Asymmetric aminocarbonylation of iodoalkenes in the presence of alpha-phenylethylamine as an N-nucleophile}, url = {https://m2.mtmt.hu/api/publication/3320441}, author = {Mikle, Gábor and Boros, Borbála and Kollár, László}, doi = {10.1016/j.tetasy.2017.10.012}, journal-iso = {TETRAHEDRON ASYMMETR}, journal = {TETRAHEDRON-ASYMMETRY}, volume = {28}, unique-id = {3320441}, issn = {0957-4166}, year = {2017}, eissn = {1362-511X}, pages = {1733-1738} }