@article{MTMT:34505067, title = {Wastewater Characterization: Chemical Oxygen Demand or Total Organic Carbon Content Measurement?}, url = {https://m2.mtmt.hu/api/publication/34505067}, author = {Wojnárovits, László and Homlok, Renáta and Kovács, Krisztina and Tegze, Anna and Takács, Erzsébet}, doi = {10.3390/molecules29020405}, journal-iso = {MOLECULES}, journal = {MOLECULES}, volume = {29}, unique-id = {34505067}, issn = {1420-3049}, year = {2024}, eissn = {1420-3049} } @article{MTMT:34046597, title = {Investigating the Effect of Reflectance Tuning on Photocatalytic Dye Degradation with Biotemplated ZnO Photonic Nanoarchitectures Based on Morpho Butterfly Wings}, url = {https://m2.mtmt.hu/api/publication/34046597}, author = {Piszter, Gábor and Nagy, Gergely and Kertész, Krisztián Imre and Baji, Zsófia and Kovács, Krisztina and Bálint, Zsolt and Horváth, Zsolt Endre and Pap, József Sándor and Biró, László Péter}, doi = {10.3390/ma16093584}, journal-iso = {MATERIALS}, journal = {MATERIALS}, volume = {16}, unique-id = {34046597}, year = {2023}, eissn = {1996-1944}, orcid-numbers = {Piszter, Gábor/0000-0001-7155-4025; Kertész, Krisztián Imre/0000-0001-8004-9135; Baji, Zsófia/0000-0001-5051-3128; Horváth, Zsolt Endre/0000-0002-4632-0136; Biró, László Péter/0000-0001-7261-0420} } @article{MTMT:34046593, title = {Hydroxyl radical induced degradation of the ß-blocker Nadolol and comparison with Propranolol}, url = {https://m2.mtmt.hu/api/publication/34046593}, author = {Kovács, Krisztina and Tegze, Anna and Bezsenyi, Anikó and Wojnárovits, László}, doi = {10.1016/j.jece.2023.110330}, journal-iso = {J ENVIRON CHEM ENG}, journal = {JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING}, volume = {11}, unique-id = {34046593}, issn = {2213-3437}, year = {2023}, eissn = {2213-3437} } @article{MTMT:34021793, title = {Ionizing Radiation Induced Removal of Ofloxacin, Abatement of Its Toxicity and Antibacterial Activity in Various Water Matrices}, url = {https://m2.mtmt.hu/api/publication/34021793}, author = {Wojnárovits, László and Homlok, Renáta and Kovács, Krisztina and Bezsenyi, Anikó and Takács, Erzsébet}, doi = {10.3390/app13127211}, journal-iso = {APPL SCI-BASEL}, journal = {APPLIED SCIENCES-BASEL}, volume = {13}, unique-id = {34021793}, year = {2023}, eissn = {2076-3417} } @article{MTMT:32831031, title = {Free radical chemistry of atenolol and propranolol investigated by pulse and gamma radiolysis}, url = {https://m2.mtmt.hu/api/publication/32831031}, author = {Kovács, Krisztina and Simon, Á. and Tóth, Tünde and Wojnárovits, László}, doi = {10.1016/j.radphyschem.2022.110141}, journal-iso = {RADIAT PHYS CHEM}, journal = {RADIATION PHYSICS AND CHEMISTRY: THE JOURNAL FOR RADIATION PHYSICS RADIATION CHEMISTRY AND RADIATION PROCESSING}, volume = {196}, unique-id = {32831031}, issn = {0969-806X}, abstract = {Using pulse- and γ-radiolysis the free radical chemistry of atenolol and propranolol was investigated in aqueous solutions evaluating also the consequences of radical reactions on the elimination of organic content and toxicity. In aerated solutions, the hydroxyl radicals (•OH) induce the degradation; at low dissolved O2 concentration, the hydrated electrons (eaq−) may also contribute to the reactions. Propranolol showed higher reactivity towards both •OH and eaq− than atenolol. About 80–90% of •OH attack occurred on the aromatic rings (benzene or naphthalene), the reactions on the oxypropanolamine side chains had lower rate. The reactions with the aromatic rings gave hydroxycyclohexadienyl radicals, by radical titration experiments α-aminoalkyl and aminium radicals were shown forming by •OH attack on the side chain. Only the end-products of propranolol showed toxicity at low doses which was attributed to the formation of naphthalene derivatives, e.g., substituted naphthols.}, year = {2022}, eissn = {1879-0895} } @article{MTMT:32687160, title = {Evaluation of advanced oxidation processes for ß-blockers degradation: a review}, url = {https://m2.mtmt.hu/api/publication/32687160}, author = {Kovács, Krisztina and Tóth, Tünde and Wojnárovits, László}, doi = {10.2166/wst.2021.631}, journal-iso = {WATER SCI TECHNOL}, journal = {WATER SCIENCE AND TECHNOLOGY}, volume = {85}, unique-id = {32687160}, issn = {0273-1223}, year = {2022}, eissn = {1996-9732}, pages = {685-705} } @article{MTMT:32632511, title = {Matrix effect in the hydroxyl radical induced degradation of ß-lactam and tetracycline type antibiotics}, url = {https://m2.mtmt.hu/api/publication/32632511}, author = {Wojnárovits, László and Wang, JL and Chu, LB and Tóth, Tünde and Kovács, Krisztina and Bezsenyi, Anikó and Szabó, László and Homlok, Renáta and Takács, Erzsébet}, doi = {10.1016/j.radphyschem.2022.109980}, journal-iso = {RADIAT PHYS CHEM}, journal = {RADIATION PHYSICS AND CHEMISTRY: THE JOURNAL FOR RADIATION PHYSICS RADIATION CHEMISTRY AND RADIATION PROCESSING}, volume = {193}, unique-id = {32632511}, issn = {0969-806X}, abstract = {Due to the spread of antibiotic resistant bacteria, elimination of antibiotics from purified wastewater is a highly important task. Purified wastewater contains large variety of organic/inorganic compounds that strongly influence the efficiency of advanced oxidation processes (AOP). In this work, we investigate the radiation-induced degradation of selected antibiotic contaminants (oxacillin and cloxacillin from the beta-lactams; tetracycline and chlortetracycline from the tetracyclines) in four matrices: pure water, tap water, synthetic wastewater and purified wastewater received from a wastewater treatment plant. Changes in technically important parameters, such as COD, TOC, BOD, OUR, acute toxicity and antibacterial activity, were investigated at 0.1 mmol dm(-3) (40-48 mg dm(-3)) antibiotic concentration. None of the four antibiotics were biodegradable in any of the four matrices, however, after irradiation with relatively low doses the obtained products were biodegradable. Oxacillin and cloxacillin were not toxic in Vibrio fischeri test, while tetracycline and chlortetracycline showed toxicity that was strongly reduced by the irradiation treatment. Both COD and TOC decreased after irradiation, their ratio shifted towards TOC indicating an increase in the average oxidation state (AOS). The increase in AOS was lower in purified wastewater matrices: this matrix may contain various small, highly oxidized molecules in high concentration, which degrade very slowly in AOP. The antibacterial activity in most of matrices was greatly reduced or completely disappeared at around 2-4 kGy. However, in purified wastewater matrices some antibiotic activity remained even at 4 kGy. Here the degradation of antibiotic is slow (small delta COD/dose value) because a large fraction of the reactive radicals is scavenged presumably by small, highly oxidized molecules in the solution. Although the water radiolysis product H2O2 affected some of the bioassays, this phenomenon was absent in purified wastewater. The purified wastewater after ionizing radiation treatment can be safely released into the receiving lakes or rivers.}, keywords = {MOLECULES; AQUEOUS-SOLUTIONS; Elimination; TOXICITY; Chemistry, Physical; HYDROGEN-PEROXIDE; WASTE-WATER; Penicillins; radiolysis; ADVANCED OXIDATION PROCESSES; TiO2 photocatalysis; oxygen uptake rate; Nuclear Science & Technology; BOD; Irradiation treatment; Average oxidation state}, year = {2022}, eissn = {1879-0895} } @article{MTMT:32126916, title = {Elimination of oxacillin, its toxicity and antibacterial activity by using ionizing radiation}, url = {https://m2.mtmt.hu/api/publication/32126916}, author = {Takács, Erzsébet and Wang, J. and Chu, L. and Tóth, Tünde and Kovács, Krisztina and Bezsenyi, Anikó and Szabó, László and Homlok, Renáta and Wojnárovits, László}, doi = {10.1016/j.chemosphere.2021.131467}, journal-iso = {CHEMOSPHERE}, journal = {CHEMOSPHERE}, volume = {286}, unique-id = {32126916}, issn = {0045-6535}, year = {2022}, eissn = {1879-1298} } @inproceedings{MTMT:32720609, title = {High energy ionizing radiation induced degradation of ß-blockers in aqueous solutions}, url = {https://m2.mtmt.hu/api/publication/32720609}, author = {Kovács, Krisztina and Simon, A and Tóth, Tünde and Wojnárovits, László}, booktitle = {Proceedings of the 27th International Symposium on Analytical and Environmental Problems}, unique-id = {32720609}, year = {2021}, pages = {188-192} } @{MTMT:32720607, title = {ß-blokkolók bomlási reakciói nagyenergiájú ionizáló sugárzás hatására vizes oldatokban.}, url = {https://m2.mtmt.hu/api/publication/32720607}, author = {Kovács, Krisztina and Simon, A and Tóth, Tünde and Wojnárovits, László}, booktitle = {Őszi Radiokémiai Napok 2021}, unique-id = {32720607}, year = {2021}, pages = {111-112} }