@inproceedings{MTMT:33645223, title = {Novel Copper Complexes with Glyoximes, Amines, Schiff Bases, Semi- and Thiosemicarbazones; Synthesis and Physico-Chemical Analysis}, url = {https://m2.mtmt.hu/api/publication/33645223}, author = {Várhelyi, Csaba, ifj. and Szalay, Roland and Pokol, György and Madarász, János and Szilágyi, Imre Miklós and Huszthy, Péter and Simon-Várhelyi, Melinda and Tötös, Róbert and RALUCA-ANCA, MEREU and ALEXANDRA, AVRAM and Korecz, László and May, Nóra Veronika and Mihály, Judith}, booktitle = {Proceedings of the 28th International Symposium on Analytical and Environmental Problems}, unique-id = {33645223}, year = {2022}, pages = {46-50}, orcid-numbers = {Szalay, Roland/0000-0003-3535-5365; Pokol, György/0000-0003-1597-9808; Huszthy, Péter/0000-0001-7305-3312; May, Nóra Veronika/0000-0003-4770-4681} } @CONFERENCE{MTMT:32761146, title = {Réz-komplexek glioximokkal, Schiff-bázisokkal, szemi- és tioszemi-karbazonokkal, valamint fizikai-kémiai és biológiai vizsgálatuk (Copper Complexes with Glyoximes, Schiff Bases, Semi- and Thiosemicarbazones, and their Physical-Chemical and Biological Study)}, url = {https://m2.mtmt.hu/api/publication/32761146}, author = {Várhelyi, Csaba, ifj. and Korecz, László and Pokol, György and Szalay, Roland and GOGA, FIRUŢA and Simon-Várhelyi, Melinda and Tötös, Róbert and Huszthy, Péter and Madarász, János and PAPP, JUDIT and Mihály, Judith}, booktitle = {EME – A Magyar Tudomány Napja Erdélyben, 20. fórum, ÉRTÉKTEREMTŐ TUDOMÁNY - Természettudományi szakosztály}, unique-id = {32761146}, abstract = {Kutatásunk során a következő típusú réz(II)-komplexeket állítottuk elő glioximokkal, aminokkal, Schiff-bázisokkal, valamint szemi (SC)- és tioszemikarbazonokkal (TSC): [Cu(GlioxH)2(amin)2], [Cu(2-heptanon)2A], [Cu(2-heptanon)2A(amin)2], [Cu(2-heptanon-SC)2], [Cu(2-heptanon-TSC)2], ahol GlioxH2: etil-butil-glioxim, metil-butil-glioxim, fenil-metil-glioxim; amin: dibutil-amin, 6-amino-3-pikolin, 1-amino-pentán, difenil-amin, 3-metil-piperidin, 3-pikolin, 3-aminofenol, diizopropil-amin, 2-pikolin, 3-amino-1,2,4-triazol, imidazol; A: 1,2-diaminoetán, 1,2- és 1,3-diaminopropán, o-fenilén-diamin. A felhasználási lehetőségek bemutatása után tárgyaljuk komplexeink kémiai és biológiai sajátosságait, szerkezetét FTIR, ESR, UV-VIS spektroszkópiai, valamint termoanalitikai (TG, DTA, DTG), tömegspektrometriai és por-röntgen diffrakciós (XRD) módszerek segítségével. A réz-komplexeket széles körben tanulmányozzák potenciális antibakteriális, maláriaellenes és gombaellenes hatásuk szempontjából. Számos képviselőjük az Alzheimer- és Parkinson-kór, valamint cél-specifikus újgenerációs rákellenes és gyulladáscsökkentő gyógyszerek.}, year = {2021}, pages = {28-30}, orcid-numbers = {Pokol, György/0000-0003-1597-9808; Szalay, Roland/0000-0003-3535-5365; Huszthy, Péter/0000-0001-7305-3312} } @article{MTMT:32089016, title = {Solid-Phase “Self-Hydrolysis” of [Zn(NH3)4MoO4@2H2O] Involving Enclathrated Water—An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer}, url = {https://m2.mtmt.hu/api/publication/32089016}, author = {Béres, Kende Attila and Sajó, István and Lendvay, György and Trif, László and Petruševski, VM. and Barta-Holló, B and Korecz, László and Paiva Franguelli, Fernanda and Nagyné László, Krisztina and Szilágyi, Imre Miklós and Kótai, László}, doi = {10.3390/molecules26134022}, journal-iso = {MOLECULES}, journal = {MOLECULES}, volume = {26}, unique-id = {32089016}, issn = {1420-3049}, year = {2021}, eissn = {1420-3049}, orcid-numbers = {Béres, Kende Attila/0000-0003-4257-0581; Sajó, István/0000-0002-1228-1407; Lendvay, György/0000-0002-2150-0376; Trif, László/0000-0002-3960-1829; Nagyné László, Krisztina/0000-0003-4499-3983; Szilágyi, Imre Miklós/0000-0002-5938-8543} } @article{MTMT:32010145, title = {Unexpected radical mechanism in a [4+1] cycloaddition reaction}, url = {https://m2.mtmt.hu/api/publication/32010145}, author = {Bors, István and Purgel, Mihály and Fehér, Péter Pál and Varga, Tamás and Speier, Gábor and Korecz, László and Kaizer, József}, doi = {10.1039/D1NJ00660F}, journal-iso = {NEW J CHEM}, journal = {NEW JOURNAL OF CHEMISTRY}, volume = {45}, unique-id = {32010145}, issn = {1144-0546}, abstract = {9,10-Phenanthrenequinone monoimines (2,7-R-PQI, R = tBu, H, Br, NO2, 1a–d) undergo a [4+1] cycloaddition reaction with triphenylphosphine to give 2,3-dihydro-2,2,2-triphenylphenanthro[9,10-d]-1,3,2λ5-oxazaphospholes (3a–d). During the reaction, highly colored radicals are formed as intermediates, which were characterized by EPR and UV-vis spectroscopy. The formation rate and the rate of decay of these radicals were determined kinetically. These radicals exhibit high persistency and under inert conditions can be handled conveniently. Based on detailed kinetic and spectroscopic studies and DFT calculations, a plausible mechanism has been proposed.}, year = {2021}, eissn = {1369-9261}, pages = {8440-8444}, orcid-numbers = {Purgel, Mihály/0000-0002-9982-8590; Varga, Tamás/0000-0002-4730-3784; Kaizer, József/0000-0002-1427-8105} } @article{MTMT:31920027, title = {Effect of the Microstructure of the Semiconductor Support on the Photocatalytic Performance of the Pt-PtOx/TiO2 Catalyst System}, url = {https://m2.mtmt.hu/api/publication/31920027}, author = {Szijjártóné Majrik, Katalin and Pászti, Zoltán and Korecz, László and Mihály, Judith and May, Zoltán and Németh, Péter and Cannilla, C and Bonura, G and Frusteri, F and Tompos, András and Tálas, Emília}, doi = {10.3390/ma14040943}, journal-iso = {MATERIALS}, journal = {MATERIALS}, volume = {14}, unique-id = {31920027}, year = {2021}, eissn = {1996-1944}, orcid-numbers = {May, Zoltán/0000-0002-6493-5425; Németh, Péter/0000-0001-5592-5877; Bonura, G/0000-0001-5793-8903; Tálas, Emília/0000-0002-9401-2584} } @{MTMT:30806124, title = {THERMAL AND SPECTROSCOPICAL ANALYSIS OF IRON(II) AND COPPER(II) COMPLEXES WITH AZOMETHINES}, url = {https://m2.mtmt.hu/api/publication/30806124}, author = {Várhelyi, Csaba, ifj. and Szilágyi, Imre-Miklós and Goga, Firuţa and Pokol, György and Kuzmann, Ernő and Szalay, Roland and Korecz, László and Papp, Judit and Várhelyi, Melinda and Mihály, Judith}, booktitle = {2nd Journal of Thermal Analysis and Calorimetry Conference}, unique-id = {30806124}, abstract = {The roles of biologically active transition metal (such as Fe, Cu) complexes with antibacterial, antifungal, and anticancer property have attracted much interest during last decades. Numerous chelates containing Cu2+ have been shown to possess anti-inflammatory activity [1]. Efforts are now focused to develop novel antitumor drugs which can improve clinical effectiveness, in order to reduce general toxicity and to broaden the spectrum of activity. Due to its interaction with many biomolecules and synthetic substances including organometallic compounds and metal complexes, DNA is a main target for the therapeutic treatment of various disorders and diseases [2]. Metal complex based functional metalloenzymes play also an important role as highly active and selective catalysts governing vital functions of living organisms [3]. In our research project new Fe(II) and Cu(II) complexes were synthesized from the reaction between azomethine derivatives (glyoximes, Schiff bases, semi- and thiosemicarbazones) and Fe(II) or Cu(II) salts, respectively, in suitable solvent. After presenting a short historical survey, classification, and possible application fields of these compounds, we report the study of their thermoanalytical behaviour (TG, DTA, DTG), spectroscopic features (such as FTIR, NMR, UV-VIS, Raman, Mössbauer, ESR spectroscopy, mass spectrometry) as well as their powder XRD. The biological activity of complexes, especially their antibacterial activity, will also be discussed.}, year = {2019}, pages = {323-324} } @article{MTMT:30746455, title = {Relationship between solid state structure and solution stability of copper(II)-hydroxypyridinecarboxylate complexes}, url = {https://m2.mtmt.hu/api/publication/30746455}, author = {May, Nóra Veronika and Gál, Gyula Tamás and Szentendrei, Zsolt and Korecz, László and May, Zoltán and Ferlin, Maria Grazia and Dean, Annalisa and Bombicz, Petra and Di Marco, Valerio B.}, doi = {10.1039/c9nj01469a}, journal-iso = {NEW J CHEM}, journal = {NEW JOURNAL OF CHEMISTRY}, volume = {43}, unique-id = {30746455}, issn = {1144-0546}, abstract = {The complementary solid state/solution studies of the systematic series of bioactive ligands 3-hydroxy-1-methyl-4-pyridinecarboxylate (L1), 3-hydroxy-1,2,6-trimethyl-4-pyridinecarboxylate (L2), 4-hydroxy-1-methyl-3-pyridinecarboxylate (L3), 4-hydroxy-1,6-dimethyl-3-pyridinecarboxylate (L4), 4-hydroxy-1-(2-hydroxyethyl)-6-methyl-3-pyridinecarboxylate (L5) and 4-hydroxy-1-(2-carboxyethyl)-6-methyl-3pyridinecarboxylate (L6) with copper(II) have been performed in order to design efficient chelating drugs for the treatment of metal overloading conditions. Single crystals of [Cu(L1)(2)(H2O)]center dot 3H(2)O (1) (monomer) with axial water coordination, [Cu-2(L2)(4)]center dot 6H(2)O (2) and [Cu-2(L3)(4)]center dot 4H(2)O (3) (cyclic dimers), where pyridinolato and carboxylato oxygens, respectively, act as linkers between adjacent copper complexes, [Cu(L4)(2)](n)center dot 3H(2)O (4) (1D polymer) and [Cu-3(L5)(6)]center dot 18H(2)O (5) (trimer), constructed using two square-pyramidal and one elongated octahedral Cu(II) complexes have been determined by SXRD. The bidentate coordination mode of the ligands has been found preferentially with cis arrangements in 1 and 2 and trans arrangements in 3-5. The solution speciation and complex stability of aqueous solutions have been studied by pH-dependent electron paramagnetic resonance spectroscopy resulting in the detection of solely monomeric [CuL](+) and [CuL2] complexes. The stability order obtained for the [CuL](+) complexes could be correlated with the deprotonation constants of their hydroxyl group (log beta(LH)) reflecting that the higher acidity increases the complex stability in the order L2 < L1 approximate to L6 < L4 approximate to L5 < L3. This stability order elucidates the different axial linkers in the cyclic dimers 2 and 3. DFT quantum-chemical calculations support the effect of the electron distribution on the established stability order.}, year = {2019}, eissn = {1369-9261}, pages = {10699-10710}, orcid-numbers = {May, Nóra Veronika/0000-0003-4770-4681; Bombicz, Petra/0000-0002-5509-1515} } @article{MTMT:30326257, title = {Spectroscopic Evidence for the Involvement of a Radical Intermediate in the Friedel-Crafts Benzylation Using Ion-Exchanged K10 Catalysts}, url = {https://m2.mtmt.hu/api/publication/30326257}, author = {Hell, Zoltán and Korecz, László and Békássy, Sándor}, doi = {10.3311/PPch.12842}, journal-iso = {PERIOD POLYTECH CHEM ENG}, journal = {PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING}, volume = {62}, unique-id = {30326257}, issn = {0324-5853}, year = {2018}, eissn = {1587-3765}, pages = {497-502} } @article{MTMT:30309327, title = {Study of PtOx/TiO2 Photocatalysts in the Photocatalytic Reforming of Glycerol: The Role of Co-Catalyst Formation}, url = {https://m2.mtmt.hu/api/publication/30309327}, author = {Szijjártóné Majrik, Katalin and Pászti, Zoltán and Korecz, László and Trif, László and Domján, Attila and Bonura, G and Cannilla, C and Frusteri, F and Tompos, András and Tálas, Emília}, doi = {10.3390/ma11101927}, journal-iso = {MATERIALS}, journal = {MATERIALS}, volume = {11}, unique-id = {30309327}, abstract = {In this study, relationships between preparation conditions, structure, and activity of Pt-containing TiO2 photocatalysts in photoinduced reforming of glycerol for H-2 production were explored. Commercial Aerolyst((R)) TiO2 (P25) and homemade TiO2 prepared by precipitation-aging method were used as semiconductors. Pt co-catalysts were prepared by incipient wetness impregnation from aqueous solution of Pt(NH3)(4)(NO3)(2) and activated by calcination, high temperature hydrogen, or nitrogen treatments. The chemico-physical and structural properties were evaluated by XRD, H-1 MAS NMR, ESR, XPS, TG-MS and TEM. The highest H-2 evolution rate was observed over P25 based samples and the H-2 treatment resulted in more active samples than the other co-catalyst formation methods. In all calcined samples, reduction of Pt occurred during the photocatalytic reaction. Platinum was more easily reducible in all of the P25 supported samples compared to those obtained from the more water-retentive homemade TiO2. This result was related to the negative effect of the adsorbed water content of the homemade TiO2 on Pt reduction and on particle growth during co-catalyst formation.}, year = {2018}, eissn = {1996-1944}, orcid-numbers = {Trif, László/0000-0002-3960-1829} } @article{MTMT:3254597, title = {Sedimentological, taphonomical and palaeoecological aspects of the late early Pleistocene vertebrate fauna from the Somssich Hill 2 site (South Hungary)}, url = {https://m2.mtmt.hu/api/publication/3254597}, author = {Pazonyi, Piroska and Virág, Attila and Gere, Kinga and Botfalvai, Gábor and Sebe, Krisztina and Szentesi, Zoltán and Mészáros, Lukács and Botka, Dániel Bálint and Gasparik, Mihály and Korecz, László}, doi = {10.1016/j.crpv.2017.06.007}, journal-iso = {CR PALEVOL}, journal = {COMPTES RENDUS PALEVOL}, volume = {17}, unique-id = {3254597}, issn = {1631-0683}, keywords = {Europe; Sedimentology; palaeoecology; biochronology; taphonomy; Carnivores; MIDDLE PLIOCENE; ESR dating; Small vertebrates; Epivillafranchian turnover; Late early Pleistocene; BURGOS; ATAPUERCA; GRAN-DOLINA; SORICIDAE REMAINS; SMALL MAMMAL TAPHONOMY; LOCALITY VILLANY HILLS}, year = {2018}, eissn = {1777-571X}, pages = {296-309}, orcid-numbers = {Virág, Attila/0000-0002-5530-0065; Botfalvai, Gábor/0000-0002-5479-9036; Sebe, Krisztina/0000-0002-4647-2199; Szentesi, Zoltán/0000-0002-7019-5478; Botka, Dániel Bálint/0000-0002-6627-4640} }