@article{MTMT:34772009, title = {Thermal diffusity in copper benzene-1,3,5-tricarboxylate–reduced graphite oxide mechanical composites}, url = {https://m2.mtmt.hu/api/publication/34772009}, author = {Gál, Márton and Samaniego Andrade, Samantha Kathiuska and Fehér, Anna Éva and Farkas, Attila and Madarász, János and Horváth, Lili and Gordon, Péter and Kovács, Róbert Sándor and Nagyné László, Krisztina}, doi = {10.1007/s10973-024-13021-x}, journal-iso = {J THERM ANAL CALORIM}, journal = {JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY}, unique-id = {34772009}, issn = {1388-6150}, abstract = {Metal organic frameworks (MOFs) and particularly copper benzene-1,3,5-tricarboxylate (HKUST-1) are excellent materials for gas storage (e.g., CH 4 , N 2 , H 2 adsorption) and gas separation. In this work, reduced graphene oxide (RGO)–HKUST-1 mechanical mixtures were studied in order to reveal the effect of RGO content on the pressure tolerance of the texture and heat conductivity. HKUST-1 was obtained by two different synthesis routes. Air-dried MOF and RGO were thoroughly mixed prior to the compression. Powder XRD and Raman spectroscopy were used to characterize the response of the crystal structure, while low-temperature nitrogen adsorption was used the follow the adsorption properties of the pellets. Finally, the "flash" heat pulse method was used to assess the thermal properties. The gas adsorption isotherms revealed that the adsorption capacity decreases when RGO is added. Based on Raman and XRD results, we found that the synthesis route has an effect on multiple scales. We experimentally confirmed that evaluation of the thermal diffusivity requires a model more complex than the simple Fourier equation, due to the inherent heterogeneous structure of the material. A good approximation of the Fourier coefficient of thermal diffusivity was obtained using the parameters of the Guyer–Krumhansl equation. The heat pulse experiments also revealed possible size-dependent behavior.}, year = {2024}, eissn = {1572-8943}, orcid-numbers = {Fehér, Anna Éva/0000-0002-2366-6388; Farkas, Attila/0000-0002-8877-2587; Kovács, Róbert Sándor/0000-0001-5822-6035; Nagyné László, Krisztina/0000-0003-4499-3983} } @article{MTMT:34742503, title = {Electrocatalytic nitrate reduction: The synthesis, recovery and upgradation of ammonia}, url = {https://m2.mtmt.hu/api/publication/34742503}, author = {Chen, Y. and Xu, B. and Nagyné László, Krisztina and Wang, Y.}, doi = {10.1016/j.jece.2024.112348}, journal-iso = {J ENVIRON CHEM ENG}, journal = {JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING}, volume = {12}, unique-id = {34742503}, issn = {2213-3437}, abstract = {The nitrogen cycle has been disrupted by human activities, and a large amount of nitrate pollutants was discharged into the environment. This has resulted in an increase in nitrate levels in groundwater, posing threats to aquatic ecosystems and human health. Electrocatalytic nitrate reduction to ammonia (NRA), as an eco-friendly technology with the potential for pollution removal and resource recycling, has been widely studied. Here, focusing on the pathway of electrocatalytic nitrate reduction to achieve turning waste into valuable resources, we provide an overview of NRA from a broader perspective. The mechanisms of NRA, various electrocatalyst design strategies, and the control of reaction conditions have all been discussed in depth. Special attention is dedicated to summarizing the process of simultaneous ammonia recovery. Meanwhile, we discussed some emerging technologies developed based on NRA, such as C-N coupling and nitrate batteries. Finally, we discussed the challenges of NRA for industrial applications. This review provides a broader and comprehensive perspective on NRA, aiming to offer guidance for the catalyst design and practical application of NRA and promote the development of sustainable chemistry. © 2024 Elsevier Ltd}, keywords = {AMMONIA; recycling; GROUNDWATER; Health risks; Nitrates; ELECTROCATALYSTS; Groundwater pollution; Human Activities; C-N coupling; C-N coupling; Ammonia synthesis; Ammonia synthesis; Aquatic ecosystems; nitrate reduction; electrocatalytic nitrate reduction; electrocatalytic nitrate reduction; resource recycling; Nitrogen cycles; Up gradations; Resources recycling; Design of electrocatalyst; Design of electrocatalysts; Recovery of ammonia; Recovery of ammonia}, year = {2024}, eissn = {2213-3437}, orcid-numbers = {Nagyné László, Krisztina/0000-0003-4499-3983} } @article{MTMT:34448239, title = {Qualitative and quantitative chemometric modelling of nanostructured carbon samples based on infrared spectroscopy}, url = {https://m2.mtmt.hu/api/publication/34448239}, author = {Rácz, Anita and Nagyné László, Krisztina and Klébert, Szilvia}, doi = {10.1016/j.carbon.2023.118743}, journal-iso = {CARBON}, journal = {CARBON}, volume = {218}, unique-id = {34448239}, issn = {0008-6223}, year = {2024}, eissn = {1873-3891}, orcid-numbers = {Nagyné László, Krisztina/0000-0003-4499-3983; Klébert, Szilvia/0000-0002-3107-3371} } @article{MTMT:34452555, title = {Kutatómunka a Fizikai Kémia és Anyagtudományi Tanszéken}, url = {https://m2.mtmt.hu/api/publication/34452555}, author = {Kállay-Menyhárd, Alfréd and Renkeczné Tátraaljai, Dóra and Pukánszky, Béla Jr. and Nagyné László, Krisztina and Bulátkó, Anna and Nagyné Albert, Emőke and Tegze, Borbála Ágnes and Márton, Péter and Hórvölgyi, Zoltán and Gyarmati, Benjámin Sándor and Szilágyi, András Ferenc and Hessz, Dóra and Kubinyi, Miklós and Kállay, Mihály}, journal-iso = {MAGY KEM LAP}, journal = {MAGYAR KÉMIKUSOK LAPJA}, volume = {78}, unique-id = {34452555}, issn = {0025-0163}, year = {2023}, eissn = {1588-1199}, pages = {370-375}, orcid-numbers = {Nagyné László, Krisztina/0000-0003-4499-3983; Szilágyi, András Ferenc/0000-0001-6898-1755; Hessz, Dóra/0000-0003-3033-2762} } @article{MTMT:34394607, title = {Ecotoxicity Assessment of Graphene Oxides Using Test Organisms from Three Hierarchical Trophic Levels to Evaluate Their Potential Environmental Risk}, url = {https://m2.mtmt.hu/api/publication/34394607}, author = {Németh, Imre and Nagyné László, Krisztina and Bulátkó, Anna and Vaszita, Emese Júlia and Molnár, Mónika}, doi = {10.3390/nano13212858}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {13}, unique-id = {34394607}, abstract = {After more than a decade of studying the ecotoxicity of graphene oxide nanomaterials (nGOs), it has been concluded that there is limited information available regarding the environmental risk of graphene-based materials. Since existing ecotoxicological studies of nanomaterials have produced contradictory results, it is recommended that case-by-case studies should be conducted to evaluate their effects. This can be carried out by employing several methods, testing species from different trophic levels, and conducting community studies. Our goal was to evaluate the toxicity effects of two GOs (AF 96/97 and PM 995) derived from different graphite precursors on various test organisms from diverse trophic levels (bacteria, protozoa, a freshwater microbial community, plants, and invertebrate animals) in aquatic environments. We compared the effects of both nGO types and estimated the predicted no-effect environmental concentration (PNEC) values to determine their potential environmental risk. Our findings demonstrated the need for a complex ecotoxicity toolkit since the ecotoxicity results varied based on the test organism, the selected endpoints, and the test method used. Additionally, we found that toxicity effects were dependent on the concentration and characteristics of the specific nGO type used, as well as the exposure time. We estimated the PNEC values for GO AF 96/97 and GO PM 995 in the aquatic compartment to be 8 ng/L and 4 ng/L, respectively. Even after applying the worst-case scenario approach, the tested nGOs pose no environmental risk.}, year = {2023}, eissn = {2079-4991}, orcid-numbers = {Németh, Imre/0000-0003-2412-1184; Nagyné László, Krisztina/0000-0003-4499-3983; Molnár, Mónika/0000-0001-5296-7924} } @article{MTMT:34152622, title = {Towards Understanding the Factors behind the Limited Integration of Multispecies Ecotoxicity Assessment in Environmental Risk Characterisation of Graphene Family Materials - A Bibliometric Review}, url = {https://m2.mtmt.hu/api/publication/34152622}, author = {Fekete-Kertész, Ildikó and Nagyné László, Krisztina and Molnár, Mónika}, doi = {10.3390/c9040090}, journal-iso = {C-J CARBON RES}, journal = {C: JOURNAL OF CARBON RESEARCH}, volume = {9}, unique-id = {34152622}, year = {2023}, eissn = {2311-5629}, orcid-numbers = {Nagyné László, Krisztina/0000-0003-4499-3983; Molnár, Mónika/0000-0001-5296-7924} } @article{MTMT:34106212, title = {The Influence of Reduced Graphene Oxide on the Texture and Chemistry of N,S-Doped Porous Carbon. Implications for Electrocatalytic and Energy Storage Applications}, url = {https://m2.mtmt.hu/api/publication/34106212}, author = {Samaniego Andrade, Samantha Kathiuska and SHIVA SHANKAR, LAKSHMI and Bakos, István and Klébert, Szilvia and Kun, Róbert and Mohai, Miklós and Nagy, Balázs and Nagyné László, Krisztina}, doi = {10.3390/nano13162364}, journal-iso = {NANOMATERIALS-BASEL}, journal = {NANOMATERIALS}, volume = {13}, unique-id = {34106212}, abstract = {In this work, we study the influence of reduced graphene oxide (rGO) on the morphology and chemistry of highly porous N,S-doped carbon cryogels. Simultaneously, we propose an easily upscalable route to prepare such carbons by adding graphene oxide (GO) in as-received suspended form to the aqueous solution of the ι-carrageenan and urea precursors. First, 1.25–5 wt% GO was incorporated into the dual-doped polymer matrix. The CO2, CO, and H2O emitted during the thermal treatments resulted in the multifaceted modification of the textural and chemical properties of the porous carbon. This facilitated the formation of micropores through self-activation and resulted in a substantial increase in the apparent surface area (up to 1780 m2/g) and pore volume (up to 1.72 cm3/g). However, adding 5 wt% GO led to overactivation. The incorporated rGO has an ordering effect on the carbon matrix. The evolving oxidative species influence the surface chemistry in a complex way, but sufficient N and S atoms (ca. 4 and >1 at%, respectively) were preserved in addition to the large number of developing defects. Despite the complexity of the textural and chemical changes, rGO increased the electrical conductivity monotonically. In alkaline oxygen reduction reaction (ORR) tests, the sample with 1.25 wt% GO exhibited a 4e− mechanism and reasonable stability, but a higher rGO content gradually compromised the performance of the electrodes. The sample containing 5 wt% GO was the most sensitive under oxidative conditions, but after stabilization it exhibited the highest gravimetric capacitance. In Li-ion battery tests, the coulombic efficiency of all the samples was consistently above 98%, indicating the high potential of these carbons for efficient Li-ion insertion and reinsertion during the charge–discharge process, thereby providing a promising alternative for graphite-based anodes. The cell from the 1.25 wt% GO sample showed an initial discharge capacity of 313 mAh/g, 95.1% capacity retention, and 99.3% coulombic efficiency after 50 charge–discharge cycles.}, year = {2023}, eissn = {2079-4991}, orcid-numbers = {SHIVA SHANKAR, LAKSHMI/0000-0003-0832-4387; Klébert, Szilvia/0000-0002-3107-3371; Nagyné László, Krisztina/0000-0003-4499-3983} } @article{MTMT:34094261, title = {Heterogenity of graphite oxide particles obtained with wet oxidative exfoliation}, url = {https://m2.mtmt.hu/api/publication/34094261}, author = {Farah, Shereen Farah Ahmed and Gyarmati, Benjámin Sándor and Madarász, János and Villar-Rodil, S. and Tascón, J.M.D. and Nagyné László, Krisztina}, doi = {10.1016/j.molliq.2023.122451}, journal-iso = {J MOL LIQ}, journal = {JOURNAL OF MOLECULAR LIQUIDS}, volume = {386}, unique-id = {34094261}, issn = {0167-7322}, year = {2023}, eissn = {1873-3166}, orcid-numbers = {Farah, Shereen Farah Ahmed/0000-0003-0153-594X; Nagyné László, Krisztina/0000-0003-4499-3983} } @article{MTMT:34065321, title = {Effect of Carbon Nanoparticles on the Porous Texture of ι-Carrageenan-Based N-Doped Nanostructured Porous Carbons and Implications for Gas Phase Applications}, url = {https://m2.mtmt.hu/api/publication/34065321}, author = {Samaniego Andrade, Samantha Kathiuska and Kállay-Menyhárd, Alfréd and Klébert, Szilvia and Mohai, Miklós and Nagy, Balázs and Nagyné László, Krisztina}, doi = {10.3390/c9030068}, journal-iso = {C-J CARBON RES}, journal = {C: JOURNAL OF CARBON RESEARCH}, volume = {9}, unique-id = {34065321}, abstract = {S and N double-doped high surface area biomass-derived carbons were obtained from marine biomass-derived ι-carrageenan. Adding carbon nanoparticles (CNPs), namely graphene oxide (GO) or carbon nanotubes (CNTs), in the early stage of the synthesis leads to a modified porous texture and surface chemistry. The porous textures were characterized by N2 (−196.15 °C) and CO2 (0 °C) isotherms. The best GO- and CNT-added carbons had an apparent surface area of 1780 m2/g and 1170 m2/g, respectively, compared to 1070 m2/g for the CNP-free matrix. Analysis of the Raman spectra revealed that CNT was more efficient in introducing new defects than GO. Based on XPS, the carbon samples contain 2–4.5 at% nitrogen and 1.1 at% sulfur. The Dubinin–Radushkevich (DR) and Henry models were used to assess the strength of the interactions between various gases and the surface. The N2/H2 and CO2/CH4 selectivities were estimated with ideal adsorbed solution theory (IAST). While the CNPs, particularly GO, had a remarkable influence on the porous texture and affected the surface chemistry, their influence on the separation selectivity of these gases was more modest.}, year = {2023}, eissn = {2311-5629}, orcid-numbers = {Klébert, Szilvia/0000-0002-3107-3371; Nagyné László, Krisztina/0000-0003-4499-3983} } @article{MTMT:33734502, title = {In situ gelation of thiolated poly(aspartic acid) derivatives through oxidant-free disulfide formation for ophthalmic drug delivery}, url = {https://m2.mtmt.hu/api/publication/33734502}, author = {Szilágyi, Barnabás Áron and Gyarmati, Benjámin Sándor and L. Kiss, Eszter and Budai-Szűcs, Mária and Misra, Anil and Csányi, Erzsébet and Nagyné László, Krisztina and Szilágyi, András Ferenc}, doi = {10.1016/j.colsurfb.2023.113254}, journal-iso = {COLLOID SURFACE B}, journal = {COLLOIDS AND SURFACES B: BIOINTERFACES}, volume = {225}, unique-id = {33734502}, issn = {0927-7765}, year = {2023}, eissn = {1873-4367}, orcid-numbers = {Budai-Szűcs, Mária/0000-0001-5187-5702; Csányi, Erzsébet/0000-0002-3010-1959; Nagyné László, Krisztina/0000-0003-4499-3983; Szilágyi, András Ferenc/0000-0001-6898-1755} }