@article{MTMT:32830278, title = {(V)UV degradation of the antibiotic tetracycline: kinetics, transformation products and pathway}, url = {https://m2.mtmt.hu/api/publication/32830278}, author = {Krakkó, Dániel and Heieren, Bjørn Tobiassen and Illés, Ádám and Kvamme, Kristin and Dóbé, Sándor and Záray, Gyula}, doi = {10.1016/j.psep.2022.05.027}, journal-iso = {PROCESS SAF ENVIRON}, journal = {PROCESS SAFETY AND ENVIRONMENTAL PROTECTION}, volume = {163}, unique-id = {32830278}, issn = {0957-5820}, year = {2022}, eissn = {1744-3598}, pages = {395-404}, orcid-numbers = {Krakkó, Dániel/0000-0003-1552-7377; Záray, Gyula/0000-0003-2164-1176} } @article{MTMT:32259266, title = {UV and (V)UV irradiation of sitagliptin in ultrapure water and WWTP effluent: Kinetics, transformation products and degradation pathway}, url = {https://m2.mtmt.hu/api/publication/32259266}, author = {Krakkó, Dániel and Illés, Ádám and Domján, Attila and Demeter, Attila and Dóbé, Sándor and Záray, Gyula}, doi = {10.1016/j.chemosphere.2021.132393}, journal-iso = {CHEMOSPHERE}, journal = {CHEMOSPHERE}, volume = {288}, unique-id = {32259266}, issn = {0045-6535}, year = {2022}, eissn = {1879-1298}, orcid-numbers = {Krakkó, Dániel/0000-0003-1552-7377; Záray, Gyula/0000-0003-2164-1176} } @article{MTMT:32008295, title = {An experimental and theoretical kinetic study of the reactions of hydroxyl radicals with tetrahydrofuran and two deuterated tetrahydrofurans}, url = {https://m2.mtmt.hu/api/publication/32008295}, author = {Illés, Ádám and Rózsa, Zsófia Borbála and Thangaraj, Ravikumar and Gombos, Erzsébet and Dóbé, Sándor and Giri, Binod and Szőri, Milán}, doi = {10.1016/j.cplett.2021.138698}, journal-iso = {CHEM PHYS LETT}, journal = {CHEMICAL PHYSICS LETTERS}, volume = {776}, unique-id = {32008295}, issn = {0009-2614}, year = {2021}, eissn = {1873-4448}, orcid-numbers = {Rózsa, Zsófia Borbála/0000-0002-7881-7921; Giri, Binod/0000-0001-9812-4455; Szőri, Milán/0000-0003-4895-0999} } @article{MTMT:31898932, title = {Application of (V)UV/O3 technology for post-treatment of biologically treated wastewater: A pilot-scale study}, url = {https://m2.mtmt.hu/api/publication/31898932}, author = {Krakkó, Dániel and Illés, Ádám and Licul-Kucera, Viktória and Dávid, Bence and Dobosy, Péter and Pogonyi, Andrea and Demeter, Attila and Mihucz, Viktor Gábor and Dóbé, Sándor and Záray, Gyula}, doi = {10.1016/j.chemosphere.2021.130080}, journal-iso = {CHEMOSPHERE}, journal = {CHEMOSPHERE}, volume = {275}, unique-id = {31898932}, issn = {0045-6535}, abstract = {For the first time, high energy VUV photons and generation of O3 by (V)UV lamps were applied together for removal of active pharmaceutical ingredients (APIs) from biologically treated wastewater (BTWW) in pilot-scale. The core of the pilot container unit was a photoreactor assembly consisting of six photoreactors, each containing a low-pressure Hg lamp (UV dose of 1.2 J/cm2 and 6.6 J/cm2 at 185 nm and 254 nm, respectively). BTWW was irradiated (4.75 min residence time) by (V)UV light in presence of in situ photochemically generated O3 from coolant air of the lamps. Experiments were conducted at the site of two wastewater treatment plants. Out of seven target APIs (namely carbamazepine, ciprofloxacin, clarithromycin, diclofenac, metoprolol, sitagliptin, and sulfamethoxazole), 80–100% removal was accomplished for five and 40–80% for two compounds. Two degradation products of carbamazepine were detected. Degradation products of other target compounds were not found. The applied O3 dose was 30–45 μg O3/mg dissolved organic carbon. Inactivation of up to log-4.8, log-4.5 and log-3.8 could be achieved for total coliform, Escherichia coli and Enterococcus faecalis, respectively. SOS Chromotest indicated no genotoxicity nor acute toxicity. Generation of neither NH4+, NO2− nor NO3− was observed during post-treatment. Electric energy per order values were calculated for the first time for (V)UV/O3 treatment in BTWW with a median value of 1.5 kWh/m3. This technology can be proposed for post-treatment of BTWWs of small settlements or livestock farms to degrade micropollutants before water discharge or for production of irrigation water. Further studies are essential in pilot-scale for other applications.}, year = {2021}, eissn = {1879-1298}, orcid-numbers = {Krakkó, Dániel/0000-0003-1552-7377; Pogonyi, Andrea/0000-0003-2612-1401; Mihucz, Viktor Gábor/0000-0002-5320-669X; Záray, Gyula/0000-0003-2164-1176} } @article{MTMT:31387568, title = {Gas-Particle Partitioning of Formaldehyde in Mainstream Cigarette Smoke}, url = {https://m2.mtmt.hu/api/publication/31387568}, author = {Edward, John and Steven, Coburn and Chuan, Liu and John, McAughey and Derek, Mariner and Kevin, G. McAdam and Bakos, István and Dóbé, Sándor}, doi = {10.2478/cttr-2020-0002}, journal-iso = {BEITR TABAKFORSCH INT}, journal = {BEITRAGE ZUR TABAKFORSCHUNG INTERNATIONAL}, volume = {29}, unique-id = {31387568}, issn = {0173-783X}, year = {2020}, eissn = {1612-9237}, pages = {2-20} } @article{MTMT:30847874, title = {Laponite immobilized TiO2 catalysts for photocatalytic degradation of phenols}, url = {https://m2.mtmt.hu/api/publication/30847874}, author = {Gombos, Erzsébet and Krakkó, Dániel and Záray, Gyula and Illés, Ádám and Dóbé, Sándor and Szegedi, Ágnes}, doi = {10.1016/j.jphotochem.2019.112045}, journal-iso = {J PHOTOCH PHOTOBIO A}, journal = {JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY}, volume = {387}, unique-id = {30847874}, issn = {1010-6030}, year = {2020}, eissn = {1873-2666}, orcid-numbers = {Krakkó, Dániel/0000-0003-1552-7377; Záray, Gyula/0000-0003-2164-1176} } @CONFERENCE{MTMT:32599874, title = {Combined VUV Photooxidation and Adsorption onto Granulated Activated Carbon as an Effective Technique for Post-treatment of Biologically Treated Effluent Wastewater}, url = {https://m2.mtmt.hu/api/publication/32599874}, author = {Krakkó, Dániel and Elabadsa, Mohammed and Gombos, Erzsébet and Varga, Margit and Dóbé, Sándor and Záray, Gyula and Mihucz, Viktor Gábor}, booktitle = {11th Eastern European Young Water Professionals Conference}, unique-id = {32599874}, year = {2019}, pages = {207} } @CONFERENCE{MTMT:30812923, title = {Laboratory scale study of photolytic and photooxidative treatment for removal of pharmaceutical residues from water matrices}, url = {https://m2.mtmt.hu/api/publication/30812923}, author = {Záray, Gyula and Dóbé, Sándor and Gombos, Erzsébet and Krakkó, D and Mihucz, Viktor Gábor}, booktitle = {16th International Conference on Environmental Science and Technology}, unique-id = {30812923}, abstract = {Photolytic and photooxidative degradations of diclofenac (DICL), naproxen (NAPR) and carbamazepine (CARB) were studied applying a batch photo-reactor containing low-pressure mercury lamp emitting at 185 and 254 nm. The drugs were added in concentration of 5×10-6 M to ultra-pure water (UPW) and biologically treated wastewater (BTWW). Almost complete photolytic and photooxidative degradations were observed by VUV irradiation for DICL, NAPR and CARB in UPW within 1.0, 1,0 and 1.5 min, respectively. But in the spiked BTWW matrix, the efficient degradation of DICL, NAPR and CARB were achieved within 1, 2 and 10 min, respectively. Several aromatic degradation products of DICL, NAPR and CARB were identified by quadrupole time-of-flight mass spectrometer hyphenated to an ultrahigh performance liquid chromatograph after preconcentration with off-line solid phase extraction upon irradiation of the UPW matrix spiked with the selected drugs at 254 nm. For several degradation products, chemical structures differing from those previously reported have been proposed. Moreover, acridine has not yet been reported as photodegradation product for DICL. Almost complete degradation of DICL, NAPR and CARB as well as their degradation products by VUV+PhO in BTWW took place in 5, 10 and 30 min, respectively applying only one 50 cm long photo-reactor and oxygen stream. The efficiency of this technology can be increased by simultaneous application of more photoreactors in a flowing system.}, year = {2019}, orcid-numbers = {Záray, Gyula/0000-0003-2164-1176; Mihucz, Viktor Gábor/0000-0002-5320-669X} } @article{MTMT:30768813, title = {Enhanced photolytic and photooxidative treatments for removal of selected pharmaceutical ingredients and their degradation products in water matrices}, url = {https://m2.mtmt.hu/api/publication/30768813}, author = {Krakkó, Dániel and Gombos, Erzsébet and Licul-Kucera, Viktória and Dóbé, Sándor and Mihucz, Viktor Gábor and Záray, Gyula}, doi = {10.1016/j.microc.2019.104136}, journal-iso = {MICROCHEM J}, journal = {MICROCHEMICAL JOURNAL}, volume = {150}, unique-id = {30768813}, issn = {0026-265X}, abstract = {Photolytic and photooxidative degradations of diclofenac (DICL), naproxen (NAPR) and carbamazepine (CARB) were compared by a conventional low-pressure mercury-vapor lamp with λmax = 254 nm and a vacuum UV (VUV) one, emitting also at 185 nm (in 11%) in ultra-pure water (UPW) and municipal wastewater (WW) spiked with 5 × 10−6 M for each drug. Almost complete photolytic and photooxidative degradations were observed by VUV irradiation for all three compounds in 2 min. About 75% decrease in the total organic carbon content was determined in UPW irradiated samples spiked at the 2–5 × 10−5 M levels in 15 min. Effective degradations of DICL, NAPR and CARB were achieved in spiked WW by photolysis and photooxidation (PhO) at 185 nm (11%) within 1, 2 and 10 min, respectively. Several aromatic degradation products of DICL, NAPR and CARB were identified by quadrupole time-of-flight mass spectrometer hyphenated to an ultra-high performance liquid chromatograph after preconcentration with off-line solid phase extraction upon irradiation of the UPW matrix spiked with the selected drugs at 254 nm. For several degradation products, chemical structures differing from those previously reported have been proposed. Moreover, acridine has not yet been reported as photodegradation product for DICL. Degradation pathways have been also proposed. Almost complete degradation of DICL, NAPR and CARB as well as their degradation products by VUV + PhO in WW took place in 5, 10 and 30 min, respectively. However, the total organic content decreased by only 25% in the WW sample.}, year = {2019}, eissn = {1095-9149}, orcid-numbers = {Krakkó, Dániel/0000-0003-1552-7377; Mihucz, Viktor Gábor/0000-0002-5320-669X; Záray, Gyula/0000-0003-2164-1176} } @article{MTMT:30365523, title = {Heterogeneous hydroconversion of levulinic acid over silica-supported Ni catalyst}, url = {https://m2.mtmt.hu/api/publication/30365523}, author = {Novodárszki, Gyula and Valyon, József and Illés, Ádám and Dóbé, Sándor and Deka, Dhanapati and Hancsók, Jenő and Rosenbergerné Mihályi, Magdolna}, doi = {10.1007/s11144-018-1507-9}, journal-iso = {REACT KINET MECH CATAL}, journal = {REACTION KINETICS MECHANISMS AND CATALYSIS}, volume = {126}, unique-id = {30365523}, issn = {1878-5190}, year = {2019}, eissn = {1878-5204}, pages = {795-810}, orcid-numbers = {Valyon, József/0000-0002-3608-060X; Hancsók, Jenő/0000-0003-1959-7604} }