TY - JOUR AU - Khoshroo, Ghazaleh AU - Efremova, Anastasiia AU - Suliman, Haythem Suliman Basheer AU - Szenti, Imre AU - Shirzadi Ahoudashti, Masoud AU - Szamosvölgyi, Ákos AU - Erdőhelyi, András AU - Sápi, András AU - Kukovecz, Ákos AU - Kónya, Zoltán TI - Design and Optimization of Trimetallic NiCoFe Catalysts for Efficient Dry Reforming of Methane JF - CATALYSTS J2 - CATALYSTS VL - 15 PY - 2025 IS - 8 PG - 16 SN - 2073-4344 DO - 10.3390/catal15080797 UR - https://m2.mtmt.hu/api/publication/36360358 ID - 36360358 AB - Dry reforming of methane is an advantageous technique to produce syngas by using greenhouse gases like CO2 and CH4. This study investigated the stability, catalytic effectiveness, and physicochemical characteristics of mono- and trimetallic catalysts based on Ni and supported on γ-Al2O3. Adding Co and Fe has been found to modify the structure and surface through the characterizations, including XRD, SEM, TEM, BET, H2-TPR, and XPS methods. Compared to the monometallic Ni catalyst, the trimetallic catalysts exhibited improved alloy formation, reduced particle size, increased metal dispersion, and enhanced surface area and pore structures. The 10% Ni, 2.5% Co, and 2.5% Fe-Al2O3 catalyst exhibits higher CH4 conversion, surpassing 75%, and also CO2 conversion around 85% at 700 °C, compared to 15% Ni-Al2O3, which showed CH4 conversion of about 65% and CO2 conversion of 70%. It also showed comparatively good stability in 24 h testing performed at 700 °C. According to the findings of the research on trimetallic catalysts, their capacity to improve dry reforming of methane (DRM) performance may be attributed to increased stability, which is a crucial challenge in the production of sustainable syngas, as well as higher activity and lower deactivation. LA - English DB - MTMT ER - TY - JOUR AU - Khoshroo, Ghazaleh AU - Sápi, András AU - Szenti, Imre AU - Efremova, Anastasiia AU - Bali, Henrik AU - Baán, Kornélia AU - Erdőhelyi, A. AU - Kukovecz, Ákos AU - Kónya, Zoltán TI - Pure Ni-Based and Trimetallic Ni-Co-Fe Catalysts for the Dry Reforming of Methane: Effect of K Promoter and the Calcination Temperature JF - CATALYSIS LETTERS J2 - CATAL LETT VL - 153 PY - 2023 IS - 9 SP - 2755 EP - 2762 PG - 8 SN - 1011-372X DO - 10.1007/s10562-022-04203-z UR - https://m2.mtmt.hu/api/publication/33545469 ID - 33545469 LA - English DB - MTMT ER -