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      <abstractText>Groundwater salinization threatens water security for 30,000 inhabitants of Siwa Oasis, Egypt, who depend on two aquifer systems: The shallow Tertiary Carbonate Aquifer (TCA) and deeper Nubian Sandstone Aquifer (NSSA). This study elucidates salinity sources and quantifies inter-aquifer mixing dynamics using an integrated approach combining self-organizing map (SOM) analysis, NETPATH inverse modeling, multiple isotopic tracers (δ 1 ⁸O, δ 2 H, ⁸⁷Sr/⁸⁶Sr, 13 C, 14 C), and 3D numerical modeling with reverse particle tracking. Analysis of 153 water samples revealed three distinct hydrochemical groups: High salinity TCA waters influenced by evaporation and recharge from salt lakes, intermediate salinity mixing zones, and low-salinity NSSA paleowaters aged 4,300–14,200 years. Salt lake contributions to TCA groundwater salinity range from 0.6–18%, while fault-controlled NSSA discharge contributes 52–90% to TCA recharge. Predictive modeling indicates the non-renewable groundwaters in the NSSA will experience 30–40 m of drawdown by 2100 under current groundwater abstraction rates, exacerbating TCA salinization. These findings provide a framework for sustainable groundwater management in complex arid aquifer systems and highlight the urgent need for protection of fault-controlled recharge zones.</abstractText>
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      <abstractText>Groundwater quality in arid and semi-arid regions is under increasing pressure from both natural and anthropogenic sources. This study presents a comprehensive assessment of groundwater quality in the Gonbad Plain, Iran, to determine its suitability for drinking and to identify the controlling hydrogeochemical processes. A total of 45 groundwater samples were analyzed for their physicochemical parameters, and the data were evaluated using an integrated approach combining hydrochemical facies analysis, geochemical modeling (PHREEQC), multivariate statistical techniques (Principal component analysis (PCA) and hierarchal cluster analysis (HCA)), and human health risk assessment (Heavy metal pollution index (HPI), Hazard quotient (HQ), Hazard index (HI)). The results reveal a hydrochemical evolution from fresh Ca-HCO₃ type water to saline Na-Cl type water, primarily controlled by three key mechanisms: (1) dissolution of evaporite minerals (halite and gypsum), (2) cation exchange, and (3) evaporation. The Gibbs diagrams confirmed that rock-water interaction and evaporation are the dominant processes governing water chemistry. Iron concentrations varied from 0.01 mg/L to 4.12 mg/L, with a mean of 0.46 mg/L and a standard deviation of 0.66 mg/L. The median iron concentration was 0.27 mg/L. Manganese concentrations ranged from 0.015 mg/L to 0.47 mg/L, with a mean of 0.09 mg/L and a standard deviation of 0.07 mg/L. The median manganese concentration was 0.08 mg/L. The HPI indicated a critical water quality crisis, with 77.8% of the samples being unsuitable for drinking (HPI > 100), primarily due to elevated concentrations of manganese. The non-carcinogenic health risk assessment revealed that while the dermal exposure pathway poses no significant risk, oral ingestion of groundwater presents a potential health hazard, particularly for children. The HI exceeded the safe limit of 1.0 in 11.1% of the samples for children, with manganese being the primary contributor to the risk. This is the first study apply integrated framework that combines multivariate statistics, geochemical modeling, and health risk indices to evaluate groundwater vulnerability in Gonbad-e Kavus. The study’s alignment with UN Sustainable Development Goal 6 (Clean Water and Sanitation).</abstractText>
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      <abstractText>Water resources management is a vital need in arid and semi-arid regions such as Sinai Peninsula, Egypt. Accordingly, the sustainability of water resources in this arid environment should be examined in terms of the possibility of groundwater recharge, particularly through runoff water, while identifying the most appropriate potential sites for drilling new water wells to cover current and future needs. The aquifer system of El-Qaa Plain in South Sinai is considered one of the structural basins associated with the tectonic setting of the Gulf of Suez. It is the main source of high-quality water in South Sinai. The present work provided an integration of mathematical flow modeling, hydrochemical composition, environmental isotopic signature, watershed modeling system (WMS), and remote sensing (RS) tools to determine the aquifer sustainability and recharge mechanisms. The obtained results indicated the following: (a) the salinity of the water ranged between 326.4 and 2261 ppm, while the environmental isotope values ranged between −6.28 to −4.48‰ for δ18O and −29.87 to −21.7‰ for δ2H, which reveals the phase of recharge and mixing between ancient water and recent rainwater; (b) sites for three dams in three sub-watersheds were proposed to harvest approximately 790,000 m3/y of runoff water to enhance groundwater recharge of the aquifer system; (c) and five scenarios using MODFLOW indicated that water drawdown is acceptable by adding 10 new production wells (discharge rate increased by 3600 m3/day). Moreover, increasing the recharge rate by 2% from the base case, leads to an increase in the piezometric water level with an average value of 0.13 masl, which reflects the positive effects of the proposed runoff water harvesting facilities. The integration applied in this work represents an integrated management system for water resources (surface and groundwater) which is suitable for application in arid or semi-arid coastal and similar areas.</abstractText>
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