TY  - JOUR
AU  - Vizi-Orosz, A
AU  - Markó, László
TI  - Reduction of Aromatic Nitro-compounds with NaBH4 Catalyzed by Nickel Complexes of o-Aminothiophenol Schiff Base Derivatives
JF  - TRANSITION METAL CHEMISTRY
J2  - TRANSIT METAL CHEM
VL  - 16
PY  - 1991
IS  - 2
SP  - 215
EP  - 217
PG  - 3
SN  - 0340-4285
UR  - https://m2.mtmt.hu/api/publication/1092484
ID  - 1092484
AB  - The nickel complexes of Schiff bases formed from omicron-aminothiophenol and alpha-dicarbonyl compounds, Ni(omicron-SC6H4N = CRCR = NC6H4S-omicron) (R = H, Me, Ph) (1a-c), catalyse the reduction of aromatic nitro compounds by NaBH4. The reduced species [Ni(omicron-SC6H4N = CHCH = NC6H4S-omicron)]- (2) and [Ni(omicron-SC6H4NHCH2CH = NC6H4S-omicron)]- (3) were identified as intermediates in the catalytic cycle.
LA  - English
DB  - MTMT
ER  -