@article{MTMT:1092484, title = {Reduction of Aromatic Nitro-compounds with NaBH4 Catalyzed by Nickel Complexes of o-Aminothiophenol Schiff Base Derivatives}, url = {https://m2.mtmt.hu/api/publication/1092484}, author = {Vizi-Orosz, A and Markó, László}, journal-iso = {TRANSIT METAL CHEM}, journal = {TRANSITION METAL CHEMISTRY}, volume = {16}, unique-id = {1092484}, issn = {0340-4285}, abstract = {The nickel complexes of Schiff bases formed from omicron-aminothiophenol and alpha-dicarbonyl compounds, Ni(omicron-SC6H4N = CRCR = NC6H4S-omicron) (R = H, Me, Ph) (1a-c), catalyse the reduction of aromatic nitro compounds by NaBH4. The reduced species [Ni(omicron-SC6H4N = CHCH = NC6H4S-omicron)]- (2) and [Ni(omicron-SC6H4NHCH2CH = NC6H4S-omicron)]- (3) were identified as intermediates in the catalytic cycle.}, year = {1991}, eissn = {1572-901X}, pages = {215-217} }