Víztudományi és Vízbiztonsági Nemzeti Laboratórium(RRF-2.3.1-21-2022-00008) Támogató:
NKFIH
Szakterületek:
Növénytermesztés és növényvédelem
Monitoring the concentration of heavy metals in urban soils is of a paramount importance
for several reasons. These inorganic pollutants can pose a significant health risk
to living organisms, as they are toxic even at low concentrations and can be present
in the soil for a long period of time. This study assesses the spatial distribution,
concentration levels, and potential anthropogenic and natural sources of eight typical
heavy metals (As, Cd, Co, Cr, Cu, Ni, Pb and Zn) occurring in urban surface soils
across Debrecen, Hungary. A total of 295 topsoil samples were collected; heavy metal
concentrations were determined by energy-dispersive X-ray fluorescence (EDXRF) spectrometry.
The results were interpreted using descriptive statistics, correlation analysis, hierarchical
clustering, factor analysis, ordinary kriging interpolation, and spatial-discriminant
analysis. The dual origin of the metal contaminants was revealed: As, Co, Pb, and
Zn showed strong anthropogenic signatures associated with traffic, urban waste, and
construction materials, whereas Cr and Ni were associated with natural geogenic sources.
Cd reflected both lithogenic and point-source urban pollution. The current evaluation
incorporated Hungarian and Dutch regulatory benchmarks to identify exceedances of
environmental quality thresholds. It was found that only Cd and Cr exceeded the Hungarian
target values, on average. Linear discriminant analysis based on pollution maps highlighted
contamination hotspots around traffic corridors and newly industrialized zones. The
importance of high-resolution soil monitoring in the rapidly urbanizing city is highlighted.
Given its anticipated industrial and transportation developments, accumulations of
heavy metals are probably going to be further exacerbated; therefore, the results
provide a critical baseline for future environmental assessments and long-term monitoring.