Realization of Intermolecular Interactions as a Basis for Controlling Pervaporation Properties of Membranes Made of Aromatic Polyamide-Imides

Kononova, Svetlana V.; Gubanova, Galina N.; Lebedeva, Galina K.; Kruchinina, Elena V.; Vlasova, Elena N.; Popova, Elena N.; Zakharova, Natalya V.; Vylegzhanina, Milana E.; Novozhilova, Elena A.; Danilova, Ksenia V.

Angol nyelvű Szakcikk (Folyóiratcikk) Tudományos
Megjelent: MEMBRANES (BASEL) 2077-0375 15 (1) Paper: 23 2025
  • SJR Scopus - Chemical Engineering (miscellaneous): Q2
Azonosítók
New aromatic co-polyamide-imides (coPAIs) containing both carboxyl and hydroxyl groups in the repeating units were synthesized for the first time. Transport, thermal and morphological properties of dense nonporous membranes from PAIs obtained using the diacid chloride of 2-(4-carboxyphenyl)-1,3-dioxoisoindoline-5-carboxylic acid and diamines 5,5′-methylene-bis (2-aminophenol)) and 3,5-Diaminobenzoic acid, taken in molar ratios of 7:3, 1:1, and 3:7, have been studied. High levels of membrane permeability accompanied by high selectivity for mixtures of liquids with significantly different polarities were determined by realization of intra- and intermolecular interactions in polymer, which was proved by thermal analyses and hydrodynamic characteristics of coPAIs. This effect is discussed in the context of the effectiveness of intermolecular interactions between polymer chains containing carboxyl and hydroxyl functional groups.
Hivatkozás stílusok: IEEEACMAPAChicagoHarvardCSLMásolásNyomtatás
2025-03-14 11:28