Organometallic Ru(II), Rh(III) and Re(I) complexes of sterane-based bidentate ligands:
Synthesis, solution speciation, interaction with biomolecules and anticancer activity
In this study, we present the synthesis, characterization and in vitro cytotoxicity
of six organometallic [Ru(II)(η6-p-cymene)(N,N)Cl]Cl, [Rh(III)(η5-C5Me5)(N,N)Cl]Cl
and [Re(I)(CO)3(N,N)Cl] complexes, in which the (N,N) ligands are sterane-based 2,2’-bipyridine
derivatives (4-Me-bpy-St-OH,...