{ "labelLang" : "hun", "responseDate" : "2024-03-29 01:23", "content" : { "otype" : "JournalArticle", "mtid" : 3354818, "status" : "APPROVED", "published" : true, "comment" : "Research Centre for Natural Sciences, Hungarian Academy of Sciences, Magyar Tudósok krt. 2, Budapest, 1519, Hungary \n Department of Chemistry, Biochemistry and Environmental Protection, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 3, Novi Sad, 21000, Serbia \n János Szentágothai Research Centre, University of Pécs, Ifjúság útja 20, Pecs, 7624, Hungary \n Institute of Chemistry, ELTE Eötvös Lorand University, Pázmány Péter sétány 1/A, Budapest, 1117, Hungary \n Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Műegyetem rakpart 3, Budapest, 1111, Hungary \n Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budafoki út 8, Budapest, 1111, Hungary \n Institute of Mineralogy and Crystallography, Universitat Wien, Althanstraße 14 (UZA 2), Vienna, 1090, Austria \n Faculty of Earth Science and Engineering, The University of Miskolc, Miskolc-Egyetemváros, 3515, Hungary \n Department of Chemistry, Deogiri College, Station Road, Aurangabad, MS 431 005, India \n Cited By :7 \n Export Date: 11 March 2021 \n CODEN: JTACF \n Correspondence Address: Kótai, L.; Research Centre for Natural Sciences, Magyar Tudósok krt. 2, Hungary; email: kotai.laszlo@ttk.mta.hu \n Funding details: Magyar Tudományos Akadémia, MTA, ÚNKP-17-4-IV-BME-188 \n Funding details: Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja, MPNTR, 172014 \n Funding text 1: Acknowledgements J. Magyari thanks for supporting the research by Ministry of Education, Science and Technological Development of the Republic of Serbia (Grant No. 172014). I. M. Szilágyi thanks for a János Bolyai Research Fellowship of the Hungarian Academy of Sciences and an ÚNKP-17-4-IV-BME-188 Grant. An OTKA PD-109129 Grant, a VEKOP-2.3.2.-16-2017-00013 and a K 124212 Grant are acknowledged.\nFunding Agency and Grant Number: Hungarian Academy of SciencesHungarian Academy of Sciences; Ministry of Education, Science and Technological Development of the Republic of Serbia [172014]; [UNKP-17-4-IV-BME-188]; [OTKA PD-109129]; [VEKOP-2.3.2.-16-2017-00013]; [K 124212]\n Funding text: J. Magyari thanks for supporting the research by Ministry of Education, Science and Technological Development of the Republic of Serbia (Grant No. 172014). I. M. Szilagyi thanks for a Janos Bolyai Research Fellowship of the Hungarian Academy of Sciences and an UNKP-17-4-IV-BME-188 Grant. 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The compound is stable in air. Its thermal decomposition proceeds without the expected quasi-intramolecular oxidation of sulfite ion with ferric ions. The disproportionation reaction of the ammonium sulfite, formed from the evolved NH3, SO2 and H2O in the main decomposition stage of 1, results in the formation of ammonium sulfate and ammonium sulfide. The ammonium sulfide is unstable at the decomposition temperature of 1 (150 A degrees C) and transforms into NH3 and H2S which immediately forms elementary sulfur by reaction with SO2. The formation and decomposition of other intermediate compounds like (NH4)(2)SnOx (n = 2, x = 3 and n = 3, x = 6) results in the same decomposition products (S, SO2 and NH3). Two basic iron sulfates, formed in different ratios during synthesizing experiments performed under N-2 or in the presence of air, have been detected as solid intermediates which contain ammonium ions. 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