Kémiai reakciók: mechanizmusok, dinamika, kinetika, katalitikus reakciók
Termodinamika
Distributed combustion, often associated with the low-oxygen condition, offers ultra-low
NOx emission. However, it was recently achieved without combustion air dilution or
internal flue gas recirculation, using a distinct approach called mixture temperature-controlled
combustion. Here, the fuel-air stream is cooled at the inlet to delay ignition and,
hence, foster homogeneous mixture formation. This numerical study aims to understand
its operation better and present a robust framework for distributed combustion modeling
in a parameter range where such operation was not predicted before by any existing
theory. Further, liquid fuel combustion was evaluated, which brings additional complexity.
Four operating conditions were presented at which distributed combustion was observed.
The reacting flow was modeled by flamelet-generated manifold, based on a detailed
n-dodecane mechanism. The Zimont turbulent flame speed model was used with significantly
reduced coefficients to achieve distributed combustion. The droplets of airblast atomization
were tracked in a Lagrangian frame. The numerical results were validated by Schlieren
images and acoustic spectra. It was concluded that the reactant dilution ratio remained
below 0.25 through the combustion chamber, revealing that the homogeneous fuel-air
mixture is the principal reason for excellent flame stability and ultra-low NOx emission
without significant internal recirculation. The potential applications of these results
are boilers, furnaces, and gas turbines.