{ "labelLang" : "hun", "responseDate" : "2024-03-29 14:21", "content" : { "otype" : "JournalArticle", "mtid" : 31740295, "status" : "VALIDATED", "published" : true, "unhandledTickets" : 0, "deleted" : false, "lastRefresh" : "2021-05-13T18:34:11.243+0000", "lastModified" : "2020-12-10T01:14:36.467+0000", "created" : "2020-12-10T01:14:34.560+0000", "creator" : { "otype" : "Admin", "mtid" : 565, "link" : "/api/admin/565", "label" : "WoS import (admin)", "familyName" : "WoS", "givenName" : "import", "published" : true, "snippet" : true }, "validated" : "2020-12-10T01:14:35.333+0000", "validator" : { "otype" : "Admin", "mtid" : 565, "link" : "/api/admin/565", "label" : "WoS import (admin)", "familyName" : "WoS", "givenName" : "import", "published" : true, "snippet" : true }, "core" : false, "citation" : true, "publicationPending" : true, "type" : { "otype" : "PublicationType", "mtid" : 24, "link" : "/api/publicationtype/24", "label" : "Folyóiratcikk", "code" : 24, "otypeName" : "JournalArticle", "listPosition" : 1, "published" : true, "oldId" : 24, "snippet" : true }, "subType" : { "otype" : "SubType", "mtid" : 10000059, "link" : "/api/subtype/10000059", "label" : "Szakcikk (Folyóiratcikk)", "name" : "Szakcikk", "nameEng" : "Article", "docType" : { "otype" : "PublicationType", "mtid" : 24, "link" : "/api/publicationtype/24", "label" : "Folyóiratcikk", "code" : 24, "otypeName" : "JournalArticle", "listPosition" : 1, "published" : true, "oldId" : 24, "snippet" : true }, "listPosition" : 101, "published" : true, "oldId" : 10000059, "snippet" : true }, "category" : { "otype" : "Category", "mtid" : 1, "link" : "/api/category/1", "label" : "Tudományos", "published" : true, "oldId" : 1, "snippet" : true }, "languages" : [ { "otype" : "Language", "mtid" : 10002, "link" : "/api/language/10002", "label" : "Angol", "name" : "Angol", "nameEng" : "English", "published" : true, "oldId" : 2, "snippet" : true } ], "firstAuthor" : "McCourt, Ruairi O.", "authorships" : [ { "otype" : "PersonAuthorship", "mtid" : 94538933, "link" : "/api/authorship/94538933", "label" : "McCourt, Ruairi O.", "listPosition" : 1, "share" : 0.0, "first" : true, "last" : false, "corresponding" : false, "familyName" : "McCourt", "givenName" : "Ruairi O.", "authorTyped" : true, "editorTyped" : false, "otherTyped" : false, "type" : { "otype" : "AuthorshipType", "mtid" : 1, "link" : "/api/authorshiptype/1", "label" : "Szerző", "code" : 0, "published" : true, "oldId" : 0, "snippet" : true }, "published" : false, "snippet" : true }, { "otype" : "PersonAuthorship", "mtid" : 94538934, "link" : "/api/authorship/94538934", "label" : "Scanlan, Eoin M. ✉", "listPosition" : 2, "share" : 0.0, "first" : false, "last" : true, "corresponding" : true, "familyName" : "Scanlan", "givenName" : "Eoin M.", "authorTyped" : true, "editorTyped" : false, "otherTyped" : false, "type" : { "otype" : "AuthorshipType", "mtid" : 1, "link" : "/api/authorshiptype/1", "label" : "Szerző", "code" : 0, "published" : true, "oldId" : 0, "snippet" : true }, "published" : false, "snippet" : true } ], "title" : "Atmospheric Oxygen Mediated Radical Hydrothiolation of Alkenes", "identifiers" : [ { "otype" : "PublicationIdentifier", "mtid" : 18111904, "link" : "/api/publicationidentifier/18111904", "label" : "DOI: 10.1002/chem.202002542", "source" : { "otype" : "PlainSource", "mtid" : 6, "link" : "/api/publicationsource/6", "label" : "DOI", "type" : { "otype" : "PublicationSourceType", "mtid" : 10001, "link" : "/api/publicationsourcetype/10001", "label" : "DOI", "mayHaveOa" : true, "published" : true, "snippet" : true }, "name" : "DOI", "nameEng" : "DOI", "linkPattern" : "https://doi.org/@@@", "publiclyVisible" : true, "published" : true, "oldId" : 6, "snippet" : true }, "validState" : "IDENTICAL", "idValue" : "10.1002/chem.202002542", "realUrl" : "https://doi.org/10.1002%2Fchem.202002542", "published" : false, "snippet" : true }, { "otype" : "PublicationIdentifier", "mtid" : 18111903, "link" : "/api/publicationidentifier/18111903", "label" : "WoS: 000582290300001", "source" : { "otype" : "PlainSource", "mtid" : 1, "link" : "/api/publicationsource/1", "label" : "WoS", "type" : { "otype" : "PublicationSourceType", "mtid" : 10003, "link" : "/api/publicationsourcetype/10003", "label" : "Indexelő adatbázis", "mayHaveOa" : false, "published" : true, "snippet" : true }, "name" : "WoS", "nameEng" : "WoS", "linkPattern" : "http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=CustomerName&SrcApp=CustomerName&DestLinkType=FullRecord&KeyUT=@@@&DestApp=WOS", "publiclyVisible" : true, "published" : true, "oldId" : 1, "snippet" : true }, "validState" : "IDENTICAL", "idValue" : "000582290300001", "realUrl" : "http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=CustomerName&SrcApp=CustomerName&DestLinkType=FullRecord&KeyUT=000582290300001&DestApp=WOS", "published" : false, "snippet" : true }, { "otype" : "PublicationIdentifier", "mtid" : 18111905, "link" : "/api/publicationidentifier/18111905", "label" : "Scopus: 85093530356", "source" : { "otype" : "PlainSource", "mtid" : 3, "link" : "/api/publicationsource/3", "label" : "Scopus", "type" : { "otype" : "PublicationSourceType", "mtid" : 10003, "link" : "/api/publicationsourcetype/10003", "label" : "Indexelő adatbázis", "mayHaveOa" : false, "published" : true, "snippet" : true }, "name" : "Scopus", "linkPattern" : "http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-@@@", "publiclyVisible" : true, "published" : true, "oldId" : 3, "snippet" : true }, "idValue" : "85093530356", "realUrl" : "http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85093530356", "published" : false, "snippet" : true } ], "journal" : { "otype" : "Journal", "mtid" : 1062264, "link" : "/api/journal/1062264", "label" : "CHEMISTRY-A EUROPEAN JOURNAL 0947-6539 1521-3765", "pIssn" : "0947-6539", "eIssn" : "1521-3765", "reviewType" : "REVIEWED", "noIF" : false, "sciIndexed" : true, "scopusIndexed" : true, "lang" : "FOREIGN", "hungarian" : false, "published" : true, "oldId" : 1062264, "snippet" : true }, "firstPageOrInternalIdForSort" : "", "pageLength" : 8, "publishedYear" : 2020, "abstractText" : "A mild, metal-free, atmospheric oxygen-mediated radical hydrothiolation of alkenes (and alkyne) is reported. A variety of sulfur containing motifs including alkanethiols, thiophenols and thioacids undergo an atmospheric oxygen-mediated radical hydrothiolation reaction with a plethora of alkenes in good yield with excellent functional group compatibility, typically with short reaction times to furnish a range of functionalized products. Biomolecules proved tolerant to the conditions and the procedure is robust and easily executable requiring no specialized equipment. Concise mechanistic studies confirm the process proceeds through radical intermediates in a thiol-ene reaction manifold. The methodology offers an efficient \"green\" approach for thiol-ene mediated \"click\" ligation and a milder alternative to thermally initiated hydrothiolation processes.", "subjects" : [ { "otype" : "Classification", "mtid" : 10293, "link" : "/api/classification/10293", "label" : "Kémiai tudományok", "published" : true, "snippet" : true } ], "keywords" : [ { "otype" : "Keyword", "mtid" : 18993, "link" : "/api/keyword/18993", "label" : "green chemistry", "published" : true, "oldId" : 18993, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1000485, "link" : "/api/keyword/1000485", "label" : "INITIATION", "published" : true, "oldId" : 1000485, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1097232, "link" : "/api/keyword/1097232", "label" : "radical", "published" : true, "oldId" : 1097232, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1392052, "link" : "/api/keyword/1392052", "label" : "THIOL-ENE", "published" : true, "oldId" : 1392052, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1520279, "link" : "/api/keyword/1520279", "label" : "Hydrothiolation", "published" : true, "snippet" : true } ], "digital" : null, "printed" : null, "sourceYear" : 2020, "foreignEdition" : true, "foreignLanguage" : true, "fullPublication" : true, "conferencePublication" : false, "nationalOrigin" : null, "missingAuthor" : false, "oaType" : "NONE", "oaCheckDate" : "2021-05-13", "oaFree" : false, "citationCount" : 0, "citationCountUnpublished" : 0, "citationCountWoOther" : 0, "independentCitCountWoOther" : 0, "doiCitationCount" : 0, "wosCitationCount" : 0, "scopusCitationCount" : 0, "independentCitationCount" : 0, "unhandledCitationCount" : 0, "citingPubCount" : 0, "independentCitingPubCount" : 0, "unhandledCitingPubCount" : 0, "citedPubCount" : 5, "citedCount" : 5, "ratings" : [ { "otype" : "SjrRating", "mtid" : 10762636, "link" : "/api/sjrrating/10762636", "label" : "sjr:D1 (2020) Scopus - Chemistry (miscellaneous) CHEMISTRY-A EUROPEAN JOURNAL 0947-6539 1521-3765", "listPos" : 41, "rankValue" : 0.1, "type" : "journal", "ratingType" : { "otype" : "RatingType", "mtid" : 10002, "link" : "/api/ratingtype/10002", "label" : "sjr", "code" : "sjr", "published" : true, "snippet" : true }, "subject" : { "otype" : "ClassificationExternal", "mtid" : 1601, "link" : "/api/classificationexternal/1601", "label" : "Scopus - Chemistry (miscellaneous)", "published" : true, "oldId" : 1601, "snippet" : true }, "ranking" : "D1", "calculation" : "FROM_LAST_YEAR", "published" : true, "snippet" : true } ], "ratingsForSort" : "D1", "hasCitationDuplums" : false, "directInstitutesForSort" : "", "ownerAuthorCount" : 13, "ownerInstituteCount" : 17, "directInstituteCount" : 0, "authorCount" : 2, "contributorCount" : 0, "hasQualityFactor" : true, "link" : "/api/publication/31740295", "label" : "McCourt Ruairi O. et al. Atmospheric Oxygen Mediated Radical Hydrothiolation of Alkenes. (2020) CHEMISTRY-A EUROPEAN JOURNAL 0947-6539 1521-3765", "template" : "