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The use of easily accessible isocyanides as amidoyl (carbamoyl) synthons in cross-coupling reactions using transition metal and inner transition metoal catalysts is a current trend in this area. Isocyanides, owing to their coordination ability as a ligand and inherent electronic properties for reactions with various partners, have expanded the potential application of these transformations for the preparation of novel synthetic molecules and pharmaceutical candidates. This review gives an overview of the achievements in isocyanide-based transition metal and inner transition metal catalyzed amide formation and discusses highlights of the proposed distinct mechanisms. 1 Introduction2 Synthesis of Arenecarboxamides3 Synthesis of Alkanamides4 Synthesis of Cyclic Amides5 Formation of Alkynamides6 Formation of Acrylamide-like Molecules7 Formation of Ureas and Carbamates8 Conclusion", "subjects" : [ { "otype" : "Classification", "mtid" : 10293, "link" : "/api/classification/10293", "label" : "Kémiai tudományok", "published" : true, "snippet" : true } ], "keywords" : [ { "otype" : "Keyword", "mtid" : 18725, "link" : "/api/keyword/18725", "label" : "ISOCYANIDES", "published" : true, "oldId" : 18725, "snippet" : true }, { "otype" : "Keyword", "mtid" : 18730, "link" : "/api/keyword/18730", "label" : "multicomponent reaction", "published" : true, "oldId" : 18730, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1000692, "link" : "/api/keyword/1000692", "label" : "AMIDE", "published" : true, "oldId" : 1000692, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1084179, "link" : "/api/keyword/1084179", "label" : "INSERTION", "published" : true, "oldId" : 1084179, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1397832, "link" : "/api/keyword/1397832", "label" : "cascade reaction", "published" : true, "oldId" : 1397832, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1413867, "link" : "/api/keyword/1413867", "label" : "Transition metal catalysis", "published" : true, "oldId" : 1413867, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1520318, "link" : "/api/keyword/1520318", "label" : "cross coupling", "published" : true, "snippet" : true } ], "digital" : null, "printed" : null, "sourceYear" : 2020, "foreignEdition" : true, "foreignLanguage" : true, "fullPublication" : true, "conferencePublication" : false, "nationalOrigin" : null, "missingAuthor" : false, "oaType" : "NONE", "oaCheckDate" : "2022-01-28", "oaFree" : false, "citationCount" : 0, "citationCountUnpublished" : 0, "citationCountWoOther" : 0, "independentCitCountWoOther" : 0, "doiCitationCount" : 0, "wosCitationCount" : 0, "scopusCitationCount" : 0, "independentCitationCount" : 0, "unhandledCitationCount" : 0, "citingPubCount" : 0, "independentCitingPubCount" : 0, "unhandledCitingPubCount" : 0, "citedPubCount" : 1, "citedCount" : 1, "ratings" : [ { "otype" : "SjrRating", "mtid" : 10867663, "link" : "/api/sjrrating/10867663", "label" : "sjr:Q1 (2020) Scopus - Organic Chemistry SYNTHESIS-STUTTGART 0039-7881 1437-210X", "listPos" : 41, "rankValue" : 0.24, "type" : "journal", "ratingType" : { "otype" : "RatingType", "mtid" : 10002, "link" : "/api/ratingtype/10002", "label" : "sjr", "code" : "sjr", "published" : true, "snippet" : true }, "subject" : { "otype" : "ClassificationExternal", "mtid" : 1605, "link" : "/api/classificationexternal/1605", "label" : "Scopus - Organic Chemistry", "published" : true, "oldId" : 1605, "snippet" : true }, "ranking" : "Q1", "calculation" : "DIRECT", "published" : true, "snippet" : true } ], "ratingsForSort" : "Q1", "hasCitationDuplums" : false, "directInstitutesForSort" : "", "ownerAuthorCount" : 7, "ownerInstituteCount" : 27, "directInstituteCount" : 0, "authorCount" : 4, "contributorCount" : 0, "hasQualityFactor" : true, "link" : "/api/publication/31692242", "label" : "Shiri Morteza et al. 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