https://m2.mtmt.hu/ eng 2026-05-02 03:52 JournalArticle 31170711 APPROVED true Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetem rkp. 3., Budapest, 1111, Hungary Advanced Membranes and Porous Materials Center, Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955–6900, Saudi Arabia Department of Chemical Engineering and Analytical Science, The University of Manchester, The Mill, Sackville Street, Manchester, M1 3BB, United Kingdom Chemical Crystallography Research Laboratory and Institute of Organic Chemistry, Research Centre for Natural Sciences, Magyar tudósok körútja 2., Budapest, 1519, Hungary Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Szent Gellért tér 4., Budapest, 1111, Hungary Cited By :1 Export Date: 4 February 2021 CODEN: EJOCF Correspondence Address: Bagi, P.; Department of Organic Chemistry and Technology, Műegyetem rkp. 3., Hungary; email: pbagi@mail.bme.hu Funding details: Hawaii Academy of Science, HAS Funding details: OTKA PD 128504 Funding details: King Abdullah University of Science and Technology, KAUST Funding details: National Research, Development and Innovation Office Funding details: Nemzeti Kutatási Fejlesztési és Innovációs Hivatal, NKFIH, OTKA PD 116096 Funding text 1: This work was supported by the National Research, Development and Innovation Office - NKFIH (Grant No. OTKA PD 116096). Tam?s Holczbauer is grateful for the support of the National Research, Development and Innovation Office-NKFIH (Grant No. OTKA PD 128504) and the J?nos Bolyai Research Scholarship of the HAS. Gy?rgy Sz?kely acknowledges the financial support from KAUST. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetem rkp. 3., Budapest, 1111, Hungary Advanced Membranes and Porous Materials Center, Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955–6900, Saudi Arabia Department of Chemical Engineering and Analytical Science, The University of Manchester, The Mill, Sackville Street, Manchester, M1 3BB, United Kingdom Chemical Crystallography Research Laboratory and Institute of Organic Chemistry, Research Centre for Natural Sciences, Magyar tudósok körútja 2., Budapest, 1519, Hungary Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Szent Gellért tér 4., Budapest, 1111, Hungary Cited By :1 Export Date: 30 May 2021 CODEN: EJOCF Correspondence Address: Bagi, P.; Department of Organic Chemistry and Technology, Műegyetem rkp. 3., Hungary; email: pbagi@mail.bme.hu Funding details: Hawaii Academy of Science, HAS Funding details: King Abdullah University of Science and Technology, KAUST Funding details: Nemzeti Kutatási Fejlesztési és Innovációs Hivatal, NKFIH, OTKA PD 116096 Funding details: National Research, Development and Innovation Office, OTKA PD 128504 Funding text 1: This work was supported by the National Research, Development and Innovation Office - NKFIH (Grant No. OTKA PD 116096). Tam?s Holczbauer is grateful for the support of the National Research, Development and Innovation Office-NKFIH (Grant No. OTKA PD 128504) and the J?nos Bolyai Research Scholarship of the HAS. Gy?rgy Sz?kely acknowledges the financial support from KAUST. 0 false 2026-03-11T14:07:31.414+0000 2025-06-19T15:13:40.357+0000 2020-02-11T12:16:10.847+0000 true 10042461 Bagi Péter /api/author/10042461 Author true 10042461 2025-11-10T16:09:19.001+0000 Admin 10067876 /api/admin/10067876 Ladányi Gusztáv true true Admin 10013962 /api/admin/10013962 Vasvari Lilian true 10013962 true 2024-10-17T16:34:06.430+0000 true false true 24 24 /api/publicationtype/24 PublicationType 1 true 24 JournalArticle true 10000059 Article true 24 24 /api/publicationtype/24 PublicationType 1 true 24 JournalArticle /api/subtype/10000059 Szakcikk SubType 101 true 10000059 true 1 /api/category/1 Category true 1 Varga, Bence Scalable Enantiomeric Separation of Dialkyl-arylphosphine oxides based on Host-Guest Complexation with TADDOL-derivatives, and their Recovery true true /api/journal/28331 REVIEWED true false 28331 false 28331 true 1434-193X 1099-0690 Journal FOREIGN 2020 12 1840 1852 1840 13 2020 Several dialkyl‐arylphosphine oxides were prepared, and the enantioseparation of the corresponding racemates was elaborated with host–guest complexation using TADDOL‐derivatives. The crystallization conditions were optimized and two separate crystallization methods, one in organic solvent, and the other in water, were found to yield five examples of phosphine oxides with enantiomeric excess values higher than 94 %. A gram scale resolution was performed, and both enantiomers of the methyl‐phenyl‐propyl‐phosphine oxide were separated with (<jats:italic>R,R</jats:italic>)‐ or (<jats:italic>S,S</jats:italic>)‐spiro‐TADDOL. The intermolecular interactions responsible for the enantiomeric recognition between the chiral host and guest molecules were investigated by single‐crystal X‐ray diffractional structural determinations. The similarities in the structural patterns of a few diastereomeric crystals were checked by powder X‐ray diffraction, as well. Organic solvent nanofiltration (OSN) was used as a scalable technique for the decomposition of the corresponding phosphine oxide–spiro‐TADDOL molecular complexes, and for the recovery of the phosphine oxide enantiomers and resolving agents. true 2020 true true true false true false RESTRICTED 2026-03-11 false 15 0 15 10 3 15 14 14 14 15 15 10 10 10 5 0 15 10 15 10 0 8 8 Folyóiratcikk Journal Article 24 14 Könyvrészlet Chapter in Book 25 1 Könyv Book 23 0 Egyéb konferenciaközlemény Conference paper 31 0 Egyéb konferenciakötet Conference proceedings 32 0 Oltalmi formák Protection forms 26 0 Disszertáció Thesis 28 0 Egyéb Miscellaneous 29 0 Alkotás Achievement 22 0 Kutatási adat Research data 33 0 Folyóiratcikk Journal Article 24 0 0 0 Könyvrészlet Chapter in Book 25 0 0 0 Könyv Book 23 0 0 0 Egyéb konferenciaközlemény Conference paper 31 0 0 0 Egyéb konferenciakötet Conference proceedings 32 0 0 0 Oltalmi formák Protection forms 26 0 0 0 Disszertáció Thesis 28 0 0 0 Egyéb Miscellaneous 29 0 0 0 Alkotás Achievement 22 0 0 0 Kutatási adat Research data 33 0 0 0 2020 0 1 1 1 1 2021 0 2 0 2 0 2022 0 5 3 5 3 2023 0 2 2 2 2 2024 0 2 1 2 1 2025 0 2 2 2 2 2026 0 1 1 1 1 Q1 false 10042461,10018289,10002580,10063224 false false false 2020-05-11T11:18:16.020+0000 Műszercentrum (TTK); Szerves Kémia és Technológia Tanszék (BME / VBK); Szerves Kémiai Intézet (MTA TTK); Szervetlen és Analitikai Kémia Tanszék (BME / VBK) 9 32 4 9 0 true 10013962 10067876 Language 10002 /api/language/10002 Angol English true 2 true PersonAuthorship 90644095 /api/authorship/90644095 1 0.11111111 true false false Author 10063224 /api/author/10063224 Varga Bence true 10063224 true Varga Bence true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644096 /api/authorship/90644096 2 0.111 false false false Author 10053841 /api/author/10053841 Herbay Réka Gizella true 10053841 true Herbay Réka true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644097 /api/authorship/90644097 3 0.11111111 false false false Author 10100956 /api/author/10100956 Székely György true true Székely György true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644098 /api/authorship/90644098 4 0.11111111 false false false Author 10014146 /api/author/10014146 Holczbauer Tamás true 10014146 true Holczbauer Tamás true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644099 /api/authorship/90644099 5 0.111 false false false Author 10002580 /api/author/10002580 Madarász János true 10002580 true Madarász János true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644100 /api/authorship/90644100 6 0.11111111 false false false Author 10018289 /api/author/10018289 Mátravölgyi Béla true 10018289 true Mátravölgyi Béla true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644101 /api/authorship/90644101 7 0.111 false false false Author 10008292 /api/author/10008292 Fogassy Elemér true 10008292 true Fogassy Elemér true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644102 /api/authorship/90644102 8 0.111 false false false Author 1272454 /api/author/1272454 Keglevich György true 1272454 true Keglevich György true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PersonAuthorship 90644103 /api/authorship/90644103 9 0.111 false true true Author 10042461 /api/author/10042461 Bagi Péter true 10042461 true Bagi Peter true false false AuthorshipType 1 /api/authorshiptype/1 0 true 0 true false true PublicationIdentifier 16615133 /api/publicationidentifier/16615133 PlainSource 6 /api/publicationsource/6 PublicationSourceType 10001 /api/publicationsourcetype/10001 true true true DOI DOI https://doi.org/@@@ true true 6 true IDENTICAL 10.1002/ejoc.202000035 https://doi.org/10.1002/ejoc.202000035 false true PublicationIdentifier 17037723 /api/publicationidentifier/17037723 PlainSource 1 /api/publicationsource/1 PublicationSourceType 10003 /api/publicationsourcetype/10003 false true true WoS WoS https://www.webofscience.com/wos/woscc/full-record/@@@ true true 1 true IDENTICAL 000522338200007 https://www.webofscience.com/wos/woscc/full-record/000522338200007 false true PublicationIdentifier 17774088 /api/publicationidentifier/17774088 SwordSource 36 /api/publicationsource/36 PublicationSourceType 10007 /api/publicationsourcetype/10007 true true true REAL REAL http://real.mtak.hu/@@@ true true 36 true RESTRICTED 114937 http://real.mtak.hu/114937 false true PublicationIdentifier 18367250 /api/publicationidentifier/18367250 PlainSource 3 /api/publicationsource/3 PublicationSourceType 10003 /api/publicationsourcetype/10003 false true true Scopus Scopus http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-@@@ true true 3 true IDENTICAL 85081727267 http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85081727267 false true PublicationIdentifier 16615134 /api/publicationidentifier/16615134 PlainSource 40 /api/publicationsource/40 PublicationSourceType 10006 /api/publicationsourcetype/10006 true true true Egyéb URL Other URL @@@ true true 40 true http://doi.wiley.com/10.1002/ejoc.202000035 http://doi.wiley.com/10.1002/ejoc.202000035 false true Classification 10293 /api/classification/10293 true true SjrRating 10876756 /api/sjrrating/10876756 40 0.24 journal RatingType 10002 /api/ratingtype/10002 sjr true true ClassificationExternal 1606 /api/classificationexternal/1606 true 1606 true Q1 DIRECT true true /api/publication/31170711 <div class="JournalArticle Publication long-list"> <div class="authors"> <img title="Forrásközlemény" style="float: left" src="/frontend/resources/grid/publication-core-icon.png"> <img title="Idézőközlemény" style="float: left" src="/frontend/resources/grid/publication-citation-icon.png"> <div class="autype autype0"> <span class="author-name" mtid="10063224"><a href="/gui2/?type=authors&mode=browse&sel=10063224" target="_blank">Varga Bence (<span class="authorship-author-name">Varga Bence</span> <span class="authorAux-mtmt"> kémiai tudományok</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Organic Chemistry and Technology</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10053841"><a href="/gui2/?type=authors&mode=browse&sel=10053841" target="_blank">Herbay Réka (<span class="authorship-author-name">Herbay Réka Gizella</span> <span class="authorAux-mtmt"> szerves kémia</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Organic Chemistry and Technology</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10100956"><a href="/gui2/?type=authors&mode=browse&sel=10100956" target="_blank">Székely György (<span class="authorship-author-name">Székely György</span> <span class="authorAux-mtmt"> elválasztástechnika, membrán, nanoszűrés, zöld ...</span>) </a> </span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10014146"><a href="/gui2/?type=authors&mode=browse&sel=10014146" target="_blank">Holczbauer Tamás (<span class="authorship-author-name">Holczbauer Tamás</span> <span class="authorAux-mtmt"> kémia, szerkezeti kémia, egykristály röntgendif...</span>) </a> </span> <span class="author-affil"><span title="MTA Research Centre for Natural Sciences">MTA TTK</span>/Institute of Organic Chemistry; <span title="Research Centre for Natural Sciences">RCNS</span>/Instrumentation Center</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10002580"><a href="/gui2/?type=authors&mode=browse&sel=10002580" target="_blank">Madarász János (<span class="authorship-author-name">Madarász János</span> <span class="authorAux-mtmt"> Analitikai kémia</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Inorganic and Analytical Chemistry</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10018289"><a href="/gui2/?type=authors&mode=browse&sel=10018289" target="_blank">Mátravölgyi Béla (<span class="authorship-author-name">Mátravölgyi Béla</span> <span class="authorAux-mtmt"> Szerves kémia</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Organic Chemistry and Technology</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10008292"><a href="/gui2/?type=authors&mode=browse&sel=10008292" target="_blank">Fogassy Elemér (<span class="authorship-author-name">Fogassy Elemér</span> <span class="authorAux-mtmt"> Szerves kémia</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Organic Chemistry and Technology</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="1272454"><a href="/gui2/?type=authors&mode=browse&sel=1272454" target="_blank">Keglevich György (<span class="authorship-author-name">Keglevich György</span> <span class="authorAux-mtmt"> Szerves kémia, foszfororganikus környezetbarát ...</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Organic Chemistry and Technology</span> ;&nbsp;&nbsp;&nbsp; <span class="author-name" mtid="10042461"><a href="/gui2/?type=authors&mode=browse&sel=10042461" target="_blank">Bagi Peter ✉ (<span class="authorship-author-name">Bagi Péter</span> <span class="authorAux-mtmt"> Szerves kémia</span>) </a> </span> <span class="author-affil"><span title="Budapest University of Technology and Economics">BUTE</span>/<span title="Faculty of Chemical Technology and Biotechnology">FCTB</span>/Department of Organic Chemistry and Technology</span> </div> </div> <div class="title"><a href="/gui2/?mode=browse&params=publication;31170711" target="_blank">Scalable Enantiomeric Separation of Dialkyl-arylphosphine oxides based on Host-Guest Complexation with TADDOL-derivatives, and their Recovery</a></div> <div> <span class="journal-title">EUROPEAN JOURNAL OF ORGANIC CHEMISTRY</span> <span class="journal-issn">(<a target="_blank" href="https://portal.issn.org/resource/ISSN/1434-193X">1434-193X</a> <a target="_blank" href="https://portal.issn.org/resource/ISSN/1099-0690">1099-0690</a>)</span>: <span class="journal-volume">2020</span> <span class="journal-issue">12</span> <span class="page"> pp 1840-1852 </span> <span class="year">(2020)</span> </div> <div class="pub-footer"> <span class="language" xmlns="http://www.w3.org/1999/html">Language: English | </span> <span class="identifiers"> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="10.1002/ejoc.202000035" target="_blank" href="https://doi.org/10.1002/ejoc.202000035"> DOI </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="000522338200007" target="_blank" href="https://www.webofscience.com/wos/woscc/full-record/000522338200007"> WoS </a> </span> <span class="id identifier oa_RESTRICTED" title=" Restricted "> <a style="color:black" title="114937" target="_blank" href="http://real.mtak.hu/114937"> REAL </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:blue" title="85081727267" target="_blank" href="http://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85081727267"> Scopus </a> </span> <span class="id identifier oa_none" title="none"> <a style="color:black" title="http://doi.wiley.com/10.1002/ejoc.202000035" target="_blank" href="http://doi.wiley.com/10.1002/ejoc.202000035"> Other URL </a> </span> </span> <OnlyViewableByAuthor><div class="ratings"> <div class="journal-subject">Journal subject: Scopus - Physical and Theoretical Chemistry&nbsp;&nbsp;&nbsp;Rank:&nbsp;Q1</div> <div class="journal-subject">Journal subject: Scopus - Organic Chemistry&nbsp;&nbsp;&nbsp;Rank:&nbsp;Q2</div> </div></OnlyViewableByAuthor> <div class="publication-citation" style="margin-left: 0.5cm;"> <span title="" class="citingPub-count">Citing papers: 15</span> | Independent citation: 10 | Self citation: 5 | Unknown citation: 0 | Number of citations in WoS: 14 | Number of citations in Scopus:&nbsp;14 | WoS/Scopus assigned:&nbsp;15 | Number of citations with DOI:&nbsp;14 </div> <div class="publication-citation"> <a target="_blank" href="/api/publication?cond=citations.related;eq;31170711&sort=publishedYear,desc&sort=title"> Number of cited publications: 8 </a> </div> <div class="mtid"><span class="long-pub-mtid">Publication: 31170711</span> | <span class="status-data status-APPROVED"> Published </span> Core Citing | <span class="type-subtype">Journal Article ( Article ) </span> | <span class="pub-category">Scientific</span> | <span class="publication-sourceOfData">kézi felvitel</span> </div> <div class="lastModified">Last Modified: 2025.06.19. 17:13 Katalin Andódy (BME admin4) </div> <div class="lockedBy">Centrally managed 2024.10.17. 18:34 Gusztáv Ladányi (MTMT API user, admin) Lilian Vasvari (MTMT Központ, admin) </div> <pre class="comment" style="margin-top: 0; margin-bottom: 0;"><u>Comments</u>: Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetem rkp. 3., Budapest, 1111, Hungary Advanced Membranes and Porous Materials Center, Physical Science and Engineering Division (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955–6900, Saudi Arabia Department of Chemi...</pre> </div></div>