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The metallization characteristics, joint microstructure and fracture behavior were investigated. Through pre-metallization, a smooth metallic coating formed on the SiC ceramic surface; the carbide layer adjacent to SiC ceramic had a semi-coherent interface with it. Brazing process showed that in situ synthesized TiC particles with fine-grains were evenly dispersed in the filler matrix due to GNPs acting as nucleation sites, promoting the refinement of microstructure of the joint. Moreover, the effect of GNPs in retarding the diffusion of metal atoms limited the reaction of Ti with Cu and Ni, thereby reducing the negative impact induced by the brittle compounds. 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