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The physical properties of the prepared particles were investigated by TEM, XRD and FT-IR. The titanium tetraisopropoxide (TTIP, 98% Aldrich), teraethylorthosilicate (TEOS, 98% Aldrich) and silver nitrate were used as precursors of titania, silica and silver, respectively. Sodium citrate tribasic dihydrate (C6H 5Na3.H2O, Aldrich) was used as a reduction agent. This paper presents the effect of nanosized TiO2-Ag-SiO 2 sols on the formation of methane hydrate in a semi-batch vessel. The micrographs of TEM showed that the TiO2-Ag-SiO2 particles possessed a spherical morphology with a narrow size distribution. The crystallite size of particles decreased with an increasing the SiO2 content. In addition, the water solution with 1.0 wt% of TiO2-Ag- SiO2 particles acted as promoter for methane hydrate formation.", "keywords" : [ { "otype" : "Keyword", "mtid" : 1062, "link" : "/api/keyword/1062", "label" : "PROMOTER", "published" : true, "oldId" : 1062, "snippet" : true }, { "otype" : "Keyword", "mtid" : 5366, "link" : "/api/keyword/5366", "label" : "transmission electron microscopy", "published" : true, "oldId" : 5366, "snippet" : true }, { "otype" : "Keyword", "mtid" : 10700, "link" : "/api/keyword/10700", "label" : "METHANE", "published" : true, "oldId" : 10700, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1013494, "link" : "/api/keyword/1013494", "label" : "X ray diffraction analysis", "published" : true, "oldId" : 1013494, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1039467, "link" : "/api/keyword/1039467", "label" : "SOL-GEL PROCESS", "published" : true, "oldId" : 1039467, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1039471, "link" : "/api/keyword/1039471", "label" : "Sol-gel method", "published" : true, "oldId" : 1039471, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1483441, "link" : "/api/keyword/1483441", "label" : "titanium dioxide", "published" : true, "oldId" : 1483441, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1734690, "link" : "/api/keyword/1734690", "label" : "Methane hydrate", "published" : true, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1734690, "link" : "/api/keyword/1734690", "label" : "Methane hydrate", "published" : true, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1819022, "link" : "/api/keyword/1819022", "label" : "Sodium citrate tribasic dihydrate", "published" : true, "snippet" : true } ], "digital" : null, "printed" : null, "sourceYear" : 2019, "foreignEdition" : true, "foreignLanguage" : true, "fullPublication" : true, "conferencePublication" : true, "nationalOrigin" : null, "missingAuthor" : false, "oaType" : "NONE", "oaCheckDate" : "2023-02-24", "oaFree" : false, "citationCount" : 0, "citationCountUnpublished" : 0, "citationCountWoOther" : 0, "independentCitCountWoOther" : 0, "doiCitationCount" : 0, "wosCitationCount" : 0, "scopusCitationCount" : 0, "independentCitationCount" : 0, "unhandledCitationCount" : 0, "citingPubCount" : 0, "independentCitingPubCount" : 0, "unhandledCitingPubCount" : 0, "citedPubCount" : 1, "citedCount" : 1, "referenceList" : "Siegel, R.W., (1991) Annu. Rev. Mater. Sci, 21, p. 559 ;\n Lee, M.S., Hong, S.-S., Mohseni, M., (2005) Journal molecular catalysis, 242, p. 135 ;\n Shiba, K., Hinode, H., Wakihara, M., (1998) React. Kinet. Catal. Lett, 64, p. 281 ;\n Ilisz, I., Laszlo, Z., Dombi, A., (1999) Appl. Catal. A, 180, p. 25 ;\n Lee, J.D., Robun, S., Englezos, P., (2005) Energy & Fuels, 19, p. 1008 ;\n Duran, A., Serna, C., Fornes, V., Fernandez-Navarro, J.M., (1986) J. Non-Cryst. Solids, 82, p. 69 ;\n Dutoit, D.C.M., Schmeider, M., Baiker, A., (1995) J. Catal, 153, p. 165 ;\n Cullity, B.D., (1978) Elements of X-Ray Diffraction, , Adison-Wesley, Reading, M", "hasCitationDuplums" : false, "userChangeableUntil" : "2019-11-17T11:24:23.203+0000", "directInstitutesForSort" : "", "ownerAuthorCount" : 3, "ownerInstituteCount" : 16, "directInstituteCount" : 0, "authorCount" : 5, "contributorCount" : 0, "book" : { "otype" : "Book", "mtid" : 30918392, "link" : "/api/publication/30918392", "label" : "Byung Tae Ahn. 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