{ "labelLang" : "hun", "responseDate" : "2024-03-28 17:58", "content" : { "otype" : "JournalArticle", "mtid" : 30524372, "status" : "APPROVED", "published" : true, "unhandledTickets" : 0, "deleted" : false, "lastRefresh" : "2021-08-07T12:09:45.027+0000", "lastModified" : "2021-08-07T12:02:23.726+0000", "created" : "2019-03-04T00:39:55.109+0000", "creator" : { "otype" : "Admin", "mtid" : 565, "link" : "/api/admin/565", "label" : "WoS import (admin)", "familyName" : "WoS", "givenName" : "import", "published" : true, "snippet" : true }, "lastDuplumOK" : "2021-08-07T05:42:00.078+0000", "lastDuplumSearch" : "2021-08-07T05:42:00.078+0000", "validated" : "2019-03-04T00:39:57.553+0000", "validator" : { "otype" : "Admin", "mtid" : 565, "link" : "/api/admin/565", "label" : "WoS import (admin)", "familyName" : "WoS", "givenName" : "import", "published" : true, "snippet" : true }, "core" : false, "citation" : true, "publicationPending" : false, "type" : { "otype" : "PublicationType", "mtid" : 24, "link" : "/api/publicationtype/24", "label" : "Folyóiratcikk", "code" : 24, "otypeName" : "JournalArticle", "listPosition" : 1, "published" : true, "oldId" : 24, "snippet" : true }, "subType" : { "otype" : "SubType", "mtid" : 10000059, "link" : "/api/subtype/10000059", "label" : "Szakcikk (Folyóiratcikk)", "name" : "Szakcikk", "nameEng" : "Article", "docType" : { "otype" : "PublicationType", "mtid" : 24, "link" : "/api/publicationtype/24", "label" : "Folyóiratcikk", "code" : 24, "otypeName" : "JournalArticle", "listPosition" : 1, "published" : true, "oldId" : 24, "snippet" : true }, "listPosition" : 101, "published" : true, "oldId" : 10000059, "snippet" : true }, "category" : { "otype" : "Category", "mtid" : 1, "link" : "/api/category/1", "label" : "Tudományos", "published" : true, "oldId" : 1, "snippet" : true }, "languages" : [ { "otype" : "Language", "mtid" : 10002, "link" : "/api/language/10002", "label" : "Angol", "name" : "Angol", "nameEng" : "English", "published" : true, "oldId" : 2, "snippet" : true } ], "firstAuthor" : "Miranda, Silvia", "authorships" : [ { "otype" : "PersonAuthorship", "mtid" : 85939200, "link" : "/api/authorship/85939200", "label" : "Miranda, Silvia", "listPosition" : 1, "share" : 0.0, "first" : true, "last" : false, "familyName" : "Miranda", "givenName" : "Silvia", "authorTyped" : true, "editorTyped" : false, "otherTyped" : false, "type" : { "otype" : "AuthorshipType", "mtid" : 1, "link" : "/api/authorshiptype/1", "label" : "Szerző", "code" : 0, "published" : true, "oldId" : 0, "snippet" : true }, "published" : false, "snippet" : true }, { "otype" : "PersonAuthorship", "mtid" : 85939201, "link" : "/api/authorship/85939201", "label" : "Gomez, Ana M.", "listPosition" : 2, "share" : 0.0, "first" : false, "last" : false, "familyName" : "Gomez", "givenName" : "Ana M.", "authorTyped" : true, "editorTyped" : false, "otherTyped" : false, "type" : { "otype" : "AuthorshipType", "mtid" : 1, "link" : "/api/authorshiptype/1", "label" : "Szerző", "code" : 0, "published" : true, "oldId" : 0, "snippet" : true }, "published" : false, "snippet" : true }, { "otype" : "PersonAuthorship", "mtid" : 85939202, "link" : "/api/authorship/85939202", "label" : "Cristobal Lopez, J.", "listPosition" : 3, "share" : 0.0, "first" : false, "last" : true, "familyName" : "Cristobal Lopez", "givenName" : "J.", "authorTyped" : true, "editorTyped" : false, "otherTyped" : false, "type" : { "otype" : "AuthorshipType", "mtid" : 1, "link" : "/api/authorshiptype/1", "label" : "Szerző", "code" : 0, "published" : true, "oldId" : 0, "snippet" : true }, "published" : false, "snippet" : true } ], "title" : "Diversity-Oriented Synthetic Endeavors of Newly Designed Ferrier and Ferrier-Nicholas Systems Derived from 1-C-Alkynyl-2-deoxy-2-C-Methylene Pyranosides", "identifiers" : [ { "otype" : "PublicationIdentifier", "mtid" : 15361785, "link" : "/api/publicationidentifier/15361785", "label" : "DOI: 10.1002/ejoc.201801004", "source" : { "otype" : "PlainSource", "mtid" : 6, "link" : "/api/publicationsource/6", "label" : "DOI", "type" : { "otype" : "PublicationSourceType", "mtid" : 10001, "link" : "/api/publicationsourcetype/10001", "label" : "DOI", "mayHaveOa" : true, "published" : true, "snippet" : true }, "name" : "DOI", "nameEng" : "DOI", "linkPattern" : "https://doi.org/@@@", "publiclyVisible" : true, "published" : true, "oldId" : 6, "snippet" : true }, "idValue" : "10.1002/ejoc.201801004", "realUrl" : "https://doi.org/10.1002%2Fejoc.201801004", "published" : false, "snippet" : true }, { "otype" : "PublicationIdentifier", "mtid" : 15361784, "link" : "/api/publicationidentifier/15361784", "label" : "WoS: 000448075100002", "source" : { "otype" : "PlainSource", "mtid" : 1, "link" : "/api/publicationsource/1", "label" : "WoS", "type" : { "otype" : "PublicationSourceType", "mtid" : 10003, "link" : "/api/publicationsourcetype/10003", "label" : "Indexelő adatbázis", "mayHaveOa" : false, "published" : true, "snippet" : true }, "name" : "WoS", "nameEng" : "WoS", "linkPattern" : "http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=CustomerName&SrcApp=CustomerName&DestLinkType=FullRecord&KeyUT=@@@&DestApp=WOS", "publiclyVisible" : true, "published" : true, "oldId" : 1, "snippet" : true }, "idValue" : "000448075100002", "realUrl" : "http://gateway.isiknowledge.com/gateway/Gateway.cgi?&GWVersion=2&SrcAuth=CustomerName&SrcApp=CustomerName&DestLinkType=FullRecord&KeyUT=000448075100002&DestApp=WOS", "published" : false, "snippet" : true } ], "journal" : { "otype" : "Journal", "mtid" : 28331, "link" : "/api/journal/28331", "label" : "EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 1434-193X 1099-0690", "pIssn" : "1434-193X", "eIssn" : "1099-0690", "reviewType" : "REVIEWED", "noIF" : false, "sciIndexed" : true, "scopusIndexed" : true, "lang" : "FOREIGN", "hungarian" : false, "published" : true, "oldId" : 28331, "snippet" : true }, "volume" : "2018", "issue" : "39", "firstPage" : "5355", "lastPage" : "5374", "firstPageOrInternalIdForSort" : "5355", "pageLength" : 20, "publishedYear" : 2018, "abstractText" : "Novel pyranose derivatives that display Ferrier- and Ferrier-Nicholas-like reactivity have been designed. These systems: 1-C-alkynyl-2-deoxy-2-C-methylene pyranosides (Ferrier), and their corresponding dicobalthexacarbonyl alkenyl derivatives (Ferrier-Nicholas), which can be accessed by a concise synthetic route from commercially available tri-O-acetyl-d-glucal, allow the incorporation of two nucleophiles (at positions C-3 and C-2) in the pyranose ring. The study of these systems has resulted in the discovery of novel reaction patterns that allow, among others, access to open-chain derivatives, branched pyranosides, 1,6-anhydro derivatives and, when reacting with indole, access to a new family of tetracyclic indole-containing carbohydrate derivatives, namely, cyclohepta[b]indole-fused glycals. The latter are, most likely, formed by a bis Ferrier-type rearrangement followed by an unusual intramolecular 7-endo-dig Friedel-Crafts alkenylation of one of the indole moieties by the C-1 alkyne.", "subjects" : [ { "otype" : "Classification", "mtid" : 10293, "link" : "/api/classification/10293", "label" : "Kémiai tudományok", "published" : true, "snippet" : true } ], "keywords" : [ { "otype" : "Keyword", "mtid" : 1002126, "link" : "/api/keyword/1002126", "label" : "glycals", "published" : true, "oldId" : 1002126, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1040047, "link" : "/api/keyword/1040047", "label" : "MOLECULAR DIVERSITY", "published" : true, "oldId" : 1040047, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1566380, "link" : "/api/keyword/1566380", "label" : "Synthesis design", "published" : true, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1640395, "link" : "/api/keyword/1640395", "label" : "Ferrier reaction", "published" : true, "snippet" : true }, { "otype" : "Keyword", "mtid" : 1640396, "link" : "/api/keyword/1640396", "label" : "Nicholas reaction", "published" : true, "snippet" : true } ], "digital" : null, "printed" : null, "sourceYear" : 2019, "foreignEdition" : true, "foreignLanguage" : true, "fullPublication" : true, "conferencePublication" : false, "nationalOrigin" : null, "missingAuthor" : false, "oaType" : "NONE", "oaCheckDate" : "2021-08-07", "oaFree" : false, "citationCount" : 0, "citationCountUnpublished" : 0, "citationCountWoOther" : 0, "independentCitCountWoOther" : 0, "doiCitationCount" : 0, "wosCitationCount" : 0, "scopusCitationCount" : 0, "independentCitationCount" : 0, "unhandledCitationCount" : 0, "citingPubCount" : 0, "independentCitingPubCount" : 0, "unhandledCitingPubCount" : 0, "citedPubCount" : 1, "citedCount" : 1, "ratings" : [ { "otype" : "SjrRating", "mtid" : 10867640, "link" : "/api/sjrrating/10867640", "label" : "sjr:Q1 (2018) Scopus - Organic Chemistry EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 1434-193X 1099-0690", "listPos" : 35, "rankValue" : 0.24, "type" : "journal", "ratingType" : { "otype" : "RatingType", "mtid" : 10002, "link" : "/api/ratingtype/10002", "label" : "sjr", "code" : "sjr", "published" : true, "snippet" : true }, "subject" : { "otype" : "ClassificationExternal", "mtid" : 1605, "link" : "/api/classificationexternal/1605", "label" : "Scopus - Organic Chemistry", "published" : true, "oldId" : 1605, "snippet" : true }, "ranking" : "Q1", "calculation" : "DIRECT", "published" : true, "snippet" : true } ], "ratingsForSort" : "Q1", "hasCitationDuplums" : false, "userChangeableUntil" : "2021-11-05T13:02:23.610+0000", "directInstitutesForSort" : "", "ownerAuthorCount" : 7, "ownerInstituteCount" : 26, "directInstituteCount" : 0, "authorCount" : 3, "contributorCount" : 0, "hasQualityFactor" : true, "link" : "/api/publication/30524372", "label" : "Miranda Silvia et al. Diversity-Oriented Synthetic Endeavors of Newly Designed Ferrier and Ferrier-Nicholas Systems Derived from 1-C-Alkynyl-2-deoxy-2-C-Methylene Pyranosides. (2018) EUROPEAN JOURNAL OF ORGANIC CHEMISTRY 1434-193X 1099-0690 2018 39 5355-5374", "template" : "