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Páez) and a CONICET research grant ( R.3646/14 , G. Páez). The authors wish to thank Stabro Kasaneva, Christian Cubelli, Jorge Osorio, Constantino Mendiz, Federico Heit and the entire El Guanaco mine staff for their help, discussions, and access to data. The authors wish to thank Prof. Karoly Nemeth and an anonymous reviewer for their thoughtful reviews, their comments and suggestions certainly helped to improve this manuscript. 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