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A stepwise mechanism has been established, and no transition state for a concerted pathway could be obtained. The electron distribution of the ring can be understood in terms of a MO model, where the two substituents at phosphorus act as a pseudo pi center. Amino substituents on the sigma (4) phosphorus and silyl group on the neighbouring carbon change the stability order of the possible isomers, stabilizing the 1,2-diphosphete ring. 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