{ "labelLang" : "hun", "responseDate" : "2024-03-28 20:32", "content" : { "otype" : "JournalArticle", "mtid" : 21272388, "status" : "ADMIN_APPROVED", "published" : true, "comment" : "Hydrolysis of dimethylphenyltin(IV) and triphenyltin(IV) chlorides in different aqueous ethanol solutions\nAN 2008:889439\nCAN 149:355966\n29-8\nOrganometallic and Organometalloidal Compounds\nChemistry Department, Shahid Beheshti University, Evin, Iran.\nJournal\n0008-4042\n76-87-9; 1058213-29-8; 1058213-31-2; 1058213-33-4 Role: FMU (Formation, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), FORM (Formation, nonpreparative), PROC (Process) (hydrolysis of dimethylphenyltin and triphenyltin chlorides in different aq. ethanol solns. and formation consts. of hydrolysis products); 639-58-7 (Triphenyltin chloride); 41825-39-2 (Dimethyl(phenyl)tin chloride) Role: PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (hydrolysis of dimethylphenyltin and triphenyltin chlorides in different aq. ethanol solns. and formation consts. of hydrolysis products)\nN1 -:Caplus\nwritten in English\n: Hydrogen bond\n: Hydrolysis\n: Solvent polarity effect (hydrolysis of dimethylphenyltin and triphenyltin chlorides in different aq. ethanol solns. and formation consts. of hydrolysis products)\n: tin triphenyl chloride hydrolysis product formation const\n: dimethylphenyltin chloride hydrolysis product formation const\n: solvent polarity effect phenyltin chloride hydrolysis\nN2: The hydrolysis of [(Me)2(Ph)Sn(IV)]+ and [(Ph)3Sn(IV)]+ was studied at 25° and different aq. solns. of EtOH, using a combination of spectrophotometric and potentiometric techniques. The species formed together with their formation consts. were detd. using the computer program Squad over a wide pH range of 1 to 11. The hydrolysis consts. in different media were analyzed in terms of Kamlet and Taft parameters. Single-parameter correlation of the formation consts., K11 and K12, vs. α (H-bond donor acidity), β (H-bond acceptor basicity), and Ď€* (dipolarity/polarizability) for both cases are relatively poor in all solns., but multiparameter correlation represents significant improvement with regard to the single-parameter models. The authors also used the normalized polarity parameter, ETN, alone and in combination with the Kamlet-Taft parameter to find a better correlation of the formation consts. in different aq. EtOH solns. 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