SPME-GC-pyrolysis-AFS determination of methylmercury in marine fish products by alkaline sample preparation and aqueous phase phenylation derivatization

Jokai, Z [Jókainé Szatura, Zsuzsa (Higanyspeciáció, ...), szerző] Alkalmazott Kémia Tanszék (BCE / ÉTK); Abranko, L [Abrankó, László (Élelmiszertudomány), szerző] Alkalmazott Kémia Tanszék (BCE / ÉTK); Fodor, P [Fodor, Péter (Analitikai kémia), szerző] Alkalmazott Kémia Tanszék (BCE / ÉTK)

Angol nyelvű Tudományos Szakcikk (Folyóiratcikk)
  • SJR Scopus - Agricultural and Biological Sciences (miscellaneous): D1
    Characterization of a cost-efficient analytical method based on alkaline sample digestion with KOH and NaOH, followed by aqueous phase phenylation derivatization with NaBPh4 and solid phase microextraction (SPME) for the determination of methylmercury in typical fish-containing food samples commercially available in Hungary, is reported. The sample preparation procedure along with the applied SPME-GC-pyrolysis-AFS system was validated by measuring certified reference materials (CRM) BCR-464, TORT-2, and a candidate CRM BCR 710. To carry out an estimation of average Hungarian methylmercury exposures via marine fish and/or fish-containing food consumption, 16 commercially available products and 3 pooled representative seafood samples of-according to a previous European survey-the three most consumed fish species in Hungary, herring, sardines, and hake, were analyzed. Methylmercury concentrations of the analyzed samples were in the range 0.016-0.137 mu g of MeHg g(-1) dry weight as Hg.
    Hivatkozás stílusok: IEEEACMAPAChicagoHarvardCSLMásolásNyomtatás
    2021-01-20 10:56