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alcohols\nbearing a phenyl group in the side-chain, diastereomers of novel 1- or\n2-phenyl-substituted 1,3,2-oxazaphosphino[4,3-a]isoquinoline 4-oxides,\nand 1,2,3-oxathiazino[4,3-a]isoquinoline 4-oxides and 4,4-dioxides were\nprepared. NMR analysis and DFT calculations on the prepared\ntetrahydroisoquinoline-condensed 1,2,3-heterocycles revealed that their\nconformational equilibria of cis(1)-trans-cis(2) type are influenced by\nthe relative configuration of P-4 in the 1,3,2-oxazaphosphinanes, and\nby the position of the phenyl group in the 1,2,3-oxathiazines. (C) 2007\nElsevier B.V. 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