Reduction of Aromatic Nitro-compounds with NaBH4 Catalyzed by Nickel Complexes of o-Aminothiophenol Schiff Base Derivatives

Vizi-Orosz, A; Marko, L [Markó, László (Fémorganikus kémia), szerző]

Angol nyelvű Tudományos Szakcikk (Folyóiratcikk)
Megjelent: TRANSITION METAL CHEMISTRY 0340-4285 1572-901X 16 (2) pp. 215-217 1991
    Azonosítók
    • MTMT: 1092484
    The nickel complexes of Schiff bases formed from omicron-aminothiophenol and alpha-dicarbonyl compounds, Ni(omicron-SC6H4N = CRCR = NC6H4S-omicron) (R = H, Me, Ph) (1a-c), catalyse the reduction of aromatic nitro compounds by NaBH4. The reduced species [Ni(omicron-SC6H4N = CHCH = NC6H4S-omicron)]- (2) and [Ni(omicron-SC6H4NHCH2CH = NC6H4S-omicron)]- (3) were identified as intermediates in the catalytic cycle.
    Hivatkozás stílusok: IEEEACMAPAChicagoHarvardCSLMásolásNyomtatás
    2020-11-26 14:05