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The basicities of the corresponding donor groups differed only slightly in the series of ligands. A purely mathematical method, the matrix rank analysis carried out on the EPR spectrum package recorded in the presence of copper(II), indicated the formation of 6 independent paramagnetic species. Accordingly, Cu2+ (aqua complex) and the complexes [CuLH](2+), [CuL](+), [CuL2H2](2+), [CuL2H](+), and [CuL2] were considered in the subsequent analysis of series of spectra, and also two isomers of [CuL2] were identified. The formation constants and the EPR parameters, e.g. the isotropic g-factors and the copper and nitrogen hyperfine couplings for the above species, were determined in the same optimization procedure by the simultaneous evaluation of spectra. The ligands \"LH\" are suggested to bind in equatorial positions through their carboxylate groups, while the amino acids in the L protonation state are likely to occupy two equatorial sites via the amino and carboxylate groups. 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